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Anchoring Pt Single Atoms on Te Nanowires for Plasmon‐Enhanced Dehydrogenation of Formic Acid at Room Temperature

Lei Han、Leijie Zhang、Hong Wu 等 14 位作者2019-04-17Advanced Science

Abstract Formic acid (HCOOH), as a promising hydrogen carrier, is renewable, safe, and nontoxic. However, the catalytic dehydrogenation of HCOOH is typically conducted at elevated temperature. Here, HCOOH decomposition is successfully achieved for hydrogen production on the developed Pt single atoms modified Te nanowi…

Catalytic Processes in Materials ScienceCarbon dioxide utilization in catalysisCO2 Reduction Techniques and Catalysts

Response of solidification cellular structures in additively manufactured 316 stainless steel to heavy ion irradiation: anin situstudy

Zhongxia Shang、Cuncai Fan、Sichuang Xue 等 9 位作者2019-04-17Materials Research Letters

In-core or cladding structural materials exposed to heavy ion irradiation often suffer serious irradiation-induced damages. Introducing defect sinks can effectively mitigate irradiation-induced degradation in materials. Here, we investigated the radiation response of additively manufactured 316 austenitic stainless st…

Fusion materials and technologiesAdditive Manufacturing Materials and ProcessesNuclear Materials and Properties

A Simple Electrochemical Route to Access Amorphous Co-Ni Hydroxide for Non-enzymatic Glucose Sensing

Hongbo Li、Ling Zhang、Yiwu Mao 等 5 位作者2019-04-17Nanoscale Research Letters

Among the numerous transition metal hydroxide materials, cobalt- and nickel-based hydroxides have been extensively studied for their excellent electrochemical performances such as non-enzymatic electrochemical sensors. Binary cobalt-nickel hydroxide has received extensive attention for its exceptionally splendid elect…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

The blue emission at 2.8 eV in strontium titanate: evidence for a radiative transition of self-trapped excitons from unbound states

Miguel L. Crespillo、Joseph Graham、F. Agulló‐López 等 5 位作者2019-04-17Materials Research Letters

The origin of the blue emission in SrTiO3 has been investigated as a function of irradiation fluence, electronic excitation density, and temperature using a range of ion energies and masses. The emission clearly does not show correlation with the concentration of vacancies generated by irradiation but is greatly enhan…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Coexistence of Different Charge-Transfer Mechanisms in the Hot-Carrier Dynamics of Hybrid Plasmonic Nanomaterials

Jin Zhang、Mengxue Guan、Johannes Lischner 等 5 位作者2019-04-17Nano Letters

Hot-carrier dynamics at the interfaces of semiconductors and nanoclusters is of significant importance for photovoltaic and photocatalytic applications. Plasmon-driven charge separation processes are considered to be only dependent on the type of donor-acceptor interactions, that is, the conventional hot-electron-tran…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Regulating Intermolecular Chain Interaction of Biopolymer with Natural Polyol for Flexible, Optically Transparent and Thermally Conductive Hybrids

Marjan Alsadat Kashfipour、Nitin Mehra、Russell S. Dent 等 4 位作者2019-04-17Engineered Science

Natural polymers like cellulose are rich in hydrophilic groups those are able to form intermolecular and intramolecular hydrogen bonding interactions. The regulation of such interactions can be critical for tuning material functionality. In this work, we designed a sustainable hybrid comprising of sodium carboxymethyl…

Thermal properties of materialsSynthesis and properties of polymersAerogels and thermal insulation

Next-Generation Composite Coating System: Nanocoating

Weiwei Bao、Zhifeng Deng、Shaodan Zhang 等 5 位作者2019-04-17Frontiers in Materials

Nanocoating combine the protective properties of conventional coating system with effects on nanoscale such as high hardness, UV scattering, uniform dispersing, etc. Their facile and low-cost synthesis, together with superior protective properties and multi-functionalities, makes nanocoating attractive candidates for…

Gas Sensing Nanomaterials and SensorsConducting polymers and applicationsPolymer Nanocomposite Synthesis and Irradiation

