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π–π Aggregation in metalloporphyrins: causative factors

Raymond J. Abraham、Fahimeh Eivazi、Harry Pearson 等 4 位作者1976-01-01Journal of the Chemical Society Chemical Communications

The strength of aggregation in PdII, NiII, ZnII, and CdII metalloporphyrins is shown by n.m.r. spectroscopy to depend upon interaction of the metal ion with the porphyrin π-system; within a selected series of 2,4-disbustituted deuteroporphyrin-IX dimethyl esters complexed with a constant metal ion the aggregation is f…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistrySurface Chemistry and Catalysis

Some effects of morphology on oxidation and stabilization of polyolefins

Norman Ć. Billingham、Paul Prentice、Timothy J. Walker1976-01-01Journal of Polymer Science Polymer Symposia

Abstract Previous work on the effects of crystallinity on the autoxidation of polyolefins is briefly reviewed and shows that polyethylene and polypropylene oxidize exclusively in the amorphous phase. Measurements of the rate of oxidation of poly(4‐methyl pentene‐1) (P4MP) show that the oxidation is first‐order in oxyg…

Polymer crystallization and propertiesMicroplastics and Plastic PollutionPolymer Science and PVC

The Cathodic Corrosion of Aluminum

E. P. G. T. van de Ven、H. Koelmans1976-01-01Journal of The Electrochemical Society

Abstract not Available.

Civil and Structural Engineering ResearchMaterial Properties and Applications

Depolarization effects in thin ferroelectric films

P. Würfel、I. P. Batra1976-01-01Ferroelectrics

For a ferroelectric in form of a thin plate with the polarization perpendicular to the surfaces it is demonstrated that for the ferroelectric state to be stable the polarization discontinuity must be compensated by free charge. In thermal equilibrium the charge compensation can never be complete. Depolarization fields…

Silicon and Solar Cell TechnologiesPhase-change materials and chalcogenidesSemiconductor materials and interfaces

Influence of Irradiation Temperature, Burnup, and Fuel Composition on Gas Pressure (Xe, Kr, CO, CO 2 ) in Coated Particle Fuels

G.W. Horsley、G. Weldrick、J.A. Turnbull 等 4 位作者1976-01-01Journal of the American Ceramic Society

Relations have been derived from gas analyses of irradiated PyC‐coated UO 2 fuel particles that enable the quantity of permanent rare gas (Xe+Kr) released within the particle to be predicted from known conditions of irradiation temperature, time, and burnup. The experimentally determined influence of fissions in urani…

Nuclear reactor physics and engineeringRadioactive element chemistry and processingNuclear Materials and Properties

Theory of non-linear dielectric effects in liquids

J. Małecki1976-01-01Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics

A general theory of non-linear dielectric phenomena in liquids is proposed with the fundamental assumption, supported by a large body of experimental data, that such phenomena are specifically sensitive to molecular association processes due to electrostatic and chemical interactions. The relationships derived provide…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation

Dielectric nonlinearity of the displacive ferroelectrics at UHF

O. G. Vendik1976-01-01Ferroelectrics

Consideration is given for the dielectric nonlinearity of ferroelectrics both in a strong static field with respect to the weak UHF field and in the strong UHF field. The dynamic theory of a soft mode is used as a basis for description of the phenomena. The parametric process in the strong UHF field is discussed. The…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Static strain waves in cholesteric liquid crystals. - I. homeotropic boundary conditions

M. J. Press、A. S. Arrott1976-01-01Journal de physique

Periodic strain waves have been studied using dilute solutions of cholesteric liquid crystals in nematic solvents. Experimental observations are in qualitative agreement with computer solutions of one constant elasticity theory. For the boundary conditions of parallel plates with homeotropic pinning of the director fi…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationCharacterization and Applications of Magnetic Nanoparticles

Stress Corrosion—New Approaches

H. Lee Craig1976-01-01OpenAlex

Description The symposium on New Approaches to Stress Corrosion was presented at the Seventy-eighth Annual Meeting of the American Society for Testing and Materials held in Montreal, Canada, 22-27 June 1975. Committee G01 on Corrosion of Metals sponsored the symposium. H. L. Craig, Jr., University of Miami, presided a…

Corrosion Behavior and InhibitionConcrete Corrosion and Durability

Aggregation of Polyion Complexes between Synthetic Polyelectrolytes

Eishun Tsuchida、Kôji Abe、Masahisa Honma1976-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAggregation of Polyion Complexes between Synthetic PolyelectrolytesEishun Tsuchida, Koji Abe, and Masahisa HonmaCite this: Macromolecules 1976, 9, 1, 112–117Publication Date (Print):January 1, 1976Publication History Published online1 May 2002Published inissue 1 January 1976…

Hydrogels: synthesis, properties, applicationsSurfactants and Colloidal SystemsPolymer Surface Interaction Studies

