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Chemistry and biology of vitamin B6. 32. Selective modification of the .alpha.4 position of pyridoxol. 4-Vinyl analog of pyridoxal, a potent antagonist of vitamin B6

W. Korytnyk、Gerald B. Grindey、Burkhard Lachmann1973-07-01Journal of Medicinal Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemistry and biology of vitamin B6. 32. Selective modification of the .alpha.4 position of pyridoxol. 4-Vinyl analog of pyridoxal, a potent antagonist of vitamin B6W. Korytnyk, G. B. Grindey, and B. LachmannCite this: J. Med. Chem. 1973, 16, 7, 865–867Publication Date (Prin…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismCancer Research and Treatments

Crystal Structure and Phase Transformations of Sodium Diarsenate, Na4As2O7

Kiang Y. Leung、C. Calvo1973-07-01Canadian Journal of Chemistry

Sodium diarsenate at room temperature is monoclinic with lattice parameters a = 5.969(1), b = 10.126(1), c = 12.272(3) Å and β = 92.87(2)°. There are four formula units per cell with space group C2/c. The structure was refined by full-matrix least-squares to a final R value of 0.027 utilizing 1157 reflections measured…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Fraunhofer Diffraction at Apertures in the Form of Regular Polygons. II

J. Komrska1973-07-01Optica Acta International Journal of Optics

In this second contribution the Fraunhofer diffraction patterns from apertures of the form of an equilateral triangle, a square, a regular pentagon, a hexagon and an octagon are compared with the calculated maps of the intensity distribution. For each shape of the aperture the first few maxima and minima of the intens…

Advanced X-ray Imaging TechniquesOptical Coatings and GratingsNear-Field Optical Microscopy

Atomizing molten metals — a review

C.F. Dixon1973-07-01Canadian Metallurgical Quarterly

(1973). Atomizing molten metals — a review. Canadian Metallurgical Quarterly: Vol. 12, No. 3, pp. 309-322.

Metallurgical Processes and ThermodynamicsMetallurgy and Material Science

Reaction of phenyl isocyanate with N-methyl-2-pyrrolidinone

R. Richter、H. Ulrich1973-07-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReaction of phenyl isocyanate with N-methyl-2-pyrrolidinoneReinhard Richter and Henri UlrichCite this: J. Org. Chem. 1973, 38, 15, 2614–2617Publication Date (Print):July 1, 1973Publication History Published online1 May 2002Published inissue 1 July 1973https://pubs.acs.org/do…

Synthesis and Reactivity of Sulfur-Containing CompoundsPolymer Synthesis and CharacterizationEducational Robotics and Engineering

Stop bands for optical wave propagation in cholesteric liquid crystals*

C. Elachi、C. Yeh1973-07-01Journal of the Optical Society of America

The stop-band characteristics of waves in cholesteric-liquid-crystal half-space are investigated using the exact wave solution, the Floquet theorem, and the corresponding Brillouin diagram. The other half-space is filled with a uniform dielectric medium. By appropriate choice of the dielectric constant of the uniform…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsOptical Polarization and Ellipsometry

Vibrational spectra of some Group Vb halides. III. A far-infrared and Raman spectral study of some Hexahalogeno-, Pentahalogeno-, and Tetrahalogeno-bismuthate(III) and -antimonate(III) salts

MA Hooper、DW James1973-07-01Australian Journal of Chemistry

Vibrational spectra of a series of halogeno-complex ions of antimony(III) and bismuth(III) are reported. Results of crystal spectra are discussed in terms of the structural environment and a comparative study of Raman solution and solid state spectra is given. Some force constants for hexahalogeno species on a modifie…

Solid-state spectroscopy and crystallography

Heat capacities of polyethylene from 2 to 360 K. I. Standard samples of linear and branched polyethylene whole polymer

Shu‐Sing Chang、A. B. Bestul1973-07-01Journal of Research of the National Bureau of Standards Section A Physics and Chemistry

Heat capacities of two well characterized polyethylene samples have been measured from 2 to 360 K in a precision vacuum adiabatic calorimeter. The two samples are derived from the same stocks from which NBS standard reference materials (SRM) 1475 and 1476 for linear and branched polyethylene whole polymers, respective…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesAdsorption, diffusion, and thermodynamic properties of materials

The origin dependence of Wyckoff site description of a crystal structure

L. L. Boyle、J. E. Lawrenson1973-07-01Acta Crystallographica Section A

When describing a crystal structure in terms of the Wyckoff sites occupied, equivalent alternatives often arise because the choice of origin of coordinates is subject to arbitrariness remaining within the standard choice in International Tables for X-ray Crystallography. The problem is explained and simple tables whic…

X-ray Diffraction in CrystallographyChemical Thermodynamics and Molecular StructureHistory and advancements in chemistry

Infrared and Raman spectra of lithium and ammonium nitrate solutions in liquid ammonia

Derek J. Gardiner、Ronald E. Hester、William Ε. L. Grossman1973-07-01The Journal of Chemical Physics

Vibrational spectra, most of them obtained from Raman scattering, are reported for LiNO3 and NH4NO3 solutions in liquid ammonia, ranging from dilute to the compositions LiNO3/1.6NH3 and NH4NO3/1NH3. All the spectra were obtained from solutions at ambient temperatures. Large changes in the N–H stretching region are cor…

