Materials Literature
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Our work focuses on the study of the adsorption of methylene blue (MB) on adsorbents based on zeolite HUSY and (γAl2O3-SiO2). To optimize the process of removing MB onto Ni/Co USY, different parameters were studied such as contact time, initial pH, initial dye concentration, zero charge’s point, and adsorbent dosage.…
This chapter aims to two-fold: to reflect on the development of a “new” description of the environment—the triad of medium, substances, and surfaces, and to highlight its significance to the study of perception and behavior. The ability to distinguish among the different substances is extremely important to us, and we…
Prolonged circulation time is beneficial for the accumulation of nanoparticles in tumors due to the enhanced permeability and retention (EPR) effect. However, the exogenous nanoparticles tend to be recognized and quickly eliminated by the reticuloendothelial system. Here, we developed autologous erythrocyte membrane c…
Abstract High‐pressure structural evolution of CeOCl, a lanthanide oxychloride, was investigated by in situ high‐pressure Raman scattering and first‐principles calculations. We report the novel observation of discontinuities in Raman wavenumber at the pressure of approximately 7 GPa, which are related to an isostructu…
The temperature dependences of the peak positions in pair distribution functions G ( r ) of pure metallic zinc (Zn) and indium (In) liquids have been studied using high-energy X-ray diffraction together with ab initio molecular dynamic simulations. It has been demonstrated that the first peak positions in G ( r ) of b…
We have studied the evaporative crystallization of dibenzoylmethanato boron difluoride complex (BF2DBM) using the quartz crystal microbalance (QCM) technique and based on fluorescence changes. The optical and mechanical properties of the liquid-like cluster state were observed during the evaporative crystallization pr…
The development of DPPP 2– (H 2 DPPP = 2,5-dihydro-3,6-di-2-pyridylpyrrolo(3,4- c )pyrrole-1,4-dione) bridged ( NN∩NN ) diruthenium complexes [(Cym)(X)Ru II (μ-dppp)Ru II (X)(Cym)] (Cym = para -cymene and X = OTf – ( 1 ), SCN – ( 2 ), N 3 – ( 3 ), NO 2 – ( 4 )) are considered as the probable molecular clips for the co…
Currently, methods of water purification and aqueous solutions leading to effective reduction of introduced chemical compounds into water purification systems have become the subject of research. Physical methods have become an alternative, because by subjecting water and aqueous solutions to UV (ultraviolet) radiatio…
Abstract Cancer phototherapy (PT) including photodynamic therapy (PDT) and photothermal therapy (PTT) has attracted extensive interest due to its non-invasive and region-specific nature. In order to enhance the efficacy, we have fabricated various nanocomposites consisting of a photosensitizer (chlorin e 6 (Ce6), pheo…
We analyzed 53 historical textile samples from a collection of caftans and brocades dating between the sixteenth and nineteenth century in the Topkapi Palace Museum (TPM) by scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX). Data were collected on the type, dimensions, elemental composit…
Surface roughness is one of the most common criteria indicating the surface finish of the part, which depends on various factors including cutting parameters, geometry of the tool, and cutting fluid. One of the goals of using cutting fluids in machining processes is to achieve improved surface finish. In addition to h…
Azulene is a non-alternant non-benzenoid aromatic system, and in turn, it possesses unusual photophysical properties. Azulene-based conjugated systems have received increasing interest in recent years as optoelectronic materials. Despite the routes available for the preparation of substituted azulene derivatives, ther…
Transition-metal nanoparticles (NPs) catalysts supported on solid material represent one of the most important subjects in organic synthesis due to their reliable carbon–carbon or carbon–heteroatom bond-forming cross-coupling reactions. Therefore methodologically and conceptually novel immobilization methods for nonpr…
An acceleration of continuous time quantum Monte Carlo (CTQMC) methods is a potentially interesting branch of work as they are matchless as impurity solvers of a dynamical mean field theory (DMFT) approach for the description of strongly correlated systems. The inversion of the $k\ifmmode\times\else\texttimes\fi{}k$ m…
As the role of polymers in undergraduate chemistry curricula continues to expand, opportunities will emerge for adopting experiments involving smart materials (i.e., materials that change properties in response to external stimuli). Slime demonstrations are routinely carried out with poly(vinyl alcohol) (i.e., PVA) hy…
The “comonomer effect” is an intriguing kinetic phenomenon in olefin copolymerization that still remains without a detailed explanation. It typically relates to the rate of enhancement undergone in ethylene and propene catalytic polymerization just by adding small fractions of an alpha-olefin. The difficulty lies in t…
A series of Mn 2 x In 2(1– x ) S 3 ( x < 0.5) nanoflower solid solutions (NSS) were synthesized by a simple one-step hydrothermal method using l -cysteine as S source and chelating reagent. The Mn 2 x In 2(1– x ) S 3 NSS exhibit excellent hydrogen evolution performance compared with pure In 2 S 3 . In particular, the…
To ensure the safety of passenger carriages by rail ferries, mathematical modeling of dynamic loading is performed. The accelerations are determined as components of the dynamic load acting on the body of a passenger car. This takes into account the actual hydrometeorological characteristics of the water area of the r…
Gelatin is a protein obtained from animal collagen tissue found in warts, bones, and connective tissue that is hydrolyzed acidic or basic. The purpose of this study was to determine the different effects of HCl and acetic acid and different extraction temperatures on the production of local rabbit skin gelatin so that…
The structure, electronic properties, and aromaticity of the para-substituted platinabenzenes were illustrated by applying the hybrid density functional MPW1PW91 theory. The electron donor groups (EDG) and electron withdraw groups (EWG) effects on geometry, frontier orbital energies, reactivity indices and aromaticity…