Materials Literature
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Abstract We report that aliphatic primary and secondary amines completely solubilize crosslinked silicone resins and rubber compositions at room temperature. The solubilization is attributed to nucleophilic cleavage of SiO bonds by amines, which apparently occurs selectively at crosslinking sites. The selectivity may…
The anodic behavior of AISI 304 stainless steel in 1M hydrochloric acid solution at 25 C has been studied at different electrode potentials under static conditions and during straining at 40%/minute. From the potential-time curves, current-time curves, and net anodic current densities, it is concluded that a film form…
Davies and Jones have shown that if the configurational state of a liquid is determined by two or more order parameters that freeze in at the glass transition temperature Tg(P), the Ehrenfest relation, r=ΔβΔCp/TV (Δα)2=1, valid if there is one such parameter, is converted to an inequality r?1. DiMarzio has shown corre…
Abstract The changes in conformation undergone by α‐gelatin molecules on quenching aqueous solutions to below the temperature at which they can gel have been monitored by nuclear magnetic resonance and dielectric relaxation techniques. The relative rates of these conformational transitions are compared with changes in…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRearrangement of N-substituted porphyrins. Preparation and structure of homoporphyrinsH. J. Callot and Theophile TschamberCite this: J. Am. Chem. Soc. 1975, 97, 21, 6175–6178Publication Date (Print):October 1, 1975Publication History Published online1 May 2002Published iniss…
Abstract The kinetics of initiation of the polymerization of 2,2,5,5‐tetramethyl‐1‐oxa‐2,5‐disilacyclopentane ( 2 ) with sodium phenyldimethylsilanolate 1a and two of its phenyl substituted derivatives was investigated as model reaction for studying the initiation and crosspropagation steps in anionic polymerization o…
R. H. Ritchie, C. J. Tung, V. E. Anderson, J. C. Ashley, Electron Slowing-Down Spectra in Solids, Radiation Research, Vol. 64, No. 1, Symposium on the Distribution of Secondary Electrons from Ionizing Collisions (Oct., 1975), pp. 181-204
The existence of the Kα2 lines in powder diffractograms has always obscured the interpretation of the diffraction patterns. Studies involving integrated intensity measurements, peak intensities and line broadening have been hampered owing to these extraneous lines. Crystal monochromators are ineffective for eliminatin…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of stable homopolyatomic anions of antimony, bismuth, tin, and lead. Crystal structure of a salt containing the heptaantimonide(3-) anionJohn D. Corbett, Douglas G. Adolphson, Don J. Merryman, Paul A. Edwards, and Frank J. ArmatisCite this: J. Am. Chem. Soc. 1975,…
PPO/iPS blends of various compositions have been crystallized isothermally and by solvent-induced treatment from the glassy state. The crystallinity as a function of composition has been determined from the integral scattering of the crystalline and amorphous regions. Applying Hosemann’s concept of the paracrystal, cr…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReaction of butyllithium with transition metal trichalcogenidesRussell R. Chianelli and Martin B. DinesCite this: Inorg. Chem. 1975, 14, 10, 2417–2421Publication Date (Print):October 1, 1975Publication History Published online1 May 2002Published inissue 1 October 1975https:/…
The effects of salt and distilled water environments on fatigue-crack growth rates have been evaluated for an X-65 line-pipe steel. Tests were conducted over a frequency range between 10 and 0.01 Hz, under conditions of cathodic potential and free corrosion. A distinct pattern in the functional dependence of growth ra…
The total polarization due to molecular dipoles in a glassy electret is computed using an Onsager cavity approach. From this result, all the possible contributions to the piezoelectric and pyroelectric coefficients are considered. It is shown that there are major contributions from the variation in dielectric constant…
The incoherent scattering law for neutron quasi-elastic scattering in liquid crystals is calculated using a classical formalism including (anisotropic) self-diffusion, rotational motion along the long molecular axis and short time vibrational behaviour. Explicit expressions are given for oriented as well as for unorie…
An extracellular coat from glycerol-induced myxospores of Myxococcus xanthus has been isolated and characterized. Coats were examined chemically and by using both transmission and scanning electron microscopy. On a dry weight basis, approximately 75% of the coat is polysaccharide composed entirely of galactosamine and…
A large deformed grain of plagioclase (Anno) contains numerous deformation (kink) bands and fewer broader kink-like zones that may have involved fracturing. The plagioclase has been recrystallized along narrow zones of relatively high strain. The orientations of the new grains are close to that ofthe original grain, i…
The threshold displacement energy E d, has been determined by high-voltage electron microscopy for copper and vanadium as a function of orientation with the following results: for copper, E d⟨100⟩=27 eV, E d⟨110⟩=18 eV, E d⟨111⟩=29 eV and for vanadium, E d⟨100⟩=30eV, E d⟨110⟩=39eV, E d⟨111⟩=34eV. The minimum threshold…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTX-ray photoelectron spectroscopic study of cobalt(II) Schiff base complexes and their oxygenation productsJ. H. Burness, J. G. Dillard, and L. T. TaylorCite this: J. Am. Chem. Soc. 1975, 97, 21, 6080–6088Publication Date (Print):October 1, 1975Publication History Published o…
Abstract This review of the literature shows that there have been many attempts to modify or revise the original definition of halloysites as distinguished from kaolinites, which was based on the greater water content of the halloysites. In general, these various attempts have arrived at definitions of halloysites as…
Interferometric measurements of the linear thermal expansion coefficients αc and αa in the c and a axial directions of well-orientated hexagonal pyrolytic boron nitride are reported for temperatures between approximately 80 and 780 K. The primary data for the direction parallel to the c-crystallographic axis yield smo…