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Reversible Assembly of Tunable Nanoporous Materials from “Hairy” Silica Nanoparticles

Amir Khabibullin、Emily Fullwood、Patrick Kolbay 等 4 位作者2014-09-22ACS Applied Materials & Interfaces

Membranes with 1-100 nm nanopores are widely used in water purification and in biotechnology, but are prone to blockage and fouling. Reversibly assembled nanoporous membranes may be advantageous due to recyclability, cleaning, and retentate recovery, as well as the ability to tune the pore size. We report the preparat…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsNanoporous metals and alloys

Empirical study and prediction of contact angle and surface free energy of commonly used plastics with pillar‐like structure

Chung‐Han Chiou、Sheng‐Jen Hsieh2014-09-22Surface and Interface Analysis

An effective approach is proposed to estimate liquids' contact angles on five commonly used plastics, polyethylene terephthalate, polypropylene, high‐density polyethylene, low‐density polyethylene, and polyvinyl chloride, with pillar‐like structures. A change in liquid droplets' three‐phase contact line due to surface…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdhesion, Friction, and Surface Interactions

Directional Photomanipulation of Breath Figure Arrays

Wei Wang、Can Du、Xiaofan Wang 等 7 位作者2014-09-22Angewandte Chemie

Abstract Porous polymeric films are of paramount importance in many areas of modern science and technology. However, processing methods typically based on direct writing, imprint, and lithography techniques have low throughput and are often limited to specific fabricated shapes. Herein, we demonstrate the directional…

Liquid Crystal Research AdvancementsBlock Copolymer Self-AssemblyAdvanced Materials and Mechanics

Interplay between snake and quantum edge states in a graphene Hall bar with a pn-junction

S. P. Milovanović、M. Ramezani Masir、F. M. Peeters2014-09-22Applied Physics Letters

The magneto- and Hall resistance of a locally gated cross shaped graphene Hall bar is calculated. The edge of the top gate is placed diagonally across the center of the Hall cross. Four-probe resistance is calculated using the Landauer-Büttiker formalism, while the transmission coefficients are obtained using the non-…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Hybrid Graphene–Giant Nanocrystal Quantum Dot Assemblies with Highly Efficient Biexciton Emission

Yongqian Gao、Oleksiy Roslyak、Enkeleda Dervishi 等 14 位作者2014-09-22Advanced Optical Materials

A monolayer of graphene strongly enhances the bi-exciton emission efficiency of CdSe/CdS core/thick-shell nanocrystal quantum dots (NQDs), the so-called “giant”-NQDs. As an explanation, a new plasmon mode is proposed, resulting from local oscillations of excess hole density (the hole puddle) that is accumulated direct…

Graphene research and applicationsQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

Fluorescence and thermal stress properties of Yb3+-doped alumino silicate glasses for ultra high peak power laser applications

Mirko Tiegel、Andreas Herrmann、Stefan Kühn 等 9 位作者2014-09-22Laser Physics Letters

Fluorescence and thermal stress properties of Yb3+-doped alumino silicate glasses for ultra high peak power laser applications, Tiegel, Mirko, Herrmann, Andreas, Kuhn, Stefan, Rüssel, Christian, Körner, Jörg, Klöpfel, Diethard, Seifert, Reinhard, Hein, Joachim, Kaluza, Malte C

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

EFFECT OF ORGANICALLY MODIFIED MONTMORILLONITE CLAY ON MORPHOLOGICAL, PHYSICOMECHANICAL, THERMAL STABILITY, AND WATER VAPOR TRANSMISSION RATE PROPERTIES OF BIIR-CO RUBBER NANOCOMPOSITE

Shubham Kumar、Golok B. Nando、Sujith Nair 等 6 位作者2014-09-22Rubber Chemistry and Technology

