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Band Gap Tunable Zn2SnO4 Nanocubes through Thermal Effect and Their Outstanding Ultraviolet Light Photoresponse

Huaming Li、Linfeng Hu、Hui Liu 等 6 位作者2014-10-30Scientific Reports

This work presents a method for synthesis of high-yield, uniform and band gap tunable Zn2SnO4 nanocubes. These nanocubes can be further self-assembled into a series of novel nanofilms with tunable optical band gaps from 3.54 to 3.18 eV by simply increasing the heat treatment temperature. The Zn2SnO4 nanocube-nanofilm…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsNanowire Synthesis and Applications

Compact Ag@Fe3O4 Core-shell Nanoparticles by Means of Single-step Thermal Decomposition Reaction

Maria Eugênia Fortes Brollo、Román López-Ruiz、Diego Muraca 等 6 位作者2014-10-30Scientific Reports

A temperature pause introduced in a simple single-step thermal decomposition of iron, with the presence of silver seeds formed in the same reaction mixture, gives rise to novel compact heterostructures: brick-like Ag@Fe3O4 core-shell nanoparticles. This novel method is relatively easy to implement, and could contribut…

Nanoparticle-Based Drug DeliveryMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

Absolute photoluminescence quantum yields of IR26 and IR-emissive Cd 1−x Hg x Te and PbS quantum dots – method- and material-inherent challenges

Soheil Hatami、Christian Würth、Martin Kaiser 等 11 位作者2014-10-30Nanoscale

Bright emitters with photoluminescence in the spectral region of 800-1600 nm are increasingly important as optical reporters for molecular imaging, sensing, and telecommunication and as active components in electrooptical and photovoltaic devices. Their rational design is directly linked to suitable methods for the ch…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsAdvanced Semiconductor Detectors and Materials

Effect of grain sizes on mechanical properties and biodegradation behavior of pure iron for cardiovascular stent application

Camillus Sunday Obayi、R. Tolouei、Afghany Mostavan 等 8 位作者2014-10-30Biomatter

Pure iron has been demonstrated as a potential candidate for biodegradable metal stents due to its appropriate biocompatibility, suitable mechanical properties and uniform biodegradation behavior. The competing parameters that control the safety and the performance of BMS include proper strength-ductility combination,…

Magnesium Alloys: Properties and ApplicationsHydrogen embrittlement and corrosion behaviors in metalsAdvanced materials and composites

Electrochemical performance of a portable asymmetric supercapacitor device based on cinnamon-like La 2 Te 3 prepared by a chemical synthesis route

Swati J. Patil、Bebi Patil、Ravindra N. Bulakhe 等 4 位作者2014-10-30RSC Advances

A cinnamon-like La2Te3 nanostructure has been prepared by a simple chemical bath deposition (CBD) route. Field emission-scanning electron microscopy (FE-SEM), X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy techniques have been used to characterize the morphological and structural properties…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationMXene and MAX Phase Materials

Seed‐Induced Growth of Flower‐Like Au–Ni–ZnO Metal–Semiconductor Hybrid Nanocrystals for Photocatalytic Applications

Yuanzhi Chen、Deqian Zeng、Michael B. Cortie 等 7 位作者2014-10-30Small

The combination of metal and semiconductor components in nanoscale to form a hybrid nanocrystal provides an important approach for achieving advanced functional materials with special optical, magnetic and photocatalytic functionalities. Here, a facile solution method is reported for the synthesis of Au-Ni-ZnO metal-s…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Biochemical Evaluation of Silver Nanoparticles in Wistar Rats

Oluyomi Stephen Adeyemı、Ifeoluwa Adewumi2014-10-30International Scholarly Research Notices

Background. Silver nanoparticles have found wider and increasing biomedical applications due to their broad antimicrobial characteristics. However, toxicity of nanoparticles is a subject of continued controversy, thus necessitating further studies in this direction. Objectives. This study investigated the biochemical…

Nanoparticles: synthesis and applications

Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate, B-(cyclotriborazanyl)amine-borane

Hassan A. Kalviri、Felix Gärtner、Gang Ye 等 5 位作者2014-10-30Chemical Science

B-(cyclotriborazanyl)amine-borane (BCTB) and a method is presented for its selective synthesis from AB. The reactivity of BCTB upon thermal treatment as well as catalytic dehydrogenation is studied and discussed with regard to facilitating the second dehydrogenation step in AB dehydrocoupling.

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionInorganic Fluorides and Related Compounds

Hot-electron cooling by acoustic and optical phonons in monolayers ofMoS2and other transition-metal dichalcogenides

Kristen Kaasbjerg、K. S. Bhargavi、S. S. Kubakaddi2014-10-30Physical Review B

We study hot-electron cooling by acoustic and optical phonons in monolayer ${\mathrm{MoS}}_{2}$. The cooling power $P$ (${P}_{e}=P/n$) is investigated as a function of electron temperature ${T}_{e}$ (0--500 K) and carrier density $n\phantom{\rule{0.28em}{0ex}}({10}^{10}--{10}^{13} {\mathrm{cm}}^{\ensuremath{-}2}$) tak…

Perovskite Materials and Applications2D Materials and ApplicationsThermal properties of materials

Fabrication and enhanced microwave absorption properties of Al 2 O 3 nanoflake-coated Ni core–shell composite microspheres

Biao Zhao、Gang Shao、Bingbing Fan 等 5 位作者2014-10-30RSC Advances

Core–shell composite microspheres with Ni cores and Al2O3 nanoflake shells have been successfully fabricated by the hydrothermal deposition method. The electromagnetic parameters of the Ni microspheres and Ni/Al2O3 composites are measured by a coaxial line method. The tangent losses for the Ni/Al2O3 composite are larg…

