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Photofunctional Nanomodulators for Bioexcitation

Eijiro Miyako、Julie Russier、Matteo Mauro 等 11 位作者2014-10-24Angewandte Chemie International Edition

A single organism comprises diverse types of cells. To acquire a detailed understanding of the biological functions of each cell, comprehensive control and analysis of homeostatic processes at the single-cell level are required. In this study, we develop a new type of light-driven nanomodulator comprising dye-function…

Quantum Dots Synthesis And PropertiesNanoplatforms for cancer theranosticsLaser-Ablation Synthesis of Nanoparticles

Vertically aligned nanocomposite La 0.8 Sr 0.2 CoO 3 /(La 0.5 Sr 0.5 ) 2 CoO 4 cathodes – electronic structure, surface chemistry and oxygen reduction kinetics

Wen Ma、Jae Jin Kim、Nikolai Tsvetkov 等 10 位作者2014-10-24Journal of Materials Chemistry A

A vertically aligned nanocomposite cathode, made of La <sub>0.8</sub> Sr <sub>0.2</sub> CoO <sub>3</sub> /(La <sub>0.5</sub> Sr <sub>0.5</sub> ) <sub>2</sub> CoO <sub>4</sub> , increases oxygen reduction kinetics by 10-fold and has better surface stability compared to its single phase constituents at 320–400 °C.

Advancements in Solid Oxide Fuel CellsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Enhancement of Osteogenesis and Biodegradation Control by Brushite Coating on Mg–Nd–Zn–Zr Alloy for Mandibular Bone Repair

Xingmin Guan、Meiping Xiong、Feiyue Zeng 等 12 位作者2014-10-24ACS Applied Materials & Interfaces

To diminish incongruity between bone regeneration and biodegradation of implant magnesium alloy applied for mandibular bone repair, a brushite coating was deposited on a matrix of a Mg-Nd-Zn-Zr (hereafter, denoted as JDBM) alloy to control the degradation rate of the implant and enhance osteogenesis of the mandible bo…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

Self-Assembly of Tetraphenylethene-Based [2]Catenane Driven by Acid–Base-Controllable Molecular Switching and Its Enabled Aggregation-Induced Emission

Mandapati V. Ramakrishnam Raju、Hong‐Cheu Lin2014-10-24Organic Letters

A novel [2]catenane 2-C based on the tetraphenylethene (TPE) and orthogonal H-bonded cleft was successfully constructed. VT-NMR and TEM measurements demonstrate that 2-C could be self-assembled to induce an enabled aggregation-induced emission (AIE) in aqueous solution and solid state owing to its TPE unit as well as…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Aliphatic Organoimido Derivatives of Polyoxometalates Containing a Bioactive Ligand

Shan She、Shengtai Bian、Jian Hao 等 8 位作者2014-10-24Chemistry - A European Journal

A series of aliphatic organoimido derivatives of hexamolybdate based on amantadine, namely (nBu4 N)2 [Mo6 O18 (NC10 H15 )] (1), (nBu4 N)2 {cis-[Mo6 O17 (NC10 H15 )2 ]} (2), (nBu4 N)2 {trans-[Mo6 O17 (NC10 H15 )2 ]} (3), and (nBu4 N)2 [Mo6 O16 (NC10 H15 )3 ] (4), was synthesized in reasonable yield by dehydration w…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis

Architectural Design of Heterogeneous Metallic Nanocrystals—Principles and Processes

Yue Yu、Qingbo Zhang、Qiaofeng Yao 等 5 位作者2014-10-24Accounts of Chemical Research

CONSPECTUS: Heterogeneous metal nanocrystals (HMNCs) are a natural extension of simple metal nanocrystals (NCs), but as a research topic, they have been much less explored until recently. HMNCs are formed by integrating metal NCs of different compositions into a common entity, similar to the way atoms are bonded to fo…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsNanocluster Synthesis and Applications

Full-dispersion Monte Carlo simulation of phonon transport in micron-sized graphene nanoribbons

