Materials Literature
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We reveal a strong elastic interaction between nonferroelastic domain walls in ferroelectric thin films. This interaction, having no analogue in bulk materials, is governed by elastic fields that are associated with the domain walls and extends to distances comparable to the film thickness. Such elastic widening of th…
A research on optimizing the synthesis conditions to obtain carboxymethyl chitosan with the highest solubility in 1%(v/v) acetic acid solvent have been performed. Optimization was performed by varying: the concentration of NaOH during alkalizing the chitosan, chitosan: monochloroacetic acid ratio, temperature and reac…
Abstract The synthesis, structures, and emission properties of vaulted trans ‐bis(salicylaldiminato)platinum(II) complexes 1 with diethylamino functionalities are described and compared with the non‐substituted analogues. The amino substitution provides an improvement of the linker dependence both for the color change…
Abstract We report on a homologous series of nine electron donor–acceptor systems featuring push–pull chromophores as electron acceptors, which are accessible by a cycloaddition‐retroelectrocyclization (CA‐RE) reaction. The conjugates comprise a Zn II porphyrin as electron donor, which is connected through either a ri…
In this study, the effect of nonwoven fabric thickness on electromagnetic shielding effectiveness (EMSE) was investigated and there was found to be a correlation between the thickness of needle-punched nonwoven fabric and EMSE. The production of needle-punched nonwoven fabrics from stainless steel staple fiber in the…
A modified sol-gel technique was developed to continuously vary the pore diameters in porous alumina templates for the purpose of growing nanowires. To coat the pore walls, the porous alumina film is initially soaked in a methanol/water solution to fill the pores with the desired concentration of water. The porous alu…
Abstract Mesoporous silicas are promising materials for the construction of host–guest hybrids by the accommodation of functional unit/guest species into the mesopore, and moreover, by hierarchical assembly with controlled location, density, and orientation. Precisely designed structures open up the versatile function…
This review covers some of the main trends in the field of synthesis and the applications of materials based on silicon nitride presented in publications over the past 10–15 years. Attention is paid to the technique for synthesizing nitride and oxynitride compounds and for the production of ceramic construction materi…
The size of colloidal quantum dot (CQD) materials and their surface modification by chemical ligands can change electronic properties thereby affecting device performances. In this study, direct measurement of the electronic structure within CQD thin film upon solid-state ligand exchange from oleic acid to 1,2-ethaned…
In this research, a novel method was developed to improve the super-hydrophobic stability of cotton fabrics without affecting the washing ability. The cotton fabrics were treated with hybrid photoreactive silica nanoparticles (denoted as silica-N 3 ) and hexadecyltrimethoxysilane under ultraviolet light. Silica nanopa…
Although organic-based direct conversion X-ray detectors have been developed, their photocurrent generation efficiency has been limited by recombination of excitons due to the intrinsically poor electrical properties of organic materials. In this report, we fabricated a polymer-based flexible X-ray detector and enhanc…
Solubility values of 39 sulfonamides in water, 1-octanol, and 1-hexane were determined by the isothermal saturation method. Thermophysical characteristics of fusion processes (melting points and fusion enthalpies) of the selected substances were measured by the DSC method. The impact of molecule structural modificatio…
Structural studies of EuTiO3, conducted using synchrotron x-ray powder diffraction, reveal the sensitivity of this material to defects. The presence of a single tetragonal-cubic (I4/mcm-Pm-3m) transition is confirmed. Neutron diffraction measurements show EuTiO3 to have a G-type antiferromagnetic arrangement. Examinat…
ABSTRACT Plasticized poly(lactic acid) (PLA)‐based nanocomposites filled with graphene nanoplatelets (xGnP) and containing poly(ethylene glycol) (PEG) and epoxidized palm oil (EPO) with ratio 2 : 1 (2P : 1E) as hybrid plasticizer were prepared by melt blending method. The key objective is to take advantage of plastici…
A report on the sol–gel preparation of nanosized ZnAl2O4:0.01% Cr3+ at a relatively low temperature (~80 °C) is presented. The catalyst/Zn mole fraction in the solution was varied from 0–3 during the synthesis. The x-ray diffraction (XRD) data show that the annealed samples were pure cubic crystalline structures at th…
Using molecular-dynamics simulations, we study the thermal transport properties of graphene nanomeshes (GNMs) as a function of material density, pore morphology, pore edge passivation, and the lattice arrangement of the nanomesh pores. Relations for the density dependence of the GNMs' thermal conductivity are establis…
Carbonaceous materials have long been attracting attention due to their physical and chemical properties as well as their low production costs. Among them, graphene oxide is considered to be an extremely promising material in the context of a wide spectrum of emerging technologies. However, since graphene oxide is cha…
Magnesium ferrite is a very important magnetic material due to its interesting magnetic and electrical properties and its chemical and thermal stability. Here we report on the magnetic and transport properties of epitaxial MgFe2O4 thin films grown on MgO (001) by molecular beam epitaxy. The structural properties and c…
Oxygen inhibition remains a challenge in photo‐curing technology despite the expenditure of considerable effort in developing a convenient, efficient, and low‐cost prevention method. Here, a novel strategy to prevent oxygen inhibition is presented; it is based on the self‐assembly of multifunctional nano‐photo‐initiat…
An efficient and chemoselective route for transforming BF2-BODIPYs to Et2B-BODIPYs (masking) was developed using Et2AlCl. The Et groups can be easily replaced with F atoms using BF3·Et2O in moist CH2Cl2 to regenerate the BF2-BODIPYs (demasking). The masking-demasking strategy is very useful for synthesizing functional…