Spectroscopy and Quantum Chemical StudiesSolid-state spectroscopy and crystallographyChemical and Physical Properties in Aqueous Solutions

Water binding and irreversible dehydration processes in cellulose acetate membranes

Moshe A. Frommer、M. Shporer、R. Messalem1973-07-01Journal of Applied Polymer Science

Abstract The relative amounts of freezing and nonfreezing water in various water‐wet cellulose acetate (CA) membranes were determined by NMR techniques, from the initial heights of the water component in the free induction decay (MNR intensity). The results suggest that (1) a significant fraction of the water in vario…

High voltage insulation and dielectric phenomenaAdvanced Cellulose Research Studies

Raman Scattering by α‐HgS (Cinnabar)

M. A. Nusimovici、A. Meskaoui1973-07-01physica status solidi (b)

Abstract Raman scattering is observed in first and second order by optically active phonons in mercury sulphide HgS having the cinnabar structure (α‐HgS). For the first time these spectra could be obtained in polarised light and interpreted using selection rules derived by group theoretical considerations. The experim…

Quantum Dots Synthesis And PropertiesAdvanced Semiconductor Detectors and MaterialsOptical properties and cooling technologies in crystalline materials

High Frequency Conductivity in Cobalt-Iron Ferrite

Yootarou Yamazaki、Minoru Satou1973-07-01Japanese Journal of Applied Physics

The frequency dependence of the ac conductivity of polycrystalline cobalt-iron ferrite Co 3- x Fe x O 4 (1.89≦ x ≦2.08) has been measured in the frequency range 1 kHz∼200 MHz and the temperature range 130∼300 K. The measured conductivity can be expressed as the sum of two kinds of conductivity σ 1 and σ 2 . σ 1 corres…

Magnetic Properties and Synthesis of FerritesMagnetic Properties and ApplicationsElectrochemical Analysis and Applications

Kerr response of nematic liquids

A. R. Johnston1973-07-01Journal of Applied Physics

The Kerr response of seven nematic substances has been measured just above their nematic-isotropic transition temperature, in their isotropic state. If the reciprocal of the Kerr constant B is plotted against temperature, a linear relationship analogous to the Curie-Weiss dielectric relationship in ferroelectrics is f…

Liquid Crystal Research AdvancementsPhase-change materials and chalcogenidesMolecular spectroscopy and chirality

Liquid-phase sintering of magnetically isotropic and anisotropic compacts of BaFe12O19 and SrFe12O19

R. H. Arendt1973-07-01Journal of Applied Physics

This report shows that magnetically isotropic and anisotropic compacts of BaFe12O19 or SrFe12O19 sinter to high density with controlled microstructure in the presence of a liquid phase. The liquid-phase compositions are in the systems MO–SiO2 and MO–Al2O3–SiO2, M=Ba, Sr. Further, it is shown that systems containing MB…

Magnetic Properties and Synthesis of FerritesPigment Synthesis and Properties

Tungstovanadate heteropoly complexes. IV. Vanadium(IV) complexes

Charles M. Flynn、M. T. Pope1973-07-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTungstovanadate heteropoly complexes. IV. Vanadium(IV) complexesC. M. Flynn, Jr. and M. T. PopeCite this: Inorg. Chem. 1973, 12, 7, 1626–1634Publication Date (Print):July 1, 1973Publication History Published online1 May 2002Published inissue 1 July 1973https://pubs.acs.org/d…

Polyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation ReactionsPigment Synthesis and Properties

Spectral losses of unclad fibers made from high-grade vitreous silica

Peter K. Kaiser1973-07-01Applied Physics Letters

Spectral loss measurements performed between 0.5 and 1.15 μm with up to 32-m-long unclad fibers drawn from Suprasil W1, Spectrosil WF, and Corning 7943 synthetic vitreous silica demonstrated that bulk glasses with total losses well below 10 dB/km at certain wavelengths of interest for future optical communication syst…

Optical Network TechnologiesGlass properties and applicationsPhotonic Crystal and Fiber Optics

Regulation of Intracellular Proteolysis in Escherichia coli

Martin J. Pine1973-07-01Journal of Bacteriology

Individual nitrogenous metabolites have been examined as regulating agents for the breakdown of intracellular proteins in Escherichia coli. Generally, NH(4) (+) is the most effective regulator. Its depletion progressively increases the basal proteolytic rate to maximum in most strains when the doubling time is increas…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

A hand-held friction meter

J.S. Comaish、P.R.H. HARBOROW、D.A. HOFMAN1973-07-01British Journal of Dermatology

A portable hand‐held friction meter has been devised which will measure the coefficient of friction between a reference material and skin at any body site regardless of position. The reference surface can be made of any of a number of materials, such as steel, nylon, PTFE, leather or even fabrics. The effects of disea…

Textile materials and evaluations

Nickel and Chromium Plating

H. Silman1973-07-01British Corrosion Journal

"Nickel and Chromium Plating." British Corrosion Journal, 8(4), p. 147

Metallurgy and Material Science