Metamaterials and Metasurfaces ApplicationsElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies

Assembly of Supramolecular Nanotubes from Molecular Triangles and 1,2-Dihalohydrocarbons

Zhichang Liu、Guoliang Liu、Yilei Wu 等 9 位作者2014-10-30Journal of the American Chemical Society

Precise control of molecular assembly is a challenging goal facing supramolecular chemists. Herein, we report the highly specific assembly of a range of supramolecular nanotubes from the enantiomeric triangular naphthalenediimide-based macrocycles (RRRRRR)- and (SSSSSS)-NDI-Δ and a class of similar solvents, namely, t…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials

Electrospinning of gelatin for tissue engineering – molecular conformation as one of the overlooked problems

Paweł Sajkiewicz、Dorota Kołbuk2014-10-30Journal of Biomaterials Science Polymer Edition

Gelatin is one of the most promising materials in tissue engineering as a scaffold component. This biopolymer indicates biocompatibility and bioactivity caused by the existence of specific amino acid sequences, being preferred sites for interactions with cells, with high similarity to natural extracellular matrix. The…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsCollagen: Extraction and Characterization

Fluorescent Nanohybrid of Gold Nanoclusters and Quantum Dots for Visual Determination of Lead Ions

Houjuan Zhu、Tao Yu、Hongda Xu 等 8 位作者2014-10-30ACS Applied Materials & Interfaces

Highly green emissive gold nanoclusters (Au NCs) are synthesized using glutathione as a stabilizing agent and mercaptopropionic acid as a ligand, and the intensity of fluorescence is specifically sensitive to lead ions. We then fabricated a ratiometric fluorescence nanohybrid by covalently linking the green Au NCs to…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Quantitative multiplexing with nano-self-assemblies in SERS

Setu Kasera、Lars O. Herrmann、Jesús del Barrio 等 5 位作者2014-10-30Scientific Reports

Multiplexed or simultaneous detection of multiple analytes is a valuable tool in many analytical applications. However, complications caused by the presence of interfering compounds in a sample form a major drawback in existing molecular sensor technologies, particularly in multi-analyte systems. Although separating a…

Gold and Silver Nanoparticles Synthesis and ApplicationsMass Spectrometry Techniques and ApplicationsSpectroscopy Techniques in Biomedical and Chemical Research

Kinetics and Thermodynamics of H 2 O Dissociation on Reduced CeO 2 (111)

Heine Anton Hansen、Christopher Wolverton2014-10-30The Journal of Physical Chemistry C

We use density functional theory to investigate the reaction between reduced CeO 2– x (111) and water. H 2 O dissociation to hydroxyl is facile on surface vacancies and lattice oxygen, while subsequent decomposition of hydroxyl into H 2 has a high barrier, which results in reversible adsorption of H 2 O under ultra-hi…

Catalytic Processes in Materials ScienceChemical Looping and Thermochemical ProcessesCatalysis and Oxidation Reactions

Relativistic Neel-order fields induced by electrical current in antiferromagnets

J. Zelezny、H. Gao、K. Vyborny 等 9 位作者2014-10-30arXiv

We predict that a lateral electrical current in antiferromagnets can induce non-equilibrium Néel order fields, i.e. fields whose sign alternates between the spin sublattices, which can trigger ultra-fast spin-axis reorientation. Based on microscopic transport theory calculations we identify staggered current-induced f…

Materials Science

Room Temperature Electrical Detection of Spin Polarized Currents in Topological Insulators

André Dankert、Johannes Geurs、M. Venkata Kamalakar 等 4 位作者2014-10-30arXiv

Topological insulators (TIs) are a new class of quantum materials that exhibit spin momentum locking (SML) of massless Dirac fermions in the surface states. Usually optical methods, such as angle and spin-resolved photoemission spectroscopy, have been employed to observe the helical spin polarization in the surface st…

Mesoscale and Nanoscale PhysicsMaterials Science

Magnetic anisotropy in FeSb studied by 57Fe Mössbauer spectroscopy

K. Komedera、A. K. Jasek、A. Blachowski 等 5 位作者2014-10-30arXiv

The Fe(1+x)Sb compound has been synthesized close to stoichiometry with x = 0.023(8). The compound was investigated by 57Fe Mössbauer spectroscopy in the temperature range 4.2 - 300 K. The antiferromagnetic ordering temperature was found as 232 K i.e. much higher than for the less stoichiometric material. Regular iron…

Materials ScienceStrongly Correlated Electrons

Intrinsic synchronization of an array of spin-torque oscillators driven by the spin-Hall effect

Giulio Siracusano、Riccardo Tomasello、Vito Puliafito 等 8 位作者2014-10-30arXiv

This paper micromagnetically studies the magnetization dynamics driven by the spin-Hall effect in a Platinum/Permalloy bi-layer. For a certain field and current range, the excitation of a uniform mode, characterized by a power with a spatial distribution in the whole ferromagnetic cross section, is observed. We sugges…

Mesoscale and Nanoscale PhysicsMaterials Science

PHASEGO: A toolkit for automatic calculation and plot of phase diagram

Zhong-Li Liu2014-10-30arXiv

The PHASEGO package extracts the Helmholtz free energy from the phonon density of states obtained by the first-principles calculations. With the help of equation of states fitting, it reduces the Gibbs free energy as a function of pressure/temperature at fixed temperature/pressure. Based on the quasi-harmonic approxim…

Materials Science