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Toward the crystal structure of nagyagite, [Pb(Pb,Sb)S 2 ][(Au,Te)]

H. Effenberger、W. H. Paar、Dan Topa 等 5 位作者1999-04-01American Mineralogist

Synthetic nagyagite was grown from a melt as part of a search for materials with high-temperature superconductivity. Electron microprobe analyses of synthetic nagyagite and of nagyagite from the type locality Nagyág, Transylvania (now Săcărîmb, Romania) agree with data from literature. The crystal chemical formula [Pb…

Crystal Structures and PropertiesAdvanced Condensed Matter PhysicsIron-based superconductors research

Spontaneous graphitization and thermal disintegration of diamond at T>2000 K

V. D. Andreev1999-04-01Physics of the Solid State

A theoretical description of the mechanism and kinetics of the graphitization of diamond taking place with two sharply differing activation energies and accompanied by explosive disintegration of the graphitized diamond crystals is obtained in the approximation of a model interatomic interaction potential.

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchAdvanced Physical and Chemical Molecular Interactions

Copper/Benzocyclobutene Interconnects for Sub‐100 nm Integrated Circuit Technology: Elimination of High‐Resistivity Metallic Liners and High‐Dielectric Constant Polish Stops

J. Neirynck、R.J. Gutmann、S. P. Murarka1999-04-01Journal of The Electrochemical Society

Copper/Benzocyclobutene Interconnects for Sub‐100 nm Integrated Circuit Technology: Elimination of High‐Resistivity Metallic Liners and High‐Dielectric Constant Polish Stops, Neirynck, J. M., Gutmann, R. J., Murarka, S. P.

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

Chemical Segregation in Vertical Bridgman Growth of GaInSb Alloys

C. Barat、Thierry Duffar、P. Dussere 等 4 位作者1999-04-01Crystal Research and Technology

A set of experiments on the solidification of Ga 1-x In x Sb alloys with a large variation of the sample diameter (from 1mm to 10mm), of the growth rate (from 0.7 to 7 μm/s) and of the concentration (from x=0.01 to x= 0.1) is described. The associated radial and longitudinal segregation of the In have been analysed by…

Theoretical and Computational PhysicsSolidification and crystal growth phenomenananoparticles nucleation surface interactions

Relationship between Succinate Transport and Production of Extracellular Poly(3-Hydroxybutyrate) Depolymerase in Pseudomonas lemoignei

Kay Terpe、Kirsten Kerkhoff、Elena Pluta 等 4 位作者1999-04-01Applied and Environmental Microbiology

The relationship between extracellular poly(3-hydroxybutyrate) (PHB) depolymerase synthesis and the unusual properties of a succinate uptake system was investigated in Pseudomonas lemoignei. Growth on and uptake of succinate were highly pH dependent, with optima at pH 5.6. Above pH 7, growth on and uptake of succinate…

biodegradable polymer synthesis and propertiesMicrobial Metabolic Engineering and BioproductionAmino Acid Enzymes and Metabolism

Sintering of calcium aluminate mixes

Vakil Singh1999-04-01British Ceramic Transactions

Measurements of initial sintering shrinkage of mixes of CaAl4O7 and CaAl2O4 are reported in the temperature range 1360–1420°C. The particle size chosen was -45 μm and the mix proportions were 5 : 8, 4 : 10, and 3 : 11 by weight of CaAl4O7 and CaAl2O4 . The soaking periods were from 10 to 180 min. The time dependence o…

Advanced ceramic materials synthesisRecycling and utilization of industrial and municipal waste in materials productionBauxite Residue and Utilization

Phonon Spectrum of the Layered In4Se3 Crystal

Д. М. Берча、K. Z. Rushchanskii、M. Sznajder1999-04-01physica status solidi (b)

In this paper, we present the results of our calculations of the phonon spectrum for the In4Se3 crystal in the central two-body interaction model without taking into account long-range forces. The model studied here contains five unknown parameters, which were determined from the experimental values of the elastic mod…

