Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption Studies on Boron Nitride SubstratesPraful Shrestha, Mazin T. Alkhafaji, Michelle M. Lukowitz, Guoliang Yang, and Aldo D. MigoneCite this: Langmuir 1994, 10, 9, 3244–3249Publication Date (Print):September 1, 1994Publication History Published online1 May 2002Publish…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGlasses with Strong Calorimetric .beta.-Glass Transitions and the Relation to the Protein Glass Transition ProblemJ. Fan, E. I. Cooper, and C. A. AngellCite this: J. Phys. Chem. 1994, 98, 37, 9345–9349Publication Date (Print):September 1, 1994Publication History Published on…
A statistical interpretation of the Preisach model led to the moving model that relaxed the congruency property and to the complete moving hysteresis model (CMH) which included a state-dependent locally-reversible magnetization. Since, like all Preisach models, these models possess the deletion property, minor hystere…
Brittle fracture of β-SiC (polytype 3C) under hydrostatic tension has been modeled by molecular dynamics simulation using an interatomic potential function that treats the solid as fully covalent. The critical stress at which the lattice becomes structurally unstable is shown to agree quantitatively with that predicte…
Protein geranylgeranyltransferase type I (GGTase I) catalyzes the prenylation of a number of proteins that play important roles in cellular signaling. The recent cDNA cloning of this enzyme (Zhang, F. L., Diehl, R. E., Kohl, N. E., Gibbs, J. B., Giros, B., Casey, P. J., and Omer, C. A. (1994) J. Biol. Chem. 269, 3175-…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and Structures of Cyclic and Acyclic Metallasiloxanes of Groups 5-7Hans-Juergen Gosink, Herbert W. Roesky, Hans-Georg Schmidt, Mathias Noltemeyer, Erhard Irmer, and Regine Herbst-IrmerCite this: Organometallics 1994, 13, 9, 3420–3426Publication Date (Print):Septemb…
Condensation of pyrrole with a benzaldehyde and 4-pyridinecarboxaldehyde mixture yields the six possible meso-substituted phenyl or pyridyl porphyrins. Nitration of four of these has yielded 13 other porphyrins containing one to four 4-nitrophenyl moieties, and SnCl 2 reduction of eight of these nitrophenylporphyrins…
Ru and RuO 2 thin films were prepared by RF magnetron sputtering. The crystalline structure and electrical properties of these films were investigated. Reactive sputtering of a ruthenium metal target was carried out in a mixed gas of argon and oxygen at 580° C. Total pressure ( P O 2 + P Ar ) was controlled to maintai…
In the Al–Pd–Re system, two kinds of icosahedral phases (I-phases) with different quasilattice constants have been found to form at 1173 K. The I-phase with larger quasilattice constant is formed in a wide composition range at 1173 K: 13–25 at.%Pd and 10–15 at.%Re. The conductivity of single-I-phase samples varies gre…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal Structures and Ferromagnetic Properties of Two New Dinuclear Complexes with Thiocyanato Bridging Ligands:{[Ni2(1,2-diamino-2-methylpropane)3(NCS)2]2(.mu.-NCS)2}[Ni(1,2-diamino-2-methylpropane)2(NCS)2].cntdot.H2O and[{Ni2(1,2-diamino-2-methylpropane)4}(.mu.-NCS)2](PF6…
Dielectric properties of <111>- and <100>-preferred lead-zirconate-titanate (PZT) films with thickness of 400 nm prepared by the sol-gel deposition technique have been investigated from ferroelectric random-access memory (FRAM) and dynamic random-access memory (DRAM) application standpoints. Remanent polar…
Chimeric genes under the control of a CaMV 35S promoter with a doubled enhancer (35S2) that encode a mammalian metallothionein (hMTII), or an Escherichia coli beta-glucuronidase (GUS), or a hMTII/GUS fusion protein were introduced into the genome of tobacco (Nicotiana tabacum cv. PBD6). Transcripts and Cd-binding prot…
Chemical modification of proteins by use of functional polymers is expected to endow them with new properties without destroying their native functions, thus providing useful materials for application in different fields. We have synthesized poly(N-isopropylacrylamide) [poly(IPAAm)] co-oligomer with N,N-dimethylacryla…
ADVERTISEMENT RETURN TO ISSUEPREVArticleInfluence of Shear on the Hexagonal-to-Disorder Transition in a Diblock Copolymer MeltFrank S. Bates, Kurt A. Koppi, Matthew Tirrell, Kristoffer Almdal, and Kell MortensenCite this: Macromolecules 1994, 27, 20, 5934–5936Publication Date (Print):September 1, 1994Publication Histo…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTunable Electron Density at a Rhenium Carbonyl Complex Coordinated to the Conducting Polymer Poly[5,5'-(2-thienyl)-2,2'-bithiazole]Michael O. Wolf and Mark S. WrightonCite this: Chem. Mater. 1994, 6, 9, 1526–1533Publication Date (Print):September 1, 1994Publication History P…
The orientation of Pb(Zr, Ti)O 3 (PZT) thin films grown by metalorganic chemical vapor deposition (MOCVD) using a two-step growth process was controlled by changing the orientation of the PbTiO 3 buffer layer. The (111)-oriented and (100)-oriented PZT films were grown on the (111)-oriented and the (001) and (100) mixe…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Comparative Study of the Coadsorption of carbon monoxide and nitric oxide on Pd(100), Pd(111), and Silica-Supported Palladium Particles with Infrared Reflection-Absorption SpectroscopyXueping Xu, Peijun Chen, and D. Wayne GoodmanCite this: J. Phys. Chem. 1994, 98, 37, 9242…
We present the calculated self-consistent electronic structure and conductivity in a hypothetical model [1/1] approximant of the icosahedral phases Al-Cu-Fe. Two main features characterize the density of states. First, a well-pronounced pseudogap, commonly attributed to electron scattering by the lattice structure (th…
The effects of thin Ti, TiN, or Ti/TiN underlayers on the development of the crystallographic texture and the grain structure are explored. Metal layers ∼0.5 μm in thickness of Al-0.5Cu or of Cu are deposited on these underlayers and on amorphous SiO2 as a reference. A strongly textured underlayer such as Ti〈0002〉 or…
Dielectric properties of (Ba 0.5 Sr 0.5 )TiO 3 and (Ba 0.75 Sr 0.25 )TiO 3 thin films have been investigated, focusing on the effects of film structure and Ba/Sr compositions on the dielectric properties. Dielectric constant of the films increased with increasing grain size and with improvement in film crystallinity.…