Materials Literature
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Abstract In situ exsolved nanoparticles (NPs) on surfaces perform well in many catalytic applications. Herein, an emerging technique of pulsed electric current (PEC) for facilitating NPs exsolution was firstly utilized in functional materials towards tailoring structure and morphology of materials. PEC facilitated Ni…
We report an in situ synthesis of ruthenium-reduced graphene oxide (Ru-rGO) using 6 MeV electron beam assisted radiolytic reduction method and its supercapacitive behavior. X-ray diffraction (XRD), transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM) explore Ru nanoparticles o…
The incorporation of magnetic impurities into semiconductor nanocrystals with size confinement promotes enhanced spin exchange interaction between photogenerated carriers and the guest spins. This interaction stimulates new magneto-optical properties with significant advantages for emerging spin-based technologies. He…
Abstract Prussian blue analogues (Ni 3 [Fe(CN) 6 ] 2 )) derived nanocube‐like Ni(OH) 2 was grown evenly on the surface of GO via solution‐precipitation and potassium hydroxide etching process at room temperature. Due to the even dispersion of Ni(OH) 2 nancubes, the obtained sample Ni(OH) 2 /GO exhibits a maximum speci…
Abstract A series of highly active and selective CuCeOx catalysts was prepared via appropriate tuning of the parameters (concentration, temperature) of a citrates‐hydrothermal method. The obtained catalysts were characterized by various physicochemical techniques such as (in‐situ) X‐ray diffraction (XRD), N2 adsorptio…
Abstract Polyelectrolyte complexes (PECs) prepared by solution mixing of cationic poly(diallyldimethylammonium chloride) and anionic poly(sodium 4‐styrene sulfonate) with various NaCl content are processed into films. Salt‐free (SF‐PEC) membranes are produced by rinsing the PEC in water overnight. The main finding of…
In air-jet weaving looms, the main nozzle pulls the yarn from the prewinder by means of a high velocity air flow. The flexible yarn is excited by the flow and exhibits high amplitude oscillations. The motion of the yarn is important for the reliability and the attainable speed of the insertion. Fluid-structure interac…
Room-temperature multiferroism in polycrystalline antiferromagnetic Fe perovskites is reported for the first time. In the perovskite-type oxides RE 1.2 Ba 1.2 Ca 0.6 Fe 3 O 8 (RE = Gd, Tb), the interplay of layered ordering of Gd(Tb), Ba, and Ca atoms with the ordering of FeO 4 -tetrahedra (T) and FeO 6 -octahedra (O)…
The transition between the insulator state and the band-conducting state is investigated by means of cyclic voltammetry in cobalt oxide porous film electrodes in phosphate-buffered solutions. It is shown that a proton-coupled faradaic oxidative process starting in the insulator region eventually builds an ohmic conduc…
Recently, comprehensive studies on positively charged manganese porphyrins show that these compounds, known for their superoxide dismutase (SOD) mimetic ability, can be equally reactive toward a broad array of other redox active molecules of biological relevance present in a cellular milieu. In this context, the exami…
In this work, we investigated the edge doping effect to graphene plasmon resonances in graphene nanoribbons (GNRs), which is known to affect the electronic doping of GNRs but has not been systematically studied. We found the Fermi levels, which reflect that the sheet charge carrier densities, extracted from the graphe…
Abstract Reduction‐responsive drug delivery systems have recently gained intense attention in intracellular delivery of anticancer drugs. In this study, we developed a PEGylated polypeptide, poly(ethylene glycol)‐ block ‐poly(ϵ‐propargyloxycarbonyl‐ l ‐lysine) (PEG 113 ‐ b ‐PPAL), as a novel clickable substrate for co…
ABSTRACT Improved dispersion of graphene oxide (GO) in the epoxy resin, as nanofiller, requires surface modification. Hence, functionalization of GO with small silane (GONSi) and bulky silane moieties (GOSi) has been carried out. Structural confirmation analysis of the prepared GO and modified forms have been performe…
The impact of hydroxypropylsulfonation/caproylation on the adhesion of cornstarch to polylactic acid (PLA) fibers was investigated for ameliorating the applications such as PLA sizing. The hydroxypropylsulfonated and caproylated cornstarch (HCS) samples with different degrees of substitution (DS) were synthesized by a…
Abstract The discharge characteristics of SF 6 dependent on gas pressure under extremely inhomogeneous electric fields are strongly nonlinear and must be carefully considered when optimizing gas-insulated equipment insulation design and defect detection. The main aim of this study was to determine the relationship bet…
The mucilaginous viscin tissue within mistletoe berries possesses an extraordinary ability to be rapidly processed under ambient conditions into stiff cellulosic fibers (>14 GPa) through simple mechanical drawing. This rapid and extreme transformation process is hydration-dependent and involves an astonishing >200-fol…
In this study, the diameter of polyvinyl butyral nanofibers was modeled using response surface method based on three variables, at three levels of central composite design and particle swarm optimization-least squares support vector machine. Under optimal conditions, the measured mean diameter of the nanofibers was 17…
Abstract The design of efficient graphene-silicon (GSi) Schottky junction photodetectors requires detailed understanding of the spatial origin of the photoresponse. Scanning-photocurrent-microscopy (SPM) studies have been carried out in the visible wavelengths regions only, in which the response due to silicon is domi…
A theoretical model based on the coupled mode theory is presented to calculate the absorption in a graphene embedded 1D guided-mode-resonance (GMR) structure that does not require a back reflector. The optimized graphene-GMR structure can absorb up to 70% of the incident light which far exceeds the already reported re…
Abstract Different nanostructured/composite materials are considered as a promising electrode material which enhances the electrochemical activity of the individual substances. V 2 O 5 /Mn 3 O 4 composite material is synthesized using hydrothermal method at different reaction time ranging from 12 h to 24 h. Obviously,…