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A direct route to polythiophenes displaying lateral substituents: Easy one‐step synthesis and polymerization of thiophene monomers substituted by a dimethylenecarboxylate (CH2CH2COOR) appendage on the 3‐position

Stéphane Sengmany、Claire Ceballos、Romain Belhadj 等 8 位作者2011-11-28Journal of Polymer Science Part A Polymer Chemistry

Abstract Thiophene monomers displaying a dimethylenecarboxylate (CH 2 CH 2 COOR) substituent on the 3‐position of the aromatic ring can be easily obtained and in one step from the electrochemically induced reaction of 3‐bromothiophene with the corresponding acrylate (CH 2 CHCOOR). The synthesis of the ethyl ester mon…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsElectrochemical Analysis and Applications

Effect of integrated extrusion–equal channel angular pressing temperature on microstructural characteristics of low carbon steel

M Ghazani Shaban、B. Eghbali2011-11-28Materials Science and Technology

In the present research, a combined forward extrusion–equal channel angular pressing was developed and executed for the deformation of a plain carbon steel. In this method, two different deformation steps, including forward extrusion and equal channel angular pressing, take place successively in a single die. The defo…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetallurgy and Material Forming

Voltage endurance characteristics of epoxy/silica nanocomposites

Tomonori Iizuka、Katsumi Uchida、Toshikatsu Tanaka2011-11-28Electronics and Communications in Japan

Abstract Two kinds of epoxy/silica nanocomposites, specifically Aerosil and Nanopox specimens, were prepared to clarify the effect of nano‐filler dispersion and of coupling agents on electric field endurance. According to SEM observation, nano‐fillers were well dispersed in the former specimens, while some agglomerati…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

Improvement of transfer characteristic for carbon nanotube field effect transistor with poly crystalline PbZrxTi1-xO3 gate by ionic liquid

Shogo Kataoka、Takayuki Arie、Seiji Akita2011-11-28Applied Physics Letters

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation Shogo Kataoka, Takayuki Arie, Seiji Akita; Improvement of transfer characteristic for carbon nano…

Carbon Nanotubes in CompositesAdvanced Memory and Neural ComputingMechanical and Optical Resonators

Influence of strain on the electronic structure of the TbMnO3/SrTiO3 epitaxial interface

Sriram Venkatesan、Markus Döblinger、Christophe Daumont 等 7 位作者2011-11-28Applied Physics Letters

Understanding the magnetotransport properties of epitaxial strained thin films requires knowledge of the chemistry at the interface. We report on the change in Mn electronic structure at the epitaxially strained TbMnO3/SrTiO3 interface. Scanning transmission electron microscopy shows an abrupt interface with a bright…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Low-temperature graphene growth using epochal catalyst of PdCo alloy

Eun Sung Kim、Hyeon‐Jin Shin、Seon‐Mi Yoon 等 9 位作者2011-11-28Applied Physics Letters

Palladium-Cobalt alloy as a catalyst was introduced to realize low temperature graphene growth on glass substrate by using remote RF plasma-enhanced chemical vapor deposition. Few layer graphene films were easily formed with high transmittance of 88.8% at temperature as low as 400 °C, in good contrast with Ni catalyst…

Advancements in Battery MaterialsGraphene research and applicationsChemical and Physical Properties of Materials

Nonradiative deactivation of europium( iii ) luminescence as a detection scheme for moisture

Astrid C. Knall、Martin Tscherner、Nadja Noormofidi 等 9 位作者2011-11-28The Analyst

The nonradiative deactivation of the excited state of europium(III)-based phosphors via OH-vibrations in the presence of water allows the detection of moisture in nitrogen at concentration levels down to at least 25 ppm (0.09% RH).

Luminescence Properties of Advanced MaterialsLuminescence and Fluorescent MaterialsLanthanide and Transition Metal Complexes

Electric field gradients at111In/111Cd probe atoms on A-sites in 211-MAX phases

Dagmar Jürgens、M. Uhrmacher、H.-G. Gehrke 等 9 位作者2011-11-28Journal of Physics Condensed Matter

The method of perturbed angular correlation (PAC) was applied to selected MAX phases with 211 stoichiometry. Radioactive (111)In ions were implanted in order to measure the electric field gradients (EFG) in the key compounds Ti(2)InC and Zr(2)InC to determine the strength and symmetry of the EFG at the In-site. Furthe…

Advanced biosensing and bioanalysis techniquesAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

Berry-curvature-mediated valley-Hall and charge-Hall effects in graphene via strain engineering

Zhen‐Gang Zhu、Jamal Berakdar2011-11-28Physical Review B

We point out a practical way to induce a finite charge-Hall conductivity in graphene via an off-diagonal strain. Our conclusions are based on a general analysis and supported by numerical examples. The interplay between a substrate-induced gap and the strain is discussed. We show that the substrate-induced gap itself…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Metastable De-excitation Spectroscopy and Density Functional Theory Study of the Selective Oxidation of Crotyl Alcohol over Pd(111)

James Naughton、Andrew Pratt、Charles Woffinden 等 8 位作者2011-11-28The Journal of Physical Chemistry C

The extremely surface sensitive technique of metastable de-excitation spectroscopy (MDS) has been utilized to probe the bonding and reactivity of crotyl alcohol over Pd(111) and provide insight into the selective oxidation pathway to crotonaldehyde. Auger de-excitation (AD) of metastable He (2 3 S) atoms reveals disti…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Time-Resolved Fluorescence Immunoassay for C-Reactive Protein Using Colloidal Semiconducting Nanoparticles

