Materials Literature
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Extended glass‐forming regions were found by twin‐roller quenching in the systems of with and/or . The crystallization of the glasses was studied by DTA and x‐ray analysis; a new metastable crystalline phase was observed for . The glasses exhibited lithium ion conductivities in the 10 −5 –10 −6 (Ω‐cm) −1 range at room…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTemperature-dependent 5T2(Oh) .dblharw. 1A1(Oh) spin equilibrium in a six-coordinate cobalt(III) complex. Investigation by phosphorus-31 NMR in solutionPhilipp Guetlich, Bruce R. McGarvey, and Wolfgang KlaeuiCite this: Inorg. Chem. 1980, 19, 12, 3704–3706Publication Date (Pr…
Abstract The scattering of X-rays from a concentrated Al (NO 3 ) 3 aqueous solution has been measured and analyzed at 25 °C. Good agreement with experimental data is achieved through a model in which Al 3+ (H 2 O) 6 interacts with twelve water molecules through short and linear H-bonds. The water molecules which are t…
The crystal structures of the following metamorphic olivines, M;*[SiO4], in the forsteritetephroite (Fo-Te) series were refned in space group Pbnm:
Summary Electron diffraction and electron-microprobe investigations have revealed the presence of order in the monazite-huttonite series. Chemical analyses from the literature and electron-microprobe analyses in this study show that the monazite-huttonite series, RE PO 4 -ThSiO 4 , is only continuous if the contributi…
It is shown that in the Flory model (1942) of semi-flexible polymer chains, an assumption of random occupation of sites is not valid for estimating the excluded volume effects when the fraction of gauche bonds is small. Thus the model is never completely ordered except presumably at T=0, and the free energy is such th…
Crosslinking of collagen is a prerequisite for the collagen fibers to withstand the physical stresses to which they are exposed. Significant progress has been made in understanding the functional groups on the molecule which are involved in the forma
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTantalum imido complexesS. M. Rocklage and R. R. SchrockCite this: J. Am. Chem. Soc. 1980, 102, 26, 7808–7809Publication Date (Print):December 1, 1980Publication History Published online1 May 2002Published inissue 1 December 1980https://pubs.acs.org/doi/10.1021/ja00546a043ht…
The microstructural changes which occur during the extrusion of a commercial aluminium alloy (AA 5456) have been investigated at macroscopic, microscopic, and substructural magnifications. Light microscopy has established that the deformation zone is not fully established until a short time after the peak or breakthro…
A theoretical description of the inelastic interactions of low-energy electrons (E≤10 keV) with solid organic insulators is presented. The response of the valence electrons to energy and momentum transfers is inferred from a model for the energy-loss function with parameters fixed by optical data. With this model ener…
Measurements of AC susceptibility and electrical resistivity show the onset of magnetic order at about 5K and the onset of superconductivity at about 1.5K in samples of Y 4 Co 3 which are believed to be single phase. Interpretations are considered which take into account the characteristic structure of the compound an…
Thin films of thermally grown have been studied by high resolution bright‐field electron microscopy. Contrast phenomena observed in images from 9 nm thick "dry" films are consistent with the existence of 1 nm pores, typically 10 nm apart. Similar films grown in a wet oxidizing ambient do not display this contrast. A p…
Starting from the appropriate Smoluchowski equation, the pair-correlation function and the associated static structure factor are calculated for a colloidal suspension which undergoes a shear flow. Terms nonlinear in the shear rate are taken into account. The results obtained are in qualitative agreement with the elli…
The paper reviews recent data on stress corrosion cracking of sensitized Type 304 stainless steel in oxygen containing pure water and in dilute solutions of sodium sulfate and sodium chloride at temperatures ranging from 100 to 300 C. The effects of the carbon content of the steel; the degree of sensitization; the com…
Discusses photoemission from solids and their surfaces. The authors concentrate in particular on angle-resolved photoemission which has been developed into one of the most powerful spectroscopic methods for studying solids, particularly when used in conjunction with light sources such as synchrotron radiation. They di…
Abstract Replicas and thin‐section electron microscopic studies were made of fractions of linear polyethylene covering the molecular weight range 2.78 × 10 4 to 6.0 × 10 6 for a variety of crystallizing conditions. Lamellar crystallites were found under all circumstances; and the supermolecular structure, or crystalli…
Diatom assemblages were monitored at weekly intervals over a 5 week period on Verde limestone, Supai sandstone, and Andesitic basalt substrata in a mountain stream in northern Arizona, U.S.A. Density, Shannon-Weiner diversity, evenness, and community similarity (SIMI) were used to compare colonization patterns and com…
Abstract Chelating organic acids hampered the hydrolytic reactions of Al and affected the nature of the crystalline aluminum hydroxides. Chemical composition, structure, size, nature of functional groups, and concentration of each organic anion, as well as the pH of the system, controlled the rate of Al(OH) 3 crystall…
The conversion of myofiber types was studied in the masseter, trapezius, longissimus, rectus femoris and vastus intermedius muscles of pigs at birth and 2, 4, 8 and 16 weeks of age. The histochemical reaction for ATPase was used to classify myofibers as type I (acid-stable, alkali-labile) or type II (alkali-stable, ac…
Abstract The use of different linking units to promote liquid crystal behaviour in rigid rod like polyarylates is reviewed. By systematically varying the proportion of non linear, meta, ortho , or bent bisphenol units in one particular series based on chloro‐ 1,4 phenylene: 4,4′ oxydibenzoate/terephthalate, complete s…