ABSTRACT Rubber nanocomposites based on bromobutyl rubber (BIIR), polyepichlorohydrin rubber (CO), carbon black (CB), and organically modified montmorillonite clay (NC) were prepared via melt compounding technique. Effects of NC dosage on various properties of the developed BIIR-CO nanocomposites were studied. Morphol…

Polymer Nanocomposites and PropertiesTribology and Wear AnalysisPolymer Nanocomposite Synthesis and Irradiation

The effect of polar nanoregions on electromechanical properties of relaxor-PbTiO3 crystals: Extracting from electric-field-induced polarization and strain behaviors

Fei Li、Zhuo Xu、Shujun Zhang2014-09-22Applied Physics Letters

The electric-field-induced polarization and strain of Pb(Mg1/3Nb2/3)O3 (PMN) and Pb(Mg1/3Nb2/3)O3-0.27PbTiO3 (PMN-0.27PT) crystals were investigated at temperatures above their respective maximum permittivity temperatures Tm, where the macro-polarizations vanish while polar nanoregions (PNRs) still persist. The local…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric materials and actuators

Ordered arrays of a defect-modified ferroelectric polymer for non-volatile memory with minimized energy consumption

Xiangzhong Chen、Xin Chen、Xu Guo 等 6 位作者2014-09-22Nanoscale

Ferroelectric polymers are among the most promising materials for flexible electronic devices. Highly ordered arrays of the defect-modified ferroelectric polymer P(VDF-TrFE-CFE) (poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene)) are fabricated by nanoimprint lithography for nonvolatile memory applicati…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Topochemical Oxidation Preparation of Regular Hexagonal Manganese Oxide Nanoplates with Birnessite-Type Layered Structure

Jianfang Wang、Gaini Zhang、Lijun Ren 等 7 位作者2014-09-22Crystal Growth & Design

The birnessite-type layered manganese oxide nanoplates with good dispersity and regular hexagonal morphology were obtained by topochemical oxidizing precursor Mn(OH) 2 in NaClO solution for 24 h at room temperature, and its formation process was systematically investigated on the basis of the XRD pattern, FESEM and TE…

Supercapacitor Materials and FabricationMultiferroics and related materialsLayered Double Hydroxides Synthesis and Applications

Diatoms as indicators of historical water quality: A comparison of samples taken in the Wemmershoek catchment (Western Province, South Africa) in 1960 and 2008

WR Harding、JC Taylor2014-09-22Water SA

Historical diatom records provide a means of retrospectively determining water quality and inferring ecological condition in rivers and streams. In this study we re-sampled sites originally sampled 48 years previously. We then determined the scores for the Biological Diatom Index (BDI) and the South African Diatom Ind…

Paleontology and Stratigraphy of FossilsMine drainage and remediation techniquesDiatoms and Algae Research

Application of Visible Light Photocatalysis with Particle Lithography To Generate Polynitrophenylene Nanostructures

Susan D. Verberne-Sutton、Rashanique D. Quarels、Xianglin Zhai 等 5 位作者2014-09-22Journal of the American Chemical Society

Visible light photoredox catalysis was combined with immersion particle lithography to prepare polynitrophenylene organic films on Au(111) surfaces, forming a periodic arrangement of nanopores. Surfaces masked with mesospheres were immersed in solutions of p-nitrobenzenediazonium tetrafluoroborate and irradiated with…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures

FTIR and EPR Studies of Nickel Substituted Nanostructured Mn Zn Ferrite

C. Venkataraju、R Paulsingh2014-09-22Journal of Nanoscience

The spinel ferrite system<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M1"><mml:msub><mml:mrow><mml:mtext>Mn</mml:mtext></mml:mrow><mml:mrow><mml:mn>0.5</mml:mn><mml:mo>-</mml:mo><mml:mi>x</mml:mi></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mtext>Ni</mml:mtext></mml:mrow><mml:mrow><mml:mi>x</mml:mi><…