Harri Härmä、Juha Toivonen、Juhani T. Soini 等 5 位作者2011-11-28Sensors

Besides the typical short-lived fluorescence with decay times in the nanosecond range, colloidal II/VI semiconductor nanoparticles dispersed in buffer also possess a long-lived fluorescence component with decay times in the microsecond range. Here, the signal intensity of the long-lived luminescence at microsecond ran…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesBiosensors and Analytical Detection

Simulation of heterogeneous end-coupling reactions in polydisperse polymer blends

Daria V. Guseva、Yaroslav V. Kudryavtsev、Anatoly V. Berezkin2011-11-28The Journal of Chemical Physics

The influence of polydispersity on the interfacial kinetics of end-coupling and microstructure formation in the melt of immiscible polymers was studied using dissipative particle dynamics simulations. The irreversible reaction started at a flat interface between two layers, each of which contained polymer chains of tw…

Advanced Polymer Synthesis and CharacterizationMaterial Dynamics and PropertiesBlock Copolymer Self-Assembly

Dispersion of carbon nanotubes through amphiphilic block copolymers: Rheological and dielectrical characterizations of poly(ethylene oxide) composites

Chantal Semaan、M. Schappacher、Alain Soum2011-11-28Polymer Composites

Abstract In this article, we report on some properties of polymer nanocomposites prepared from dispersions of multiwall carbon nanotubes (CNT) in aqueous solution prepared using amphiphilic block copolymers. These nanocomposites are made of polyethylene oxide as matrix and CNT wrapped with copolymers as fillers. We in…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesDielectric materials and actuators

Mean field theory of charged dendrimer molecules

Thomas Lewis、Victor Pryamitsyn、Venkat Ganesan2011-11-28The Journal of Chemical Physics

Using self-consistent field theory (SCFT), we study the conformational properties of polyelectrolyte dendrimers. We compare results for three different models of charge distributions on the polyelectrolytes: (1) a smeared, quenched charge distribution characteristic of strong polyelectrolytes; (2) a smeared, annealed…

DNA and Nucleic Acid ChemistryPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Design technique for all-dielectric non-polarizing beam splitter plate

A. Rizea2011-11-28Opto-Electronics Review

Abstract There are many situations when, for the proper working, an opto-electronic device requiring optical components does not change the polarization state of light after a reflection, splitting or filtering. In this paper, a design for a non-polarizing beam splitter plate is proposed. Based on certain optical prop…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Quantitative determination of energy enhanced interlayer transport in pulsed laser deposition of SrTiO3

Gyula Eres、J. Z. Tischler、Christopher M. Rouleau 等 6 位作者2011-11-28Physical Review B

We show that the analysis of single-shot surface x-ray diffraction transients in terms of time-dependent coverages allows quantitative determination of interlayer transport in pulsed-laser deposition of SrTiO${}_{3}$. The fast interlayer transport during and immediately after the arrival of the laser plume and before…

Semiconductor materials and devicesAdvanced X-ray and CT ImagingElectronic and Structural Properties of Oxides

Dual frequency operation of a blue phase liquid crystal

Shuhei Yabu、Hiroyuki Yoshida、Gihwan Lim 等 8 位作者2011-11-28Optical Materials Express

The authors demonstrate dual frequency switching in a cubic blue phase liquid crystal. The dual frequency blue phase was prepared by adding a strongly twisting chiral dopant to a dual-frequency nematic liquid crystal mixture. The crossover frequency appeared at few hundred kHz in the blue phase, and sub-millisecond re…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsAdvanced Optical Imaging Technologies

Preparation of CoNi high surface area porous foams by substrate controlled electrodeposition

Lidija D. Rafailović、Christoph Gammer、Christian Rentenberger 等 7 位作者2011-11-28Physical Chemistry Chemical Physics

We demonstrate that nanofabrication of 3D dendritic CoNi alloy foams with an open porous structure can be achieved by electrodeposition onto a single-crystalline Cu(111) substrate at ambient conditions. The very low wettability of this substrate caused by its low surface energy allows tailoring the CoNi deposit morpho…

Electrocatalysts for Energy ConversionElectrodeposition and Electroless CoatingsNanoporous metals and alloys

Aggregation-induced conformational transitions in bovine β-lactoglobulin adsorbed onto open chitosan structures

João Borges、José M. Campiña、Hiléia K.S. Souza 等 5 位作者2011-11-28Soft Matter

Chitosan is a natural polysaccharide which strongly interacts with whey proteins in solution. Certain protein–polyelectrolyte complexes and electrostatically assembled thin films have been shown to be good platforms for the preservation of globular and small proteins in their native state mainly due to the hydrophilic…

Proteins in Food SystemsNanocomposite Films for Food PackagingPolymer Surface Interaction Studies

Copper oxide activation of soft-templated mesoporous carbons and their electrochemical properties for capacitors

Chunfeng Xue、Yingying Lv、Fan Zhang 等 5 位作者2011-11-28Journal of Materials Chemistry

Ordered mesoporous carbon with a 2-D hexagonal mesostructure was prepared by an organic–organic co-assembly method. The mesoporous carbon was activated by using CuO to improve its mesoporosity. Compared with pristine mesoporous carbon (PMC-900) carbonized at 900 °C, the mean mesopore size of the activated mesoporous c…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationMesoporous Materials and Catalysis