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Photoluminescence Properties of Cu+ Centers in MgS, CaS, SrS and BrS

Nobuhiko Yamashita1991-12-01Japanese Journal of Applied Physics

The detailed emission and excitation spectra and the temperature dependence of the excitation efficiency are obtained for MgS:Cu + , CaS:Cu + , SrS:Cu + and BaS:Cu + at various temperatures between 16 and 293 K. In the excitation spectra of all the powder phosphors, two bands assigned to the intraionic transitions in…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Order parameter saturation at low temperatures -numerical results for displacive and O/D systems

Ekhard K. H. Salje、B. Wruck、S. Marais1991-12-01Ferroelectrics

The temperature dependence of the order parameters in quartz, NaNO3, Mo8O23 show saturation behaviour with characteristic saturation temperatures θ. The quantitative behaviour is in good agreement with the predictions of Salje, Wruck and Thomas (1991) for both displacive (eg. quartz) and order/disorder systems (eg. Na…

Material Dynamics and PropertiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

An experimental study of the interaction of hydrogen with the Mg(0001) surface

Phillip Sprunger、E. W. Plummer1991-12-01Chemical Physics Letters

The interaction of atomic and molecular hydrogen with the (0001) surface of magnesium has been studied using EELS, TDS, work-function measurements, and core-level spectroscopy. No evidence for molecular or dissociative adsorption of H2 is observed at the substrate temperature investigated (>110 K, atomic hydrogen is b…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

Three-dimensional structure of the Escherichia coli phosphocarrier protein IIIglc.

David K. Worthylake、N D Meadow、Saul Roseman 等 6 位作者1991-12-01Proceedings of the National Academy of Sciences

The crystal structure of a proteolytically modified form of the Escherichia coli phosphocarrier and signal transducing protein IIIglc has been determined by multiple isomorphous and molecular replacement. The model has been refined to an R-factor of 0.166 for data between 6- and 2.1-A resolution with an rms deviation…

Protein Structure and DynamicsBacterial Genetics and BiotechnologyEnzyme Structure and Function

Smectic Ordering in Block-Copolymer Melts

A. N. Semenov1991-12-01Molecular crystals and liquid crystals

Microscopic theory of smectic ordering in melts of rod-coil copolymers is proposed. It is shown that a second-order phase transition nematic-smectic A or a first-order transition nematic-smectic C may occur in the system as Flory's parameter of incompatibility of the blocks, x is increased. A number of phase transitio…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsAdvanced Materials and Mechanics

New Molecular Superconductor, β-[(CH3)4N][Pd(dmit)2]2

Akiko Kobayashi、Hayao Kobayashi、Akihito Miyamoto 等 6 位作者1991-12-01Chemistry Letters

Abstract High-pressure resistivity studies on [(CH3)4N][Pd(dmit)2]2 have revealed the system to be a new molecular superconductor. The superconducting transition has been observed above 6 kbar. The mid-point transition temperature T is 6.2 K at 6.5 kbar. The crystal has the structure almost isomorphous to the high-pre…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesInorganic Chemistry and Materials

Fluorinated Liquid Crystals for Active Matrix Displays

Yoshihiro Gotō、T. Ogawa、S. Sawada 等 4 位作者1991-12-01Molecular crystals and liquid crystals

Eight types of two- and three-ring liquid-crystalline compounds each possessing a 3,4-difluorophenyl substituent were synthesized. Their liquid-crystalline mixtures were such as to make them useful for active matrix displays, such as TFT (thin-film-transistor) and MIM (metal-insuiator-metal) systems. They have high st…

Liquid Crystal Research Advancements

Photoproduction of gold colloids and films

R. Krasnansky、SHIRO YAMAMURA、J. K. Thomas 等 4 位作者1991-12-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoproduction of gold colloids and filmsR. Krasnansky, S. Yamamura, J. K. Thomas, and R. DellaguardiaCite this: Langmuir 1991, 7, 12, 2881–2886Publication Date (Print):December 1, 1991Publication History Published online1 May 2002Published inissue 1 December 1991https://do…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and Applications

Elektrochemische Korrosionsuntersuchungen an gasoxinitriertem und salzbadnitrocarburiertem Stahl in Abhängigkeit vom Aufbau der Nitrierschicht

U. Ebersbach、Semiramis Friedrich、T. Nghia 等 4 位作者1991-12-01HTM Journal of Heat Treatment and Materials

Article Elektrochemische Korrosionsuntersuchungen an gasoxinitriertem und salzbadnitrocarburiertem Stahl in Abhängigkeit vom Aufbau der Nitrierschicht was published on December 1, 1991 in the journal HTM Journal of Heat Treatment and Materials (volume 46, issue 6).

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Effect of acid concentration and other reaction parameters on epoxidation of natural rubber latex

Sanjoy Roy、Bramha Gupta、Binoy Maiti1991-12-01Industrial & Engineering Chemistry Research

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of acid concentration and other reaction parameters on epoxidation of natural rubber latexSanjoy Roy, B. R. Gupta, and B. R. MaitiCite this: Ind. Eng. Chem. Res. 1991, 30, 12, 2573–2576Publication Date (Print):December 1, 1991Publication History Published online1 May…

Polymer Nanocomposites and PropertiesLignin and Wood ChemistryPlant biochemistry and biosynthesis

Dynamics in concentrated polymer solutions by polarized Rayleigh–Brillouin scattering and dynamic light scattering

Wyn Brown、Robert M. Johnsen、Cestmir Konak 等 4 位作者1991-12-01The Journal of Chemical Physics