Chalcogenide Semiconductor Thin FilmsSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

Effect of chemical structures of polyimides on photosensitivity of liquid crystal alignment using a polarized UV exposure

Megumi Nishikawa、Yu. Reznikov、John L. West1999-04-01Liquid Crystals

Unidirectional liquid crystal (LC) alignment produced by polarized UV exposure was examined using polyimides (PIs) synthesized using different diamines. The dichroic ratio of the resulting LC cells suggests that the UV photosensitivity is primarily controlled by the chemical structures of the PIs used. The UV absorpti…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistrySynthesis and properties of polymers

Constitutive Modeling of Inelastic Solids for Plastic Flow Processes Under Cyclic Dynamic Loadings

W. Dornowski、P. Perzyna1999-04-01Journal of Engineering Materials and Technology

The main objective of the paper is the description of the behavior and fatigue damage of inelastic solids in plastic flow processes under dynamic cyclic loadings. Experimental motivations and physical foundations are given. Recent experimental observations for cycle fatigue damage mechanics at high temperature of meta…

Fatigue and fracture mechanicsMetal Forming Simulation TechniquesHigh-Velocity Impact and Material Behavior

Stress in copper ion-exchanged glass waveguides

N. Valles-Villarreal、A. Villalobos、H. Márquez1999-04-01Journal of Lightwave Technology

This paper obtains stress profiles of copper ion-exchanged glass waveguides from the analysis of transverse electric (TE) and transverse magnetic (TM) modes which was measured by means of the prism-coupling technique. The reconstruction of stress profiles have been realized from an interpolation of the obtained data o…

Photonic and Optical DevicesGlass properties and applicationsMagneto-Optical Properties and Applications

Synthese und Kristallstruktur von Ti12Sn3O10 - einem niedervalenten Oxid des Titans mit oxidischem Gerüst und intermetallischen „Inseln”

Harald Hillebrecht、Martin Ade1999-04-01Zeitschrift für anorganische und allgemeine Chemie

Die neue ternäre Phase Ti12Sn3O10 wird durch Umsetzung von Ti, TiO2 und Sn bei 1500 °C erhalten. Die Einkristall-Strukturanalyse (kubisch, Raumgruppe Fm3m, a = 13.5652(9) Å, Z = 8, wR2(I) = 0.048, R1(F) = 0.020) der luftstabilen Verbindung zeigt, daß ein neuer Strukturtyp vorliegt, in dem Strukturelemente von Oxiden u…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesChemical Synthesis and Characterization

Formation of Surface Micelles from Adsorbed Asymmetric Block Copolymers: A Monte Carlo Study

Andrey Milchev、Kurt Binder1999-04-01Langmuir

The properties of surface micelles formed from flexible short block copolymers of composition A f B 1 - f with f = 1 / 4 and chain lengths of N = 8 and N = 16 effective monomers are obtained from Monte Carlo simulation of a coarse-grained bead spring model. We consider the case where the surface has a short-range attr…

Advanced Polymer Synthesis and CharacterizationMesoporous Materials and CatalysisBlock Copolymer Self-Assembly

Hexagonal Al81Fe8Cr11 with a=4.00 nm and c=1.24nm

H. X. Sui1999-04-01Philosophical Magazine Letters

A new hexagonal compound, Al81Fe8Cr11, with lattice parameters a=4.00 nm and c=1.24 nm, was found in Al12FeCr2 and Al12Fe2Cr alloys by means of transmission electron microscopy. The main zonal electron diffraction patterns of this new hexagonal phase were found to resemble those of a group of hexagonal phases, especia…

Aluminum Alloy Microstructure PropertiesQuasicrystal Structures and PropertiesNanoporous metals and alloys

A Thermodynamical Theory of Plastic Spin and Internal Stress With Dislocation Density Tensor

