Materials Literature
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Small molecular probes able to act as sensors are of enormous interest thanks to their multiple applications. Here, we report on the development of a novel supramolecular dual viscosity and polarity probe based on the foldamer concept, which increases the resolution limits of traditional probes at low viscosity values…
The high-pressure behavior of layered CrOCl is shown to be governed by non-bonded interactions between chlorine atoms in relation to a rigid framework composed of Cr and O atoms. The competition between optimizing intra- and interlayer Cl-Cl distances and the general trend towards denser packing defines a novel mechan…
Ceramics of composition (1− x )BaTiO 3 – x Bi(Zn 1/2 Ti 1/2 )O 3 ( BT ‐ BZT ) were prepared by solid‐state synthesis; they have been shown to exhibit excellent properties suited for high‐temperature dielectric applications. The X‐ray diffraction data showed a single‐phase perovskite structure for all the compositions…
Recent experimental realization of ${\mathrm{CaSi}}_{2}$ paves the way of restoring the Dirac dispersion in layered materials by means of intercalation [E. Noguchi et al., Adv. Mater. 27, 856 (2015)]. Here we investigate this new material with several possible stacking sequences within ab initio calculations. The robu…
Graphene and hexagonal boron nitride (h-BN) nanoribbons of diverse widths and edge geometries are laterally repeated to form commensurate, single-layer, hybrid honeycomb structures. The resulting composite materials appear as continuous, one atom thick stripes of graphene and BN having the average mechanical propertie…
Graphene is being widely investigated as a material to replace activated carbon in supercapacitor (electrochemical capacitor) electrodes. Supercapacitors have much higher energy density, but are typically slow devices (∼0.1 Hz) compared to other types of capacitors. Here, top-down semiconductor processing has been app…
Rheological behavior of aqueous suspensions containing nanometer-sized powders is of relevance to many branches of industry. Unusually high viscosities observed for suspensions of nanoparticles compared to those of micron size powders cannot be explained by current viscosity models. Formation of so-called hydration la…
Quantum dots (QDs) and graphene are both promising materials for the development of new-generation optoelectronic devices. Towards this end, synergic assembly of these two building blocks is a key step but remains a challenge. Here, we show a one-step strategy for organizing QDs in a graphene matrix via interfacial se…
An emerging topic of our days is nanoscience and nanotechnology successfully applied in the food industry. Characteristics such as size, surface area and morphology can modify the basic properties and the chemical reactivity of the nanomaterials. The breakthrough of innovative materials, processes, and phenomena at th…
In the present study, we have demonstrated the excitation energy transfer (EET) from silicon quantum dots (Si QDs) to silver nanoparticles (Ag NPs) and its modulation in the presence of cetyltrimethylammonium bromide (CTAB) surfactant by means of steady-state and time-resolved photoluminescence (PL) spectroscopy. Sign…
The electronic and magnetic properties of EuAlO3 are calculated by first-principles full-potential linearized augmented plane wave (FP-LAPW) method based on density functional theory (DFT). The exchange and correlation potential is treated with different approximations: mBJ and GGA + U. Coulomb repulsion (U) has been…
Urea intercalated layered material nanohybrid formulations based on two types of layered clays, layered double hydroxides and montmorillonite were developed for agricultural applications as slow release nitrogen plant nutrient formulations. The resulting nanohybrids were prepared by the intercalation of urea between t…
Voltage controlled 180° magnetization reversal has been achieved in BiFeO3-based multiferroic heterostructures, which is promising for the future development of low-power spintronic devices. However, all existing reports involve the use of an in-plane voltage that is unfavorable for practical device applications. Here…
A systematic spin-polarized density functional theory (DFT) study of hydrogen interaction with pristine and Rh-decorated zigzag (8,0) single-walled carbon nanotubes (SWCNTs) was performed. The most stable decoration site for Rh atoms as well as atomic and molecular hydrogen adsorption inside and outside the SWCNT was…
Atomically thin semiconducting transition-metal dichalcogenides have been attracting lots of attentions, particularly, molybdenum disulfide (MoS2) monolayers show promising applications in field effect transistors, optoelectronics and valleytronics. However, the controlled synthesis of highly crystalline MoS2 remain a…
In this paper, we perform a comparative study based on ab initio modeling for perovskite $AB{\mathrm{O}}_{3}$ (001) surfaces and surface defect energetics in order to understand the influence of polarity and redox active Mn in the $\mathrm{LaMn}{\mathrm{O}}_{3}$ system. We consider $\mathrm{LaMn}{\mathrm{O}}_{3},\phan…
The ability to engineer surfaces at the supramolecular level by controlled integration of specific chemical units through substrate‐independent methodologies represents one of the new paradigms of contemporary materials science. Here, a method is reported to form multifunctional supramolecular coatings through simple…
© 2015 Optical Society of America. This work reports the mid-infrared emission properties around 2 μm in Ho3+/Yb3+ codoped germanate glasses. The glass not only possesses good chemical durability and good thermal stability but also has high midinfrared transmittance around 2 μm (90%). In addition, the glass possesses…
Perfluoropentane (PFP) gas filled biodegradable iron-doped silica nanoshells have been demonstrated as long-lived ultrasound contrast agents. Nanoshells are synthesized by a sol-gel process with tetramethyl orthosilicate (TMOS) and iron ethoxide. Substituting a fraction of the TMOS with R-substituted trialkoxysilanes…
3D architecture V2O5 nanoribbon/reduced graphene oxide is successfully fabricated as an electrode material for supercapacitors. In combination with the advantages from the good rate performance of carbon-based materials and the high specific capacitance of metal oxides, as well as its 3D architecture, this material sh…