S. Mei、Leon Maurer、Zlatan Akšamija 等 4 位作者2014-10-24Journal of Applied Physics

We simulate phonon transport in suspended graphene nanoribbons (GNRs) with real-space edges and experimentally relevant widths and lengths (from submicron to hundreds of microns). The full-dispersion phonon Monte Carlo simulation technique, which we describe in detail, involves a stochastic solution to the phonon Bolt…

Graphene research and applicationsAdvanced Thermoelectric Materials and DevicesThermal properties of materials

A facile and general fabrication method for organic silica hollow spheres and their excellent adsorption properties for heavy metal ions

Jing Hu、Xuge Wang、Liqin Liu 等 4 位作者2014-10-24Journal of Materials Chemistry A

This paper presents a facile and general method for fabrication of organic silica hollow spheres by co-hydrolysis and condensation reactions of TEOS and other silane coupling agents under the catalysis of ammonia. Silane coupling agents were first pre-hydrolyzed to form micelles. When TEOS was added, a sol–gel reactio…

Mesoporous Materials and CatalysisDiatoms and Algae ResearchCovalent Organic Framework Applications

A mechanistic model for drug release in PLGA biodegradable stent coatings coupled with polymer degradation and erosion

Xiaoxiang Zhu、Richard D. Braatz2014-10-24Journal of Biomedical Materials Research Part A

Biodegradable poly(d,l-lactic-co-glycolic acid) (PLGA) coating for applications in drug-eluting stents has been receiving increasing interest as a result of its unique properties compared with biodurable polymers in delivering drug for reducing stents-related side effects. In this work, a mathematical model for descri…

Nanoparticle-Based Drug DeliveryElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Influence of Cu Vacancy on Knit Coir Mat Structured CuS as Counter Electrode for Quantum Dot Sensitized Solar Cells

A. Dennyson Savariraj、Kodakkal Kannan Viswanathan、Kandasamy Prabakar2014-10-24ACS Applied Materials & Interfaces

Knit-coir-mat-like structured CuS thin films prepared by chemical bath deposition with different time duration were used as counter electrode in qunatum dot sensitized solar cells. The film deposited at 4 h exhibited better electrochemical and photovoltaic performance with JSC, VOC, and FF values of 14.584 mA cm(-2),…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Assembling and Redispersibility of Rice Straw Nanocellulose: Effect of tert-Butanol

Feng Jiang、You‐Lo Hsieh2014-10-24ACS Applied Materials & Interfaces

Self-assembling of sulfuric-acid-hydrolyzed cellulose nanocrystals (CNCs, 6.4 nm wide) and TEMPO oxidized cellulose nanofibrils (CNFs, 2.1 nm wide) from aqueous suspensions was induced by rapid freezing (-196 °C, 10 min) and slow lyophilization (-50 °C, 0.05 mbar, 2 days). The assembled structures contain submicron (2…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesPolysaccharides and Plant Cell Walls

Multicolor Electrochromism Showing Three Primary Color States (Cyan–Magenta–Yellow) Based on Size- and Shape-Controlled Silver Nanoparticles

Ayako Tsuboi、Kazuki Nakamura、Norihisa Kobayashi2014-10-24Chemistry of Materials

Inorganic electrochromic (EC) materials have various advantages for use in display devices. We demonstrate here a new multicolor EC device based on an electrochemical silver deposition mechanism. Ag nanoparticles electrochemically deposited on an electrode exhibit a wide variety of optical states based on their locali…

ZnO doping and propertiesPhotonic Crystals and ApplicationsTransition Metal Oxide Nanomaterials

Demystifying umklapp vs normal scattering in lattice thermal conductivity

A. A. Maznev、Oliver B. Wright2014-10-24American Journal of Physics

We discuss the textbook presentation of the concept of umklapp vs normal phonon-phonon scattering processes in the context of lattice thermal conductivity. A simplistic picture, in which the “momentum conservation” in a normal process leads to the conservation of the heat flux, is only valid within the single-velocity…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Expansion and Ionic Conductivity

A facile approach to fabricate a UV/heat dual-responsive triple shape memory polymer

