Materials Literature
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Complexation of a boron atom with a series of bidentate heterocyclic ligands successfully gives rise to corresponding BF2-chelated heteroarenes, which could be considered as novel boron(III)-cored dyes. These dye molecules exhibit planar structures and expanded π-conjugated backbones due to the locked conformation wit…
In order to decrease the turbulence influence and the backflow during weft insertion in an air-jet loom, a new main nozzle composed of two nozzle needles connected in series is designed. The internal flow fields of the commonly used nozzle and the new nozzle are numerically studied by means of a three-dimensional mode…
The cefuroxime acid and its acetonitrile solvate were characterized by using a series of methods, such as optical microscopy, powder X-ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy, and Raman spectroscopy. The solvation profile of cefuroxime acid in acetonitrile and water mixture…
An organic–inorganic hybrid polymer, composed of poly(methylsilsesquioxane) (PMSSQ) and poly(4‐vinyl benzaldehyde) (PStCHO), is prepared by reversible addition–fragmentation chain transfer (RAFT) polymerization of 4‐vinyl benzaldehyde (StCHO) using a macro‐chain transfer agent (CTA) based on PMSSQ. The obtained PMSSQ–…
Er(3)/Yb(3)-codoped phosphate glass with compositions of (78.2-x)P(2)O(5)-14Al(2)O(3)-5Li(2)O-1K(2)O-1.8Yb(2)O(3)-xEr(2)O(3)(x=0.2,0.4,0.6) in mol. % were investigated. Judd-Ofelt (JO) intensity parameters have been calculated to predict radiative properties based on absorption spectra. The stimulated emission cross s…
Starch platelets of micro particle size in the range of 10–100 µm were extracted from potato by acid hydrolysis. Two types of starch-reinforced composites, one with poly(vinyl alcohol) (PVA) and the other with poly(lactic acid) (PLA), were prepared by solvent casting and hot press molding methods, respectively. Mechan…
Abstract This work is focused on viscosity of chalcogenide system Se–Te. Viscosity values of four glass-forming compositions in this system (containing 5, 10, 20 and 30 at.% of tellurium) were measured by penetration and parallel-plate method in the region of undercooled melt and glass. These results are combined with…
The synthesis of indium phosphide quantum dots (QDs) in toluene under supercritical conditions was carried out in a macroscopic continuous flow reaction system. The results of first experiments are reported in comparison with analogous reactions in octadecene. The reaction system is described and details are provided…
A novel phosphor LiBaPO4 doped with rare earths Eu and Dy prepared by high temperature solid-state reaction method is reported. The phosphors were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL). The emission and excitation spectra of these materials were…
This study concerns with the preparation of flame retardant and hydrophobic cellulosic fabric by using hexagonal boron nitride nanosheets (h-BNNs). h-BNNs were prepared from hexagonal boron nitride (h-BN) using two different exfoliation methods. These methods include direct sonication (aq-BNNs) and sonication after pr…
Polyethylene glycol (PEG) and related polymers are often used in the functionalization of carbon nanomaterials in procedures that involve sonication. However, PEG is very sensitive to sonolytic degradation and PEG degradation products can be toxic to mammalian cells. Thus, it is imperative to assess potential PEG degr…
With molecular dynamics simulations, we systematically investigate melting of a set of Σ3〈110〉70.53° tilt grain boundaries (GB) in Cu bicrystals, including coherent twin boundaries (CTBs), 12 asymmetric tilt grain boundaries (ATGBs), and symmetric incoherent twin boundaries (SITBs), in the order of increasing length w…
We report the transfer of sub-10 nm half-pitch grating patterns created through a combination of block copolymer directed self-assembly and sidewall spacer-based self-aligned double patterning into Si substrates. Low substrate bias reactive ion etching of TiOx conformally deposited onto carbon mandrels using atomic la…
Novel waterborne polyurethane (WPU) composites based on NiAl‐LDH and ZnO were successfully synthesized by in‐situ polymerization. The nanostructured NiAl‐LDH/ZnO was first grafted by isophorone diisocyanate (IPDI), forming the NiAl‐LDH/ZnO‐NCO complex with ―NCO group on the surface, which promotes its homogeneous disp…
We use molecular dynamics simulations in 2D to study multi-component systems in the limiting case where all the particles are different (APD). The particles are assumed to interact via Lennard-Jones potentials, with identical size parameters but their pair interaction parameters are generated at random from a uniform…
A suitable carbon source is significant for biological nitrate removal from groundwater. In this study, slow-release carbon sources containing polylactic acid (PLA) and starch at 8:2, 7:3, 6:4, 5:5, 4:6, and 3:7 ratios were prepared using a blending and fusing technique. The PLA/starch blend was then used as a solid c…
Hydrogen constitutes an important feedstock for clean-energy technologies as well as for production of bulk and fine chemicals. Hence, the development of novel processes to convert easily available biomass into H2 is of general interest. Herein, we demonstrate a one-pot protocol hydrogen generation from monosaccharide…
In this study , bamboo/tencel 50:50 blended fabric has been used for microencapsulation finishing by essential oil combination using exhaustion method in order to enhance the wash durability of the fabric. The three shell materials, namely sodium alginate, Acacia arabica and Moringa oleifera gum and three core materia…
Sericin is a water-soluble component of silk and has been used as a biomaterial due to its antibacterial and ultraviolet radiation-resistant properties. This study was designed to evaluate the effect of sericin supplementation in a maturation medium on the meiotic competence and fertilisability of sheep oocytes. Cumul…
We propose a systematic and simulation-free strategy for coarse graining of homopolymer melts, where each chain of Nm monomers is uniformly divided into N segments, with the spatial position of each segment corresponding to the center-of-mass of its monomers. We use integral-equation theories suitable for the study of…