Design Principles of p-Type Transparent Conductive Materials

Ruyue Cao、Hui‐Xiong Deng、Jun‐Wei Luo2019-04-17ACS Applied Materials & Interfaces

Transparent conductive materials (TCMs) has always been playing a significant role in electronic and photovoltaic area, due to its prominent optical and electronic properties. To render those transparent materials highly conductive, efficient n- and p- type doping is critically needed to obtain high concentration of f…

ZnO doping and propertiesPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Raman spectroscopy study of the La‐modified (Bi0.5Na0.5)0.92Ba0.08TiO3 lead‐free ceramic system

Y. Méndez-González、A. Peláiz‐Barranco、Ana Laura Curcio 等 5 位作者2019-04-17Journal of Raman Spectroscopy

Abstract A Raman spectroscopy study has been performed, at room temperature, on the (Bi0.5Na0.5)0.92Ba0.08‐3x/2LaxTiO3 lead‐free ceramic system (with x = 0, 1, 2, and 3 at.% La). The signature of the Raman spectra showed that the structural properties were noticeably affected by the La3+‐ions concentration, revealing…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Designing Metagratings via Local Periodic Approximation: From Microwaves to Infrared

Vladislav Popov、Marina Yakovleva、Fabrice Boust 等 6 位作者2019-04-17Physical Review Applied

Metamaterial-inspired diffraction gratings, or $m\phantom{\rule{0}{0ex}}e\phantom{\rule{0}{0ex}}t\phantom{\rule{0}{0ex}}a\phantom{\rule{0}{0ex}}g\phantom{\rule{0}{0ex}}r\phantom{\rule{0}{0ex}}a\phantom{\rule{0}{0ex}}t\phantom{\rule{0}{0ex}}i\phantom{\rule{0}{0ex}}n\phantom{\rule{0}{0ex}}g\phantom{\rule{0}{0ex}}s$, hav…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Recent Advances in the Z/E Isomers of Tetraphenylethene Derivatives: Stereoselective Synthesis, AIE Mechanism, Photophysical Properties, and Application as Chemical Probes

Yujun Xie、Zhen Li2019-04-17Chemistry - An Asian Journal

Focused research on the Z/E isomers of tetraphenylethene (TPE) derivatives is scarce in comparison with the thousands of luminogens with AIE properties (AIEgens) that have been synthesized based on the TPE moiety. The similar chemical and physical properties of the Z/E isomers make them difficult to separate by using…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications

Reconfigurable step-zoom metalens without optical and mechanical compensations

Rao Fu、Zile Li、Guoxing Zheng 等 8 位作者2019-04-17Optics Express

A polarization-dependent metasurface that consists of nanobrick arrays with spatial varying dimensions in two orthogonal directions has shown independent phase control ability, which paves a new way to design a reconfigurable step-zoom lens with two different focal lengths depending on the polarization states of an in…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

Angular optical response of cellulose nanocrystal films explained by the distortion of the arrested suspension upon drying

Bruno Frka‐Petesic、Gen Kamita、Giulia Guidetti 等 4 位作者2019-04-17Physical Review Materials

Cellulose nanocrystals (CNCs) are bio-sourced chiral nanorods that can form stable colloidal suspensions able to spontaneously assemble above a critical concentration into a cholesteric liquid crystal, with a cholesteric pitch usually in the micron range. When these suspensions are dried on a substrate, solid films wi…

Liquid Crystal Research AdvancementsAdvanced Cellulose Research StudiesElectrohydrodynamics and Fluid Dynamics

The Efficiency of Biobased Carbonization Agent and Intumescent Flame Retardant on Flame Retardancy of Biopolymer Composites and Investigation of Their Melt-Spinnability

Muhammad Maqsood、Fabian Langensiepen、Gunnar Henrik Seide2019-04-17Molecules

The objective of this study is to assess the efficiency of biobased carbonization agent in intumescent formulations (IFRs) to examine the flame retardant properties of polylactic acid (PLA) composites and to investigate their melt-spinnability. We used phosphorous-based halogen free flame retardant (FR) and kraft lign…

biodegradable polymer synthesis and propertiesFlame retardant materials and propertiesPolymer Foaming and Composites