K. Shizawa、Hussein M. Zbib1999-04-01Journal of Engineering Materials and Technology

A thermodynamical theory of elastoplasticity including kinematic hardening and dislocation density tensor is developed. The theory is self-consistent and is based on two fundamental principles of thermodynamics, i.e., the principle of increase of entropy and maximal entropy production rate. The thermodynamically consi…

Microstructure and mechanical propertiesThermoelastic and Magnetoelastic PhenomenaNonlocal and gradient elasticity in micro/nano structures

Heat Capacity of K3LnCl6 Compounds with Ln = La, Ce, Pr, Nd

Marcelle Gaune‐Escard、Leszek Rycerz1999-04-01Zeitschrift für Naturforschung A

The heat capacities of the solid and liquid K 3 LnCl 6 compounds (Ln = La, Ce, Pr, Nd) have been determined by differential scanning calorimetry (DSC) in the temperature range 300 -1100 K. Their temperature dependence is discussed in terms of the phase transitions of these compounds as reported in literature. The heat…

Solid-state spectroscopy and crystallographyChemical Thermodynamics and Molecular StructureOptical properties and cooling technologies in crystalline materials

Effect of Grain Thermal Expansion Mismatch on Thermal Conductivity of Porous Ceramics

Efim Litovsky、Tatiana Gambaryan‐Roisman、M. Shapiro 等 4 位作者1999-04-01Journal of the American Ceramic Society

Many ceramics contain microcracks, which are often situated between sintered grains. These microcracks constitute thermal resistances, which may affect heat transfer through the material and its effective thermophysical properties. The thicknesses and the contact areas of the microcracks change with temperature as a r…

Advanced ceramic materials synthesisThermal properties of materialsComposite Material Mechanics

The Interaction Between Point Defects and Edge Dislocation in BCC Iron

Vijay Shastry、T. Dı́az de la Rubia1999-04-01Journal of Engineering Materials and Technology

We present results of atomistic simulations of the interaction between self interstitial atoms and vacancies with edge dislocations in BCC iron. The calculations are carried out using molecular dynamics with an energy minimization scheme based on the quasi-Newton approach and use the Finnis-Sinclair interatomic potent…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsFusion materials and technologies

Effects of inorganic sulphide and ammonia on microbial corrosion behaviour of 70Cu–30Ni alloy in sea water

H.M. Shalaby、Abdelfattah Hasan、F. Al-Sabti1999-04-01British Corrosion Journal

A laboratory electrochemical investigation was carried out on the effects of inorganic sulphide (1 ppm) and ammonia (10 ppm), as sea water pollutants, on the corrosion of 70Cu–30Ni alloy owing to sulphate reducing bacteria (SRB). Potential–time and linear polarisation measurements revealed that the presence of SRB mak…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Electrochemical Properties of Zr‐V‐Ni System Hydrogen Storage Alloys

Xiaoguang Yang、W. K. Zhang、Y.Q. Lei 等 4 位作者1999-04-01Journal of The Electrochemical Society

The Zr‐V‐Ni system multicomponent alloys were investigated by electrochemical measurements, X‐ray diffraction analysis, scanning electron microscopy, and energy‐dispersive spectroscopy. At room temperature, the discharge capacity of alloys remains at a high level when = 0.3–0.5. A C15 main phase alloy has good capacit…

Fuel Cells and Related MaterialsHydrogen Storage and MaterialsNuclear Materials and Properties

Extraction of soil‐available phosphate, nitrate, and sulphate ions using ion exchange membranes and determination by ion exchange chromatography

Marı́a-Belén Turrión、Juan‐Fernando Gallardo、María‐Isabel González1999-04-01Communications in Soil Science and Plant Analysis

In recent years, ion exchange membranes (IEM) have been used successfully to determine the availability of soil nutrient elements for plants. In general, the procedures proposed are applied to the determination of a single ion, and in only a few of these studies, the selectivity of these IEM was considered. Therefore,…

Groundwater and Isotope GeochemistryClay minerals and soil interactionsPhosphorus and nutrient management