Atomic geometry of the low‐index surfaces of ZnO: LEED analysis

A. R. Lubinsky、C. B. Duke、S. C. Chang 等 5 位作者1976-01-01Journal of Vacuum Science and Technology

Low‐energy‐electron‐diffraction (LEED) intensities have been measured for the (0001), (0001̄), (101̄0), and (112̄0) faces of ZnO and analyzed using a dynamical multiple‐scattering model of the diffraction process. Atomic and ionic overlapping charge density models are used to construct the electron–ion‐core potential.…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Relationship Between Mechanical Properties, Microstructure, and Fracture Topography in α + β Titanium Alloys

J. C. Chesnutt、CG Rhodes、JC Williams1976-01-01OpenAlex

The influence of forging schedule and subsequent heat treatment on the microstructure and mechanical properties of three α + β titanium alloys has been investigated. The alloys studied were Ti-6Al-4V, Ti-6Al-6V-2Sn, and Ti-6Al-2Sn-4Zr-6Mo. The microstructural comparisons included (α + β) finished and β-processed mater…

Fatigue and fracture mechanicsMagnesium Alloys: Properties and ApplicationsTitanium Alloys Microstructure and Properties

The thermal‐mechanical degradation of high density polyethylene

G. R. Rideal、John C. Padget1976-01-01Journal of Polymer Science Polymer Symposia

Abstract The changes in molecular structure of high density polyethylene which can take place during processing have been studied using a nitrogen blanketed Brabender plastograph to simulate processing conditions. At high melt temperatures (> 290°C) decreases in melt viscosity and a narrowing of molecular weight di…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Thermal diffusivity of dispersed composites

H. J. Lee、Rex N. Taylor1976-01-01Journal of Applied Physics

The thermal diffusivity of a series of copper whiskers-copper spheres dispersed in solder was measured by the flash method at room temperature. These diffusivity values are compared with the calculated thermal diffusivity values using effective thermal conductivity values computed with Maxwell’s dispersion equation. T…

Thermal properties of materialsComposite Material MechanicsHygrothermal properties of building materials

The magnetic barkhausen effect

J.C. McClure、Klaus Schröder1976-01-01C R C Critical Reviews in Solid State Sciences

When the magnetization of a ferromagnet (in this paper “ferromagnet” will often include “fernmagnet”) is changed under the influence of an applied magnetic field, the magnetization, particularly in the vicinity of the coercive force, is not smooth function of the field but rather shows a structure composed of many ind…

Magnetic Properties and ApplicationsGeomagnetism and Paleomagnetism StudiesGeophysics and Sensor Technology

Effect of solute size and shape on orientational order in liquid crystal systems

Bengt Kronberg、D. F. R. Gilson、Donald Patterson1976-01-01Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics

Wide-line n.m.r. has been used to obtain the order parameter, S, as a function of temperature, for nematic p-methoxybenzylidine-p-n-butylaniline (MBBA) containing solutes of differing size and shape. These consisted of : (i) anisotropic molecules, capable of correlating their orientations with MBBA molecules, viz n-he…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

L'effet néphélauxétique pour les configurations 4fN en phase solide

P. Caro、O. Beaury、E. Antic1976-01-01Journal de physique

On étudie les variations de la position énergétique des niveaux 2 P1/2(4f3), 5Do(4f 6 ) et 6P7/2(4f7) par dopage des éléments correspondants dans des matrices isomorphes, ou structuralement apparentées, à travers la série des lanthanides. On montre que lorsqu'un ion 4f N est introduit dans un solide, les paramètres de…

Thermography and Photoacoustic TechniquesElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

An evaluation of cation exchange capacity measurements for soils in the tropics

A. S. R. Juo、S.A. Ayanlaja、J. A. Ogunwale1976-01-01Communications in Soil Science and Plant Analysis

Comparisons of CEC and exchange acidity neasurements were made on a group of selected West African soils using three commonly used analytical procedures, namely, neutral‐acetate displacement, BaCl2‐TEA leaching at pH 8, and unbuffered KCl extraction. The three methods gave large differences in CEC values which followe…

Clay minerals and soil interactionsIron oxide chemistry and applicationsMine drainage and remediation techniques

Controlled Surface Flaws in Hot‐Pressed SiC

J. J. Petrovic、L.A. Jacobson1976-01-01Journal of the American Ceramic Society

Controlled semi‐elliptical surface flaws were produced in hot‐pressed SiC by Knoop microhardness indentation. Flawed specimens were placed in 4‐point bending in order to determine their critical stress intensity factor, K IC , at both room and high temperatures. Room‐temperature fracture and K IC values after annealin…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced Surface Polishing Techniques

Thermal Fatigue of Materials and Components

D. A. Spera、D. F. Mowbray1976-01-01OpenAlex

Description The Symposium on Thermal Fatigue of Materials and Components was presented at the meeting held in New Orleans, 17-18 Nov. 1975. The symposium was sponsored by The American Society for Testing and Materials through its Committee E09 on Fatigue. D. A. Spera, National Aeronautics and Space Administration Lewi…

Fatigue and fracture mechanicsMaterial Properties and ApplicationsMechanical and Thermal Properties Analysis