Facial Control Intramolecular Charge Transfer of Quinoid Conjugated Polymers for Efficient in Vivo NIR-II Imaging

Wansu Zhang、Ting Huang、Jiewei Li 等 10 位作者2019-04-17ACS Applied Materials & Interfaces

Low-band gap conjugated polymers with donor-acceptor (D-A) structures have emerged as second near-infrared (NIR-II) fluorescence probes for biological imaging. However, how to control the intramolecular charge transfer (ICT) to maintain the low band gap and improve the NIR-II fluorescence intensity is an urgent issue.…

Conducting polymers and applicationsOptical Imaging and Spectroscopy TechniquesLuminescence and Fluorescent Materials

Highly Oxidized Graphene Quantum Dots from Coal as Efficient Antioxidants

Christian Nilewski、Kimberly Mendoza、Almaz S. Jalilov 等 17 位作者2019-04-17ACS Applied Materials & Interfaces

Graphene quantum dots (GQDs) have recently been employed in various fields including medicine as antioxidants, primarily because of favorable biocompatibility in comparison to common inorganic quantum dots, although the structural features that lead to the biological activities of GQDs are poorly understood. Here, we…

Electrochemical sensors and biosensorsCarbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

nMgO-incorporated PLLA bone scaffolds: Enhanced crystallinity and neutralized acidic products

Cijun Shuai、Jun Zan、Fangwei Qi 等 7 位作者2019-04-17Materials & Design

Poly‑l‑lactic acid (PLLA) is a promising bone repair material because of its good biocompatibility and natural degradability. Nevertheless, the poor mechanical properties and local inflammatory response limits its further application in bone repair. In this research, nano magnesium oxide (nMgO) was incorporated into P…

Bone Tissue Engineering MaterialsMagnesium Alloys: Properties and Applicationsbiodegradable polymer synthesis and properties

Influence of Surface Charge on the Phytotoxicity, Transformation, and Translocation of CeO 2 Nanoparticles in Cucumber Plants

Mengyao Liu、Sheng Feng、Yuhui Ma 等 14 位作者2019-04-17ACS Applied Materials & Interfaces

The physiochemical properties of nanoparticles (NPs), including surface charge, will affect their uptake, transformation, translocation, and final fate in the environment. In this study, we compared the phytoxoxicity and transport behaviors of nano CeO 2 (nCeO 2 ) functionalized with positively charged (Cs-nCeO 2 ) an…

Nanoparticles: synthesis and applicationsCarbon and Quantum Dots ApplicationsAdvanced Nanomaterials in Catalysis

Temperature-responsive biometamaterials for gastrointestinal applications

Sahab Babaee、Simo Pajovic、Ameya R. Kirtane 等 13 位作者2019-04-17Science Translational Medicine

We hypothesized that ingested warm fluids could act as triggers for biomedical devices. We investigated heat dissipation throughout the upper gastrointestinal (GI) tract by administering warm (55°C) water to pigs and identified two zones in which thermal actuation could be applied: esophageal (actuation through warm w…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsAdvanced Materials and Mechanics

Decoration of Pd Nanoparticles with N and S Doped Carbon Quantum Dots as a Robust Catalyst for the Chemoselective Hydrogenation Reaction

Chunshan Lu、Qianwen Zhu、Xuejie Zhang 等 10 位作者2019-04-17ACS Sustainable Chemistry & Engineering

Achieving high selectivity is one of the major challenges for the noble metal catalysts. A strategy of decoration of Pd nanoparticles by N–S doped carbon quantum dots (N,S-CQDs) to regulate selectivity is proposed. Through adjusting the loading amounts of N,S-CQDs, high selectivity toward catalytic hydrogenation react…

Carbon and Quantum Dots ApplicationsCaching and Content DeliveryNanomaterials for catalytic reactions