Magnetic Properties and Synthesis of FerritesIron oxide chemistry and applicationsMagneto-Optical Properties and Applications

Fluoropolymer coatings for improved carbon nanotube transistor device and circuit performance

Seonpil Jang、Bong-Jun Kim、Michael L. Geier 等 6 位作者2014-09-22Applied Physics Letters

We report on the marked improvements in key device characteristics of single walled carbon nanotube (SWCNT) field-effect transistors (FETs) by coating the active semiconductor with a fluoropolymer layer such as poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE). The observed improvements include: (i) A reduction…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsMechanical and Optical Resonators

Demonstration of magnetoelectric memory cell in (110) [Pb(Mg1/2Nb2/3)O3]0.68-[PbTiO3]0.32/Ru/FeCo heterostructures

Xuemeng Han、Li Xi、Li Yue 等 8 位作者2014-09-22Applied Physics Letters

An electric-field pulses driven magnetoelectric memory cell in a single layered ferromagnetic thin film was fabricated by direct-current magnetron sputtering Ru/Fe65Co35 on ferroelectric (110) [Pb(Mg1/2 Nb2/3)O3]0.68-[PbTiO3]0.32 (PMN-PT) substrates. The magnetization in the orthogonal directions can be reset by the p…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Theoretical Model of Oxidative Adsorption of Water on a Highly Reduced Reconstructed Oxide Surface

Nathan Z. Koocher、John Mark P. Martirez、Andrew M. Rappe2014-09-22The Journal of Physical Chemistry Letters

Highly reduced surface reconstructions of BaTiO3 (001) have been found to be composed of a TiO2 surface covered with Ti adatoms occupying surface interstitial sites. We predict the reactivity of these highly oxophilic and reduced surface Ti species through density functional theory, where we calculate the adsorption o…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

Preparation of Gold Nanorods and Their Applications in Photothermal Therapy

Kai Xia、Liming Zhang、Yuanfu Huang 等 4 位作者2014-09-22Journal of Nanoscience and Nanotechnology

Gold nanorods (GNRs) have recently been widely studied due to their unique optical and electronic properties which are dependent on their shape, size, and aspect ratio. Seed-mediated growth method has become the most widely method for the synthesis of GNRs due to its advantages of simplicity of procedure, high yield o…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Probing Polymer–Pendant Interactions in the Conducting Redox Polymer Poly(pyrrol-3-ylhydroquinone)

Christoffer Karlsson、Hao Huang、Maria Strømme 等 5 位作者2014-09-22The Journal of Physical Chemistry C

High Resolution Image Download MS PowerPoint Slide Conducting polymers with redox active pendant groups show properties typical of both conducting polymers (i.e., capacitive charging and intrinsic conductivity) and redox polymers (i.e., electrochemical surface response at the formal potential of the pendant groups). T…

Organic Electronics and PhotovoltaicsSupercapacitor Materials and FabricationConducting polymers and applications

Effect of spatial dispersion on the topological transition in metamaterials

Maxim A. Gorlach、Pavel A. Belov2014-09-22Physical Review B

We investigate the topological transition in metamaterials considering a structure composed of the uniaxial electric scatterers. Our study is based on the discrete dipole model, which allows us to take into account the effects of spatial dispersion in the structure. The nonlocal effects lead to the existence of the tr…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAcoustic Wave Phenomena Research

Effects of melamine polyphosphate and halloysite nanotubes on the flammability and thermal behavior of polyamide 6

Jun Sun、Xiaoyu Gu、Mathieu Coquelle 等 7 位作者2014-09-22Polymers for Advanced Technologies

Melamine polyphosphate (MPP) and halloysite nanotubes (HNT) were introduced to polyamide 6 (PA6) by melt blending in order to improve the fire resistance. PA6 composite containing 12% flame retardants with good spinnability was obtained. The flammability of PA6 composite was characterized by limiting oxygen index (LOI…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesSynthesis and properties of polymers