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Einfluß von Natriumchlorid auf die Oxidation von hochlegierten Chrom‐ und Chrom‐Nickel‐Stählen

E. Reese、H. J. Grabke1993-02-01Materials and Corrosion

Abstract Untersucht wurde der Einfluß fester NaCl‐Ablagerungen auf der Zunderschicht auf die Oxidation der technischen Stähle X10 CrMoV 12 1, X15 CrNiSi 20 12 und X10 CrNiSi 25 20 bei 700°C. Unabhängig von der Legierungszusammensetzung löste die Anwesenheit von NaCl(s) auf der Oberfläche voroxidierter Proben stark bes…

Advanced ceramic materials synthesisAdvanced materials and compositesMagnesium Oxide Properties and Applications

Li5B7S13 und Li9B19S33: Zwei Lithiumthioborate mit neuen hochpolymeren Anionengerüsten

Frank Hiltmann、Peter Hebel、A. Hammerschmidt 等 4 位作者1993-02-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Li 5 B 7 S 13 (C2/c; a = 17,304(2) Å, b = 21,922(3) Å, c = 12,233(2) Å, β = 134,91(1)°; Z = 8 und Li 9 B 19 S 33 (C2/c; a = 23,669(9) Å, b = 14,361(3) Å, c = 12,237(3) Å, β = 103,77(2)°; Z = 4 wurden durch Reaktion von stöchiometrischen Mengen Lithiumsulfid, Bor und Schwefel bei 750°C (Li 5 B 7 S 13 ) und 700…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationInorganic Chemistry and Materials

Development of Ammonium-Saponites from Gels with Variable Ammonium Concentration and Water Content at Low Temperatures

J. Theo Kloprogge、Johan Breukelaar、J. Ben H. Jansen 等 4 位作者1993-02-01Clays and Clay Minerals

Abstract Ammonium-saponite is hydrothermally grown at temperatures below 300°C from a gel with an overall composition corresponding to (NH 4 ) 0.6 Mg 3 Si 3.4 Al 0.6 O 10 (OH) 2 . The synthetic saponite and coexisting fluid have been characterized by means of X-ray powder diffraction, X-ray fluorescence, Induced Coupl…

Building materials and conservationClay minerals and soil interactionsIron oxide chemistry and applications

New disc-shaped mesogens based on pentakis(phenylethynyl)benzene derivatives

Dietmar Janietz、Klaüs Praefcke、D. Singer1993-02-01Liquid Crystals

First examples of amphiphilic alkyl pentakis(phenylethynyl)benzene ethers containing functional groups at the terminal position of their alkoxy chains were synthesized by etherification of pentabromophenol with 11-bromoundecan-1-ol and 11-bromoundecanoic acid ethyl ester, respectively, and subsequent palladium catalyz…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesSynthesis and Properties of Aromatic Compounds

Accurate Determination and Measurement Error of Pretilt Angle in Liquid Crystal Cell

Kwan‐Young Han、Tetsuya Miyashita Tetsuya Miyashita、Tatsuo Uchida1993-02-01Japanese Journal of Applied Physics

To measure the pretilt angle in a liquid crystal cell, the crystal rotation method is commonly used because it is very precise and measurements can be obtained rapidly. However when a liquid crystal cell with insufficient uniformity of the cell gap is used, a significant error occurs due to a shift in the measurement…

Liquid Crystal Research AdvancementsAdvanced Optical Imaging TechnologiesOptical Polarization and Ellipsometry

Bioabsorbable composites. II: Nontoxic, L‐lysine‐based poly(ester‐urethane) matrix composites

Robson F. Storey、Jeffrey S. Wiggins、Kenneth A. Mauritz 等 4 位作者1993-02-01Polymer Composites

Abstract Bioabsorbable composites were fabricated from poly(D, L‐lactide‐urethane) matrix reinforced with poly(glycolic acid) (DEXON) surgical mesh. The crosslinked polyurethane matrix was formed from the reaction of ethy1–2, 6‐diisocyanatohexanoate and poly (D, L‐lactide) triol, initiated from glycerol; the ultimate…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesTribology and Wear Analysis

