Materials Literature
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A review of the available electrical and structural data on both pure and doped 1T-TaS2 leads us to propose that the nearly commensurate to commensurate transition at 200 K is accompanied by Mott localization in two dimensions. One electron out of 13 in the Ta plane is localized onto the centre of a star of 13 Ta atom…
We consider a system of rodlike molecules interacting with a model pair potential $\ensuremath{\varphi}(\frac{r}{\ensuremath{\sigma}})$, where $r$ is the center-of-mass distance and $\ensuremath{\sigma}$ is an angle-dependent range parameter. It is shown that if the pair correlation function $g$ scales as $g(\frac{r}{…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe difference between metallic and insulating salts of tetracyanoquinodimethone (TCNQ): how to design an organic metalJerry B. TorranceCite this: Acc. Chem. Res. 1979, 12, 3, 79–86Publication Date (Print):March 1, 1979Publication History Published online1 May 2002Published…
Abstract Sandstones and shales of the Wilcox Group (lower Eocene) in southwest Texas were examined by X-ray powder diffraction, electron microprobe, and petrographically to interpret their diagenetic history. Samples analyzed are from depths of 975 to 4650 m, representing a temperature range of 55 degrees C to 210 deg…
A first-principles order-parameter theory of the fluid-solid transition is presented in this paper. The thermodynamic potential $\ensuremath{\Omega}$ of the system is computed as a function of order parameters ${\ensuremath{\lambda}}_{i}(={\ensuremath{\lambda}}_{{\stackrel{\ensuremath{\rightarrow}}{\mathrm{k}}}_{i}})$…
A theory of dislocation-mediated melting in two dimensions is described in detail, with an emphasis on results for triangular lattices on both smooth and periodic substrates. The transition from solid to liquid on a smooth substrate takes place in two steps with increasing temperatures. Dissociation of dislocation pai…
The computational and theoretical studies in the field of homogeneous polycondensation are subjected to a critical analysis on the basis of the universal classification of the kinetic and thermodynamic models used in this field. The limits of the applicability of the models are discussed from the standpoint of the phy…
A review is presented of the theory of optical properties of cholesteric liquid crystals (CLC). The diffraction nature of the unusual optical properties of CLC is exhibited in the simplest and most easily visualizable kinematic approximation of diffraction theory. A quantitative description of the optical properties i…
In this paper a theoretical investigation of convection currents in anisotropic porous media is performed. The porous layer is homogeneous and bounded by two infinite perfectly heat-conducting horizontal planes. The criterion for the onset of convection is derived. The supercritical steady two-dimensional motion, the…
Abstract This paper describes an experimental study of the centre of mass diffusion of linear hydrocarbon or deuterocarbon molecules, of the type (CH2)N or (CD2)N, through bulk polyethylene. N was varied between about 15 and 1500. The diffusion coefficient D was measured as a function of temperature, matrix morphology…
The movement of atoms during twinning is described as a simple relative movement and not by means of a shear parallel to the twin plane, even with added “shuffles”. It is shown that displacive waves similar to those which describe the β → ω transformation, can be associated with these atom movements.
Experimental evidence supports the hypothesis that the concentration and distribution of dissolved aluminum in ocean water are controlled by biological activity in the surface waters. The growth of the diatom Skeletonema costatum in artificial seawater media spiked with aluminum reduced the aluminum concentration to t…
We have made a high-resolution (0.12 eV) measurement of the electron energy-loss spectrum of the layered compound Ti${\mathrm{S}}_{2}$ for energy loss $E$ in the range 0.5-150 eV. After subtracting the contribution of plural scattering, we performed a Kramers-Kronig analysis to obtain the dielectric function. The refl…
In order to confirm the existence of an ordering transition in ice VI, an investigation of the thermal expansion was carried out at low temperatures 4.2° K–200° K and high pressure l0.54 kbar. (AIP)
The angular distribution of double scattering for aluminum and nickel have been studied using the relativistic Klein-Nishina cross section. The differences between the nonrelativistic Thomson cross section and the Klein-Nishina cross section are studied at different energies. The effects of using a momentum-dependent…
Laser action in dyes dissolved in liquid crystal matrices is described. Planar thin film structures, filled with rhodamine 6G dissolved in CBOA, M24, and K18 liquid crystals, have been studied. Lasing action has been obtained in the isotropic, nematic, and smectic mesophases. In liquid crystal mesophases, alignment of…
The detailed molecular interactions occurring during thermal degradation of PVC polymer formulations containing MoO3 additives are investigated using laser microprobe techniques coupled with mass analysis of the volatile pyrolysis products. Comparison with Sb2O3–PVC compounds indicate that the additive effects exhibit…
A fundamental study of bubble morphology development and apparent rheological properties in foam extrusion is reported. The influence of melt temperature, die length/diameter ratio, and blowing agent level on the morphology are considered. Measurements of the influence of blowing agent on viscosity, extrudate swell, a…
The long-wavelength vibrational modes of monoclinic GaTe have been investigated by Raman scattering and far-infrared absorption and reflection. The energies of 14 of the expected 18 Raman-active modes have been measured and their symmetries identified. Ten of the 15 predicted infrared-active modes have been found in t…
Experimental data on the dependence of the specific volume on temperature and pressure (PVT data) to 2000 kg/cm2 of isotactic polypropylene and isotactic poly(butene-1) are reported and discussed. The temperature range covered is 30–297°C for polypropylene and 30–246°C for poly(butene-1), thus encompassing the solid a…