You Wu、Junyan Hu、C. Zhang 等 6 位作者2014-10-24Journal of Materials Chemistry A

In the present work, a facile approach was employed to fabricate a UV/heat dual-responsive triple shape memory polymer (SMP) by simply mixing Zn(Mebip) <sub>2</sub> (NTf <sub>2</sub> ) <sub>2</sub> , a metallosupramolecular unit formed by coordinating 2,6-bis( <italic>N</italic> -methyl-benzimidazolyl)-pyridine (Mebip…

Polymer composites and self-healingSynthetic Organic Chemistry MethodsPhotochromic and Fluorescence Chemistry

Breathing Pores on Command: Redox‐Responsive Spongy Membranes from Poly(ferrocenylsilane)s

Kaihuan Zhang、Xueling Feng、Xiaofeng Sui 等 5 位作者2014-10-24Angewandte Chemie International Edition

Redox-responsive porous membranes can be readily formed by electrostatic complexation between redox active poly(ferrocenylsilane) PFS-based poly(ionic liquid)s and organic acids. Redox-induced changes on this membrane demonstrated reversible switching between more open and more closed porous structures. By taking adva…

Ionic liquids properties and applicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Enhanced Room-Temperature Ferromagnetism on Co-Doped CeO2 Nanoparticles: Mechanism and Electronic and Optical Properties

Kugalur Shanmugam Ranjith、Padmanapan Saravanan、Shih-Hsien Chen 等 8 位作者2014-10-24The Journal of Physical Chemistry C

The present study reports the effect of Co doping on the structural, optical, magnetic, and electronic properties of CeO 2 nanoparticles (NPs) synthesized by a simple low-temperature co-precipitation method. Co doping was introduced by adding CoCl 3 with different mole percentages (0%, 2%, 4%, and 6%) to cerium nitrat…

ZnO doping and propertiesCatalytic Processes in Materials ScienceGeochemistry and Elemental Analysis

Novel λ3‐Iodane‐Based Functionalization of Synthetic Carbon Allotropes (SCAs)—Common Concepts and Quantification of the Degree of Addition

Ferdinand Hof、Ricarda A. Schäfer、Cornelius Weiß 等 5 位作者2014-10-24Chemistry - A European Journal

The covalent functionalization of carbon allotropes represents a main topic in the growing field of nano materials. However, the development of functional architectures is impeded by the intrinsic polydispersibility of the respective starting material, the unequivocal characterization of the introduced functional moie…

Porphyrin and Phthalocyanine ChemistryAnalytical Chemistry and SensorsOxidative Organic Chemistry Reactions

Investigation of the crystal and magnetic structures of the trigonal multiferroic iron-boracite Fe3B7O13(OH)

Gwilherm Nénert、Ippei Nomoto、Hirohiko Sato2014-10-24arXiv

We have investigated the crystal and magnetic structures of the trigonal iron-boracite Fe3B7O13X with X = OH by neutron diffraction. Neutron diffraction enables us to locate the hydrogen atom of the hydroxyl group and determine the magnetic ground state of this member of the multiferroic boracite family. No evidence w…

Materials ScienceStrongly Correlated Electrons

Chemical Bonding of Partially Fluorinated Graphene

Si Zhou、Sonam D. Sherpa、Dennis W. Hess 等 4 位作者2014-10-24The Journal of Physical Chemistry C

Understanding the interactions of graphene and chemical additives is crucial to achieve control over chemically modified graphene materials. Here, density functional theory and experiments are used to elucidate the chemical bonding of partially fluorinated graphene. This material includes F–C bonds whose ionicity vari…

Graphene research and applicationsFiber-reinforced polymer compositesInorganic Fluorides and Related Compounds

Phonon-Mediated Mid-Infrared Photoresponse of Graphene

M. Badioli、A. Woessner、K. J. Tielrooij 等 8 位作者2014-10-24Nano Letters

The photoresponse of graphene at mid-infrared frequencies is of high technological interest and is governed by fundamentally different underlying physics than the photoresponse at visible frequencies, as the energy of the photons and substrate phonons involved have comparable energies. Here, we perform a spectrally re…

Graphene research and applicationsThermal properties of materialsThermal Radiation and Cooling Technologies