Liquid-crystalline order in mucus

Christopher Viney、Anne E. Huber、Pedro Verdugo1993-02-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLiquid-crystalline order in mucusChristopher Viney, Anne E. Huber, and Pedro VerdugoCite this: Macromolecules 1993, 26, 4, 852–855Publication Date (Print):February 1, 1993Publication History Published online1 May 2002Published inissue 1 February 1993https://pubs.acs.org/doi/…

Liquid Crystal Research Advancements

Transient charging current in nematic liquid crystals

Hiroyoshi Naito、Kazuyuki Yoshida、Masahiro Okuda 等 4 位作者1993-02-01Journal of Applied Physics

Transient charging currents in nematic liquid crystals have been measured with a single- and a double-voltage pulse technique to elucidate the role of impurity ions incorporated in the materials in the transient charging processes. In the single pulse experiment, a peak in the current transient is observed in the nema…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationQuantum optics and atomic interactions

Synthesis and transport properties ofSrxNbO3(0.75≤x≤0.90)

Kazuyuki Isawa、Jun Sugiyama、Kiyotaka Matsuura 等 5 位作者1993-02-01Physical review. B, Condensed matter

Polycrystalline samples of ${\mathrm{Sr}}_{\mathit{x}}$${\mathrm{NbO}}_{3}$ (0.75\ensuremath{\le}x\ensuremath{\le}0.90) have been successfully synthesized by a solid-state reaction technique using TiO as a reducing agent. Powder x-ray-diffraction analysis indicated that the samples with x\ensuremath{\ge}0.80 were sing…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Cobalt Tetra(hydroquinone)porphyrin: An Efficient Electron Transfer Reagent in Aerobic Pd‐Catalyzed 1,4‐Diacetoxylation of 1,3‐Cyclohexadiene

Helena Grennberg、Sylvie Faizon、Jan‐E. Bäckvall1993-02-01Angewandte Chemie International Edition in English

An efficient bifunctional catalyst for the title reaction is cobalt tetra(hydroquinone)porphyrin 1. The oxidized form of 1 (shown right, R = hydroquinone) has one unit for the interaction with molecular O2, and another for the interaction with the Pd catalyst. Thus, electrons can be transferred rapidly from the Pd com…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions

Evidence for a self-associating equilibrium intermediate during folding of human growth hormone

Michael R. DeFelippis、Leila A. Alter、Allen H. Pekar 等 5 位作者1993-02-01Biochemistry

It has been previously shown, by equilibrium denaturation, that human growth hormone (hGH) folds by a cooperative two-state process. This is in contrast to the folding pathways of other nonhuman growth hormones that contain stable monomeric and multimeric equilibrium intermediates. We have reinvestigated the equilibri…

Protein Structure and DynamicsGrowth Hormone and Insulin-like Growth FactorsEnzyme Structure and Function

Electronic states of bis(phthalocyaninato)lutetium radical and its related compounds: the application of localized orbital basis set to open-shell phthalocyanine dimers

Naoto Ishikawa、Osamu Ohno、Youkoh Kaizu1993-02-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic states of bis(phthalocyaninato)lutetium radical and its related compounds: the application of localized orbital basis set to open-shell phthalocyanine dimersNaoto Ishikawa, Osamu Ohno, and Youkoh KaizuCite this: J. Phys. Chem. 1993, 97, 5, 1004–1010Publication Dat…

Photosynthetic Processes and MechanismsMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry

Nonlinear optical analysis of a series of triblock copolymers containing model polyenes: the dependence of hyperpolarizability on conjugation length

Gordon S. W. Craig、Robert E. Cohen、Richard R. Schrock 等 7 位作者1993-02-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNonlinear optical analysis of a series of triblock copolymers containing model polyenes: the dependence of hyperpolarizability on conjugation lengthG. S. W. Craig, R. E. Cohen, R. R. Schrock, R. J. Silbey, G. Puccetti, I. Ledoux, and J. ZyssCite this: J. Am. Chem. Soc. 1993,…

Organic Electronics and PhotovoltaicsLiquid Crystal Research AdvancementsNonlinear Optical Materials Research

