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Switchable organoplatinum metallacycles with high quantum yields and tunable fluorescence wavelengths

Junlong Zhu、Lin Xu、Yuanyuan Ren 等 14 位作者2019-09-19Nature Communications

The preparation of fluorescent discrete supramolecular coordination complexes (SCCs) has attracted considerable attention within the fields of supramolecular chemistry, materials science, and biological sciences. However, many challenges remain. For instance, fluorescence quenching often occurs due to the heavy-atom e…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Synthesis of Metal Oxide Nanoparticles by Rapid, High‐Temperature 3D Microwave Heating

Geng Zhong、Shaomao Xu、Chaoji Chen 等 14 位作者2019-09-19Advanced Functional Materials

Abstract Microwave‐assisted fabrication has propelled the recent synthesis and processing approaches of various nanomaterials. However, in most previous studies, the synthesis temperature is limited to below 1100 K, which restricts its application. Here, a rapid, in situ 3D heating method to manufacture well‐dispersed…

MXene and MAX Phase MaterialsNanomaterials for catalytic reactionsMicrowave-Assisted Synthesis and Applications

Two Dimensions Are Better for Perovskites

Kaibo Zheng、Tõnu Pullerits2019-09-19The Journal of Physical Chemistry Letters

ADVERTISEMENT RETURN TO ISSUEPREVViewpointNEXTTwo Dimensions Are Better for PerovskitesKaibo Zheng*Kaibo ZhengDepartment of Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, DenmarkDepartment of Chemical Physics and NanoLund, Lund University, P.O. Box 124, 22100 Lund, Sweden*E-mail: [email protected]…

Perovskite Materials and ApplicationsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Evaporation‐Free Nonfullerene Flexible Organic Solar Cell Modules Manufactured by An All‐Solution Process

Yong Woon Han、Sung Jae Jeon、Hyoungsuk Lee 等 7 位作者2019-09-19Advanced Energy Materials

Abstract To ensure laboratory‐to‐industry transfer of next‐generation energy harvesting organic solar cells (OSCs), it is necessary to develop flexible OSC modules that can be produced on a continuous roll‐to‐roll basis and to apply an all‐solution process. In this study, nonfullerene acceptors (NFAs)‐based donor poly…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

On the Origin of the Large Remanent Polarization in La:HfO2

Tony Schenk、Chris M. Fancher、Min Hyuk Park 等 9 位作者2019-09-19Advanced Electronic Materials

Abstract The outstanding remanent polarization of 40 µC cm–2 reported for a 10 nm thin La:HfO2 film in 2013 has attracted much attention. However, up to now, no explanation for this large remanent polarization has been presented. Density functional theory and X‐ray diffraction are used to shine light onto three major…

Semiconductor materials and devicesMXene and MAX Phase MaterialsFerroelectric and Negative Capacitance Devices

Supramolecular‐Macrocycle‐Based Crystalline Organic Materials

Yujuan Zhou、Kecheng Jie、Run Zhao 等 4 位作者2019-09-19Advanced Materials

Supramolecular macrocycles are well known as guest receptors in supramolecular chemistry, especially host-guest chemistry. In addition to their wide applications in host-guest chemistry and related areas, macrocycles have also been employed to construct crystalline organic materials (COMs) owing to their particular st…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

The Causes of Degradation of Perovskite Solar Cells

Juan Bisquert、Emilio J. Juárez‐Pérez2019-09-19The Journal of Physical Chemistry Letters

Peer reviewed

Perovskite Materials and ApplicationsConducting polymers and applicationsAdvanced battery technologies research

Advanced Nanotechnology Leading the Way to Multimodal Imaging‐Guided Precision Surgical Therapy

Cong Wang、Wenpei Fan、Zijian Zhang 等 6 位作者2019-09-19Advanced Materials

Surgical resection is the primary and most effective treatment for most patients with solid tumors. However, patients suffer from postoperative recurrence and metastasis. In the past years, emerging nanotechnology has led the way to minimally invasive, precision and intelligent oncological surgery after the rapid deve…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsPhotoacoustic and Ultrasonic Imaging

Complete Additively Manufactured (3D-Printed) Electrochemical Sensing Platform

Eduardo M. Richter、Diego P. Rocha、Rafael M. Cardoso 等 7 位作者2019-09-19Analytical Chemistry

Herein, we report a complete additively manufactured (AM) electrochemical sensing platform. In this approach, a fully AM/3D-printed electrochemical system, using a conventional low-cost 3D printer (fused deposition modeling) fabricating both the conductive electrodes and the nonconductive/chemically inert electrochemi…

Electrochemical sensors and biosensorsConducting polymers and applicationsNeuroscience and Neural Engineering

Advances in the Application of Magnetic Nanoparticles for Sensing

Lucy Gloag、Milad Mehdipour、Dongfei Chen 等 5 位作者2019-09-19Advanced Materials

Magnetic nanoparticles (MNPs) are of high significance in sensing as they provide viable solutions to the enduring challenges related to lower detection limits and nonspecific effects. The rapid expansion in the applications of MNPs creates a need to overview the current state of the field of MNPs for sensing applicat…

Nanoparticle-Based Drug DeliveryElectrostatics and Colloid InteractionsCharacterization and Applications of Magnetic Nanoparticles