Solutions of polystyrene in toluene in the concentration range 0.1–1.0 g/ml have been examined using polarized Rayleigh–Brillouin scattering and dynamic light scattering. The purpose was to extend measurements to the hitherto little studied interval between semidilute solutions and the bulk polymer. The Brillouin shif…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical StudiesAdvanced Physical and Chemical Molecular Interactions

Mixed methyl-(2,4-dinitrophenyl)-aminopropanoate: 2-methyl-4-nitroaniline crystal−a new nonlinear optical material

S. M. Rao、A. K. Batra、Ratan Lal 等 7 位作者1991-12-01Journal of Applied Physics

Single crystals of mixed methyl-(2,4-dinitrophenyl)-aminopropanoate (MAP): 2-methyl-4-nitroaniline (MNA) have been grown from solution using a 40:60 mixture of ethanol and ethyl acetate. Formation of an equimolar complex is confirmed by x-ray diffraction studies. The complex crystallizes in the monoclinic space group…

Crystal structures of chemical compoundsNonlinear Optical Materials ResearchChemical synthesis and pharmacological studies

Two variants of wild emmer (Triticum dicoccoides) native to Israel: morphology and distribution

Helena Poyarkova、Z. K. Gerechter‐Amitai、A. Genizi1991-12-01Canadian Journal of Botany

A detailed morphological comparison between the narrow-spiked and the wide-spiked variants of Triticum dicoccoides growing in Israel revealed significant differences that became evident in almost all organs, both vegetative and reproductive, in juvenile and adult stages, on macro- and micro-morphological levels. Pheno…

Aquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae ResearchBiocrusts and Microbial Ecology

Binary Mesogenic Systems Comprised of Ester Mesogens and Non-Mesogens

R. A. Vora、Sadhana Rajput1991-12-01Molecular crystals and liquid crystals

With a view to evaluate the effect of non-mesogen or mesogen on the binary systems comprised of a nematogon or a polymesomorph, the present study was undertaken where the compounds have general structure (I): The binary systems are selected with variation in R and R′ (I). The binary phase diagrams have very interestin…

Liquid Crystal Research AdvancementsSurfactants and Colloidal Systems

High‐Temperature‐Post‐Exposure Bake Process (HIT‐PEB) for Base‐Developable Polyimides Consisting of Diazonaphthoquinones and Polyamic Acids

Shuzi Hayase、Kei Takano、Yukihiro Mikogami 等 4 位作者1991-12-01Journal of The Electrochemical Society

A process, which makes it possible for polyimide resists to be developed using dilute base aqueous solutions, is reported. The process contains soft bake, UV exposure, post exposure bake and development with basic aqueous solutions. The post exposure bake at a temperature range from 140 to 160°C, which is higher than…

Advancements in Photolithography TechniquesSynthesis and properties of polymersNanofabrication and Lithography Techniques

The K258R mutant of aspartate aminotransferase stabilizes the quinonoid intermediate.

Michael D. Toney、Jack F. Kirsch1991-12-01Journal of Biological Chemistry

Lys-258 of aspartate aminotransferase forms a Schiff base with pyridoxal phosphate and is responsible for catalysis of the 1,3-prototropic shift central to the transamination reaction sequence. Substitution of arginine for Lys-258 stabilizes the otherwise elusive quinonoid intermediate, as assessed by the long wavelen…

RNA and protein synthesis mechanismsEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Cluster synthesis. 36. New platinum-ruthenium and platinum-osmium carbonyl cluster complexes from the reactions of the complexes Pt2M4(CO)18 (M = ruthenium, osmium) with cycloocta-1,5-diene in the presence of UV irradiation

Richard D. Adams、Michael S. Alexander、Isam M. Arafa 等 4 位作者1991-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCluster synthesis. 36. New platinum-ruthenium and platinum-osmium carbonyl cluster complexes from the reactions of the complexes Pt2M4(CO)18 (M = ruthenium, osmium) with cycloocta-1,5-diene in the presence of UV irradiationRichard D. Adams, Michael S. Alexander, Isam Arafa,…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesNanocluster Synthesis and Applications

Generalization of Bruggeman’s unsymmetrical effective-medium theory to a three-component composite

A. M. Jayannavar、N. Kumar1991-12-01Physical review. B, Condensed matter

A unified treatment of effective-medium theory for the dielectric constant and conductivity of a macroscopically inhomogeneous medium based on renormalization is presented. Our expression recovers in appropriate limits Bruggeman's unsymmetrical as well as symmetrical results. In addition, the same expression also desc…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatics and Colloid Interactions

Refinement of the Structure of MnSi by Powder Diffraction

Jens‐Erik Jørgensen、Svend Erik Rasmussen1991-12-01Powder Diffraction

Abstract Crystal data and results of structure refinements for MnSi are reported. The material is cubic, P2 1 3, with a = 4.5603(2) Å, V d = 94.84(1) Å 3 , Z = 4, D x = 5.815 Mg/m 3 . Intensity data were obtained from a Stoe transmission type diffractometer equipped with a position sensitive detector. CuKα 1 radiation…

Magnetic Properties and Synthesis of FerritesCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Synthesis and polymerization of N-(4-vinylphenyl)maleimide

Tokio Hagiwara、Iwao Suzuki、Kazushi Takeuchi 等 5 位作者1991-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and polymerization of N-(4-vinylphenyl)maleimideTokio Hagiwara, Iwao Suzuki, Kazushi Takeuchi, Hiroshi Hamana, and Tadashi NaritaCite this: Macromolecules 1991, 24, 26, 6856–6858Publication Date (Print):December 1, 1991Publication History Published online1 May 2002…

Photochemistry and Electron Transfer StudiesSynthesis and Properties of Aromatic CompoundsSynthesis and properties of polymers