Alkali halide nanocrystals

Robert L. Whetten1993-02-01Accounts of Chemical Research

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAlkali halide nanocrystalsRobert L. WhettenCite this: Acc. Chem. Res. 1993, 26, 2, 49–56Publication Date (Print):February 1, 1993Publication History Published online1 May 2002Published inissue 1 February 1993https://pubs.acs.org/doi/10.1021/ar00026a003https://doi.org/10.1021…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesCrystal Structures and Properties

Fracture Resistance Characteristics of a Metal‐Toughened Ceramic

Brian D. Flinn、C.S. Lo、Frank W. Zok 等 4 位作者1993-02-01Journal of the American Ceramic Society

The fracture characteristics of an Al 2 O 3 /Al composite are examined. Measurements of resistance curves and work of rupture are compared with predictions of a micromechanical model, incorporating the effects of crack bridging by the Al reinforcements. The bridging traction law is assumed to follow linear softening b…

Advanced ceramic materials synthesisNumerical methods in engineeringHigh-Velocity Impact and Material Behavior

Quasi‐perfect polar alignment of nonlinear chromophores in a crystalline H‐bonded guest–host structure: 2‐Amino‐5‐nitropyridinium‐L‐monohydrogentartrate

Joseph Zyss、R. Masse、M. Bagieu‐Beucher 等 4 位作者1993-02-01Advanced Materials

The nonlinear optical properties of organo‐mineral salts based on 2‐amino‐5‐nitropyridine (2A5NP) and tartrate anions are presented. The mineral anion provides improved structural cohesion compared to van der Waals or hydrogen‐bonded organic molecular crystals while the organic species is responsible for the nonlinear…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchMolecular spectroscopy and chirality

Crossover from a displacive to an order-disorder transition in the nonlinear-polarizability model

M. G. Stachiotti、A. Dobry、R. Migoni 等 4 位作者1993-02-01Physical review. B, Condensed matter

The dynamics of a two-dimensional shell model with a double-well potential in the core-shell interaction is simulated by means of molecular-dynamics techniques. Snapshots of the lattice displacement pattern reveal the presence of precursor regions in the high-temperature phase, while in the low-temperature phase the d…

Material Dynamics and PropertiesTheoretical and Computational PhysicsSolid-state spectroscopy and crystallography

Electrical Conductivity, Defect Equilibrium and Oxygen Vacancy Diffusion Coefficient of La1 − x Ca x AlO3 − δ Single Crystals

Junichiro Mizusaki、Isamu Yasuda、Jun‐ichi Shimoyama 等 5 位作者1993-02-01Journal of The Electrochemical Society

Electrical Conductivity, Defect Equilibrium and Oxygen Vacancy Diffusion Coefficient of La1 − x Ca x AlO3 − δ Single Crystals, Mizusaki, Junichiro, Yasuda, Isamu, Shimoyama, Jun‐ichi, Yamauchi, Shigeru, Fueki, Kazuo

Ferroelectric and Piezoelectric MaterialsAdvancements in Solid Oxide Fuel CellsThermal Expansion and Ionic Conductivity

Perfluorooctylbromide as a contrast agent for CT and sonography: preliminary clinical results.

Michael Behan、D O’Connell、Robert F. Mattrey 等 4 位作者1993-02-01American Journal of Roentgenology

OBJECTIVE: Perflubron emulsion is a bromine-based particulate contrast agent that is taken up selectively by the liver and spleen after IV injection. It does not leave the vascular space and also persists in the blood for a longer period than iodinated contrast agents do. We performed a preliminary study to determine…

Hepatocellular Carcinoma Treatment and PrognosisUltrasound and Hyperthermia ApplicationsLanthanide and Transition Metal Complexes

Improved TEM samples of semiconductors prepared by a small‐angle cleavage technique

J. P. McCaffrey1993-02-01Microscopy Research and Technique

A small-angle cleavage technique has been developed that produces superior transmission electron microscope (TEM) samples of semiconductors and related materials. The technique involves back-thinning the sample to approximately 100 microns, then scribing a groove on this back face at a specified small angle to a stand…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesAnodic Oxide Films and Nanostructures