Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn electrochemical study of the protonation site of the cobaltocene anion and of cyclopentadienylcobalt(I) dicarbollidesWilliam E. Geiger Jr., William L. Bowden, and Nabil El MurrCite this: Inorg. Chem. 1979, 18, 9, 2358–2361Publication Date (Print):September 1, 1979Publicat…
Summary Na‐Mg and Na‐Ca exchange isotherms were determined at electrolyte concentrations of 500, 50, 5 and 1 meq per litre for illite, vermiculite and montmorillonite and for three soils containing illite and montmorillonite. This enabled comparisons to be made of clay swelling, dispersion and soil hydraulic conductiv…
Contractile properties of an isolated segment of the secretory coil of the monkey palm eccrine sweat gland were studied in vitro with a transducer. Contraction of up to 10 mgf was induced with acetylcholine but not with alpha or beta adrenergic agonists, caffeine, prostaglandin E1, or by a calcium ionophore A23187. Ot…
The vibrational frequencies of Si–H groups, SiH, SiH2, and SiH3, in substituted silane molecules, and hydrogenated amorphous solids, display shifts in frequency that can be correlated with the relative electronegativities of the silicon nearest neighbors, i.e, the substituting atoms or groups in the molecules, and the…
A new series of $^{27}\mathrm{Al}$ hyperfine spectra have been discovered by EPR studies in irradiated type-I and -II vitreous silica. Our analysis of these spectra indicate that under ionizing irradiation at low temperatures ($T\ensuremath{\lesssim}260$ K), pre-existent, diamagnetic network defects of the form $\math…
ADVERTISEMENT RETURN TO ISSUEPREVArticleA New Liquid-Crystalline Material. Transition Metal-Poly(yne) PolymersS. Takahashi, E. Murata, M. Kariya, K. Sonogashira, and N. HagiharaCite this: Macromolecules 1979, 12, 5, 1016–1018Publication Date (Print):September 1, 1979Publication History Published online1 May 2002Publis…
The application and maintenance of outdoor ceramic insulation on overhead transmission systems has been an art learned by experience. This document combines the experiences of electric utilities, manufacturers, and research laboratories into a single comprehensive report on the design and maintenance of transmission i…
Secondary ion mass spectrumètry has been applied for measuring the tracer diffusivity of oxygen in the c direction of single‐crystal rutile for a temperature range of 1150 to 1450 K at 6000 Pa pressure of oxygen gas. Specimens diffusion‐annealed in oxygen gas containing 18 O were subsequently continuously sputtered an…
The magnetic field dependence of the capacitance of a twisted nematic layer has been analysed by Shtrikman et al (1) who found only moderate agreement between their theory and the experimental results of Gerritsma et al (2). Here we investigate the voltage dependence of the capacitance of a twisted nematic liquid crys…
Solutions of octaalkyl metalloporphyrin Π cation radicals react with nucleophiles such as nitrite, chloride, pyridines, imidazole, cyanide, triphenylphosphine, thiocyanate, acetate, and azide, to produce the corresponding meso-(methine) substituted metalloporphyrins. Demetalation then gives the appropriate meso-substi…
A simple and efficient numerical procedure is presented for determining the static charge distribution on arbitrary-shaped surfaces. Surfaces are modeled by planar triangular subdomains in which the charge density is assumed to be constant. The method of moments is employed to calculate the charge distribution on the…
Abstract Polycarbonate tensile bars were aged up to 18 months at 0%, 75%, and 100% relative humidity and temperatures of 65–93°C. In the humid aged samples hydrolysis caused progressive reductions in molecular weight. Below a critical molecular weight ( M w = 33,800, M n = 14,300) tensile strength dropped off rapidly.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPentagonal-bipyramidal complexes. Synthesis and characterization of aqua(nitrato)[2,6-diacetylpyridine bis(benzoyl hydrazone)]cobalt(II) nitrate and diaqua[2,6-diacetylpyridine bis(benzoyl hydrazone)]nickel(II) nitrate dihydrateThomas J. Giordano, Gus J. Palenik, Ruth C. Pal…
Abstract— The triplet absorption spectra, lifetimes, extinction coefficients, e TT , and intersystem crossing quantum yields to the lowest triplet T 1 , ø T1 , of thymidine, thymidine monophosphate, uridine and uridine monophosphate, have been determined in various solvents at 300 K. The effect of H‐bonding on ø T1 ,…
Studies of the electrical transport properties---resistivity, Hall effect, and Seebeck coefficient---of the hexagonal tungsten bronze ${\mathrm{Rb}}_{x}\mathrm{W}{\mathrm{O}}_{3}$ for $0.16<~x<~0.33$ are reported for the temperature range from 1.5 to 300 K. In the normal state, these properties show temperature-…
The boson theory is reformulated in a form applicable to the mixed state in the rare-earth compounds, $R{\mathrm{Rh}}_{4}{\mathrm{B}}_{4}$, ${R}_{x}{\mathrm{Mo}}_{6}{\mathrm{S}}_{8}$, and ${R}_{x}{\mathrm{Mo}}_{6}{\mathrm{Se}}_{6}$. The magnetic field induced by the persistent current of vortices, and the spin magneti…
The crystal structures of the title compounds [${\mathrm{C}}_{4}$${\mathrm{H}}_{8}$SO (TMSO), ${\mathrm{C}}_{2}$${\mathrm{H}}_{6}$SO (DMSO)] have been determined. The TMSO salt is orthorhombic [space group $\mathrm{Pbca}$, $a=13.844(10)$, $b=6.418(12)$, and $c=17.480(16)$ \AA{}] while the DMSO salt is monoclinic [spac…
Polyhedral tilt transformations are a subgroup of pure displacive solid-solid phase transitions that occur in many ionic compounds and have all the following characteristics: (1) the transitions occur in compounds with structures composed of corner-linked, rigid polyhedral elements; (2) transitions are between a highe…
Integrated X-ray intensities of Bragg peaks were observed from single crystals of Zr0.866Ca0.134Ol.866 and Zr0.786Y0.214O1.893 in the disordered state. There are displacements of oxygen ions (characterized by Δ/a ~ 0.05) from the ideal positions of the fluorite structure along (100) directions similar to those that oc…
Abstract Behavior of poly(ethylene oxalate) in a temperature range of 148–240°C was studied, and a new method of isolating 1,4‐dioxane‐2,3‐dione from the products of decomposition of poly(ethylene oxalate) was used. The process of decomposition was second order. Equilibrium of poly(ethylene oxalate) and 1,4‐dioxane‐2,…