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Copolymerization of 3,3,3‐trifluoro‐1,2‐epoxypropane with N‐phenylmaleimide using organozinc initiators

Yoji Ikeda、Yasuhiko Yoshida、Kenji Ishihara 等 6 位作者1996-10-01Macromolecular Rapid Communications

Abstract Novel copolymers consisting of 3,3,3‐trifluoro‐1,2‐epoxypropane (TFEP) and N ‐phenylmaleimide (PMI) units were prepared by the copolymerization of TFEP with PMI initiated with an organozinc compound. Using [Zn(OCH 3 ) 2 · (C 2 H 5 ZnOCH 3 ) 4 ] as an initiator, the copolymer chains consisted mainly of TFEP‐TF…

Organometallic Complex Synthesis and CatalysisSynthetic Organic Chemistry MethodsSynthesis and properties of polymers

Diffractive beamshaping elements at the fabrication limit

Wolfgang Singer1996-10-01Optical Engineering

We treat the generation of flat-top intensity distributions, as required for laser applications at short wavelengths. To obtain high fill factors and almost arbitrary shapes, arrays of diffractive Fresnel zone plates at the fabrication limit are investigated. The angular power spectrum noise due to the binarization of…

Optical measurement and interference techniquesPhotorefractive and Nonlinear OpticsOptical Coatings and Gratings

The Significance of High Value of Ignition Retard Control on the Catalyst Lightoff

Siew Hwa Chan、Jianhui Zhu1996-10-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">Ever stringent emission legislation has called for more advanced measures for petrol engine emission control. The main chanllenge is to largely cut off the engine cold-start emissions. The problem is that the catalytic converter does not operate effectively at temperature below th…

Catalytic Processes in Materials ScienceIndustrial Technology and Control Systems

Further applications of a recursive modal method for calculating the efficiencies of X-UV multilayer gratings

K. Krastev、Jean‐Marc André、R. Barchewitz1996-10-01Journal of the Optical Society of America A

We apply a recursive propagation method to the modal theory of diffraction by laminar amplitude multilayer gratings (LAMG’s). We compute the reflection efficiency in the X-UV domain of several LAMG’s and show the numerical stability of this method with respect to a nonrecursive one.

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

A modified high-temperature cell (up to 3300 K) for use with a cubic press

SK Bhaumik、C. Divakar、M. Murali Mohan 等 4 位作者1996-10-01Review of Scientific Instruments

A high temperature-high pressure pyrophyllite cell with a graphite heater has limitations when temperature exceeds ∼2100 K. A conventional cell used with the cubic anvil high pressure apparatus has been modified to reach ∼3300 K. The heater power versus temperature calibration curve has been established using Pt–Pt10%…

Advanced ceramic materials synthesisHigh-Temperature Coating BehaviorsAdvanced materials and composites

Reactivity and Exhaust Emissions from an EHC-Equipped LPG Conversion Vehicle Operating on Butane/Propane Fuel Blends

Matthew S. Newkirk、Lawrence Smith、Michael E. Payne 等 4 位作者1996-10-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">This paper describes experiments conducted to determine Federal Test Procedure (FTP) exhaust emissions, ozone-forming potentials, specific reactivities, and reactivity adjustment factors for several butane/propane alternative fuel blends run on a light-duty EHC-equipped gasoline v…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceVehicle emissions and performance

Dielectric properties of supercooled cryoprotectant agents

S. Michelson、Stephen D. Evans1996-10-01Physics in Medicine and Biology

The dielectric properties of glycerol, propylene glycol, ethylene glycol and dimethyl sulphoxide have been measured in various aqueous concentrations generally sufficient to allow supercooling rather than freezing. The temperature range investigated is from -80 degrees C to +20 degrees C and the frequency range is 100…

Material Dynamics and PropertiesElectrostatics and Colloid Interactions

Optical properties of Ce3+‐doped Lu2O3 and Y2O3 single crystals

M. Raukas、S. A. Basun、W. M. Dennis 等 7 位作者1996-10-01Journal of the Society for Information Display

Abstract— The study of phosphor materials generally focuses on systems with a high quantum efficiency. On the other hand, a thorough understanding why certain systems show very low quantum yield will certainly, lead to a better understanding of phosphor materials in general. Here we present studies on cerium‐doped lut…

Luminescence Properties of Advanced MaterialsPhotorefractive and Nonlinear OpticsSolid State Laser Technologies

Permeation Rate of Hydrogen Isotopes through Palladium- Silver Alloy

Masabumi Nishikawa、Tomofumi Shiraishi、Yoshinori Kawamura 等 4 位作者1996-10-01Journal of Nuclear Science and Technology

Experiments were performed to study the permeation of hydrogen isotopes through a membrane of palladium-silver alloy in the temperature range of 353 to 673 K using the co-current double tube method. It is observed that permeation is limited by the diffusion process of hydrogen atoms in the bulk of membrane in the larg…

Fusion materials and technologiesHydrogen Storage and MaterialsNuclear Materials and Properties

Wigner crystallization of electrons and holes in amorphous silicon nitride. Antiferromagnetic ordering of localized electrons and holes as a result of a resonance exchange interaction

V. A. Gritsenko、A. D. Milov1996-10-01Journal of Experimental and Theoretical Physics Letters

The predicted quantitative relation between the density and trapping cross section of traps in Si3N4 and the Coulomb repulsion radius in the Wigner crystallization of carriers in localized states is observed experimentally. The absence of ESR for localized electrons and holes in Si3N4 is interpreted on the basis of a…