Enhanced sensing performance of ZnO nanostructures-based gas sensors: A review

Vijendra Singh Bhati、Mirabbos Hojamberdiev、Mahesh Kumar2019-09-19Energy Reports

Metal oxide semiconductors-based gas sensors have been extensively explored due to their high sensing response, cost-effectivity, long-term stability, and simple fabrication. However, their utilization at low operating temperature is still challenging. Thus, reduction in power consumption is highly essential for long-…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsAdvanced Chemical Sensor Technologies

Fermi-arc diversity on surface terminations of the magnetic Weyl semimetal Co 3 Sn 2 S 2

Noam Morali、Rajib Batabyal、Pranab Kumar Nag 等 10 位作者2019-09-19Science

Magnetic Weyl semimetals Weyl semimetals (WSMs)—materials that host exotic quasiparticles called Weyl fermions—must break either spatial inversion or time-reversal symmetry. A number of WSMs that break inversion symmetry have been identified, but showing unambiguously that a material is a time-reversal-breaking WSM is…

2D Materials and ApplicationsTopological Materials and PhenomenaIron-based superconductors research

Electronic Skin: Recent Progress and Future Prospects for Skin‐Attachable Devices for Health Monitoring, Robotics, and Prosthetics

Jun Chang Yang、Jaewan Mun、Se Young Kwon 等 6 位作者2019-09-19Advanced Materials

Recent progress in electronic skin or e-skin research is broadly reviewed, focusing on technologies needed in three main applications: skin-attachable electronics, robotics, and prosthetics. First, since e-skin will be exposed to prolonged stresses of various kinds and needs to be conformally adhered to irregularly sh…

Advanced Sensor and Energy Harvesting MaterialsAdvanced Memory and Neural ComputingConducting polymers and applications

(INVITED) Impurities in large scale produced Nd-doped phosphate laser glasses. I. Cu ions

Yongchun Xu、Meng Li、Congjuan Wang 等 7 位作者2019-09-19Optical Materials X

Impurity ions such as transition metals and rare earth metals in Nd-doped phosphate laser glasses will degrade Nd-laser performance, among which Cu is the most harmful. Divalent Cu2+ not only results in an optical loss at Nd-laser wavelength, but also reduces the energy storage for laser amplification. A large-scale p…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Effect of cold rolling and annealing temperature to the characteristics of α + β' phases in Cu-29.5Zn-2.5Al alloy produced by gravity casting

Irene Angela、Imam Basori、Bondan Tiara Sofyan2019-09-19Journal of Mining and Metallurgy Section B Metallurgy

Al-brass alloys (Cu29.5Zn2.5Al wt. %) were produced by gravity casting and homogenized at 800?C for 2 h, resulting in a binary phase morphology identified as cubic ? and martensitic ?? phases through X-ray diffraction (XRD). Samples were then subsequently cold rolled and annealed at 150, 300, 400, and 600?C for 30 min…

Aluminum Alloy Microstructure PropertiesMetallurgy and Material FormingMetallurgy and Material Science

Ab initio molecular dynamics simulations of the ferroelectric-paraelectric phase transition in sodium nitrite

Johannes P. Dürholt、Rochus Schmid2019-09-19Physical Review Materials

This paper reports on the first ab initio molecular dynamics study of the ferroelectric sodium nitrite, shedding light on its ferroelctric-paraelectric phase transition. The remnant polarization ${P}_{r}$ was calculated using a Mulliken population analysis and maximally localized Wannier functions. Especially the Wann…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Inelastic X-Ray Scattering and X-Ray Powder Diffraction Applications

Alessandro Cunsolo、Margareth K.K.D. Franco、Fabiano Yokaichiya2019-09-19IntechOpen eBooks

This book illustrates a few exemplary scientific topics addressed through the use of two complementary x-ray scattering techniques: inelastic x-ray scattering and x-ray powder diffraction. These scattering methods are the focus of the two main sections of this book. These sections are subdivided into chapters discussi…

X-ray Diffraction in Crystallography

Materials selection rules for optimum power factor in two-dimensional thermoelectrics

Adithya Kommini、Zlatan Akšamija2019-09-19Journal of Physics Materials

Abstract Two-dimensional (2D) materials have emerged as the ideal candidates for many applications, including nanoelectronics, low-power devices, and sensors. Several 2D materials have been shown to possess large Seebeck coefficients, thus making them suitable for thermoelectric (TE) energy conversion. Whether even hi…

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Modulation of LSPR spectra and enhanced RI-sensitivity through symmetry breaking in hollow gold nanoprism

Jyotirban Dey、Bidhan Hazra、Manabendra Chandra2019-09-19The Journal of Chemical Physics

Optical responses of plasmonic nanostructures can be tailor-made by judiciously controlling their structural parameters. Here in this article, we describe how symmetry-breaking influences the optical properties of an anisotropic hollow nanostructure, a hollow gold nanoprism (HGN). We find that the introduction of stru…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Understanding Adsorption Behavior of Periodic Mesoporous Organosilica Having a Heterogeneous Chemical Environment: Selective Coverage and Interpenetration of Adsorbates inside the Channel Wall

Hae Sung Cho、Yongjin Lee、Jiasheng Wu 等 6 位作者2019-09-19The Journal of Physical Chemistry C

Gas adsorption of periodic mesoporous organosilica (PMO) containing bipyridine ligands within the framework (BPy-PMO) has been studied by in situ gas adsorption powder X-ray diffraction (XRD) analysis. Both Ar and CO 2 molecules showed strong affinity with organic moiety than silica during monolayer adsorption, even t…

Metal-Organic Frameworks: Synthesis and ApplicationsZeolite Catalysis and SynthesisMesoporous Materials and Catalysis