Glass properties and applicationsThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Phase assemblages in the system Ca(OH)2—Al2O3—Ca(NO3)2—H2O

John Q. Dumm、Paul W. Brown1996-10-01Advances in Cement Research

Phase formation in the system Ca(OH) 2 —Al 2 O 3 —Ca(NO 3 ) 2 —H 2 O was investigated at 25° and 80°e. The formation of an AFt phase was not observed. Three AFm phase were observed: one is the AFm phase previously reported by Kuzel; the remaining two appear not to have been previously identified. The compatibility rel…

Solid-state spectroscopy and crystallographyCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Clay Mineral Diagenesis and Thermal History of the Thonex Well, Western Swiss Molasse Basin

Roland Schegg、W. Leu1996-10-01Clays and Clay Minerals

Abstract Results are presented of a diagenetic study from the 1300 m thick Oligocene Molasse deposits penetrated by the Thônex geothermal exploration well (Geneva, Switzerland). The x-ray diffraction (XRD) studies of fine-grained rocks indicate the following diagenetic changes: a decrease of illite/smectite (US) expan…

Geological and Geochemical AnalysisHydrocarbon exploration and reservoir analysisClay minerals and soil interactions

Effects of yttrium on the oxidation behaviour of Iron‐Chromium‐Aluminium Alloys

J. Klöwer、Jiechen Li1996-10-01Materials and Corrosion

Abstract The effects of yttrium additions on the oxidation behaviour of Fe‐20Cr‐5Al(wt%) alloys have been investigated in oxidation tests and cyclic heating‐element tests at temperatures ranging from 1100 to 1400°C in air. Experimental results showed that the oxidation resistance of the alloys depends sensitively on t…

High-Temperature Coating BehaviorsMetallurgy and Material Science

THE EFFECT OF CONVECTION ON DENDRITIC GROWTH UNDER MICROGRAVITY CONDITIONS

M. B. Koss、L.T. Bushnell、Jeffrey LaCombe 等 4 位作者1996-10-01Chemical Engineering Communications

The Isothermal Dendritic Growth Experiment (IDGE) is an orbital space flight experiment, launched by NASA, in March, 1994, as part of the United States Microgravity Payload (USMP-2). The IDGE provided accurately measured dendritic growth rates, tip radii of curvature, and morphological observations of ultra-pure succi…

Theoretical and Computational PhysicsSolidification and crystal growth phenomenaMetallurgical Processes and Thermodynamics

Three-dimensional Rayleigh hysteresis of oriented core samples from the German Continental Deep Drilling Program: susceptibility tensor, Rayleigh tensor, three-dimensional Rayleigh law

H. Markert、Alessandra Geddo Lehmann1996-10-01Geophysical Journal International

Rayleigh hysteresis, as defined by the well-known Rayleigh relations, has been observed not only when magnetization of pyrrhotite-bearing KTB-samples is measured in parallel to a weak dc magnetic field, but also in experiments where field and measuring directions have been adjusted strictly perpendicularly to each oth…

Geophysical and Geoelectrical MethodsMagnetic Properties and ApplicationsGeomagnetism and Paleomagnetism Studies

Electronic structure of second harmonic generation crystal Li3VO4

Sei-ichiro SAKATA、Y. Nagoshi、Hiroyuki Nii 等 5 位作者1996-10-01Journal of Applied Physics

The origin of second harmonic generation (SHG) of Li3VO4 was investigated from the viewpoint of the band structure by using the tight-binding method. The tight-binding parameters were optimized to reproduce the density of states (DOS) obtained from x ray photoelectron spectroscopy and the optical band gap. Although Li…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesPhotorefractive and Nonlinear Optics

Synthesis and properties of poly(1‐alkyl‐3‐methylene‐2‐pyrrolidone)s

George M. Iskander、Toni R. Ovenell、Thomas P. Davis1996-10-01Macromolecular Chemistry and Physics

Abstract A series of α‐methylene‐ N ‐alkyl‐2‐pyrrolidone monomers with varying length of the alkyl chain from C 1 to C 8 were synthesised. The monomers were subjected to free radical polymerisation to yield a range of polymers each with a different balance in hydrophobic/hydrophilic properties originating from the pyr…

Polymer Nanocomposites and PropertiesThermal and Kinetic AnalysisPolymer Science and PVC

Research Results on Processes and Catalyst Materials for Lean NOx Conversion

Axel König、Thomas Richter、Edward Jobson 等 8 位作者1996-10-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure</div> <div class="htmlview paragraph"> <ul class="list…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsPigment Synthesis and Properties

The active dopant concentration in ion implanted indium tin oxide thin films

T.J. Vink、M.H.F. Overwijk、W. Walrave1996-10-01Journal of Applied Physics

The effect of oxygen ion implantation on the electrical and optical properties of Sn-doped In2O3 (ITO) thin films, sputter deposited from a planar magnetron source on glass substrates, is described. The films were characterized as a function of the implanted dose (3×1013–1×1016 O+ cm−2) by Hall effect, resistivity, an…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Crosslinking of Gelatin in the Reaction with Formaldehyde: An FT-IR Spectroscopic Study

T. Salsa、M. E. Pina、J.J.C. Teixeira‐Dias1996-10-01Applied Spectroscopy

The reaction of an aqueous solution of formaldehyde with gelatin dispersed in a potassium bromide pellet is monitored in real time by FT-IR spectroscopy. Principal component regression analysis of the spectra recorded at different times is carried out. On the whole, the latter results and the observed spectral changes…

Meat and Animal Product QualityDyeing and Modifying Textile FibersCollagen: Extraction and Characterization