Materials Literature
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The magnetic anisotropy of R2Co17 and R2Co17−xTx compounds with R=Y, Ce, Pr, Nd, Th and T=Mn, Fe has been investigated. The directions of easy magnetization were determined by x-ray studies on oriented powders. The several R2Co17 compounds, except for Ce2Co17, have an easy basal plane; the behavior of Ce2Co17 could no…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSwelling, Crazing, and Cracking of an Aromatic Copolyether-Sulfone in Organic MediaR. P. Kambour, E. E. Romagosa, and C. L. GrunerCite this: Macromolecules 1972, 5, 4, 335–340Publication Date (Print):July 1, 1972Publication History Published online1 May 2002Published inissue…
The phenomenon of frequency-modulation (F M) sidebands induced with rf fields in the M\"ossbauer spectra of ferromagnetic materials is considered in detail. The general expression for the M\"ossbauer transition probability in the presence of rf acoustic vibrations is given and is derived on a quantum basis. The experi…
Abstract Alkoxides of transition metals, such as Fe, Ti, Nb, and Zr, were found to react with atmospheric carbon dioxide in benzene solution at 30°C. The measurement of CO2 volume absorbed and IR data suggest that transition metal alkoxides are partially carbonated.
It is demonstrated that argon-ion beams are effective in drilling holes in diamonds. Truncated conical holes were made with basal diameters as small as ∼0.375 mm and tapering to ∼0.05-mm diameter at the top. Larger holes with diameters at the two surfaces of 1.45 and 2.26 mm were milled through a 1.58-mm-thick diamond…
Abstract The thermal decomposition reactions of metal oxalato complexes in the solid state were studied by the TG and DSC methods. The results from TG indicated that the thermal stability of the anhydrous complex decreases approximately with the increase in the electron affinity of the central metal ion. From DSC, the…
Room‐temperature strengths are reported for titania and aluminum silicate in various biaxial stress states. Results are compared with failure criteria based on either energy or internal‐friction concepts. In general, more complete and reliable data for ceramic materials are needed before specific failure criteria can…
Abstract It has been demonstrated that the poly(vinyl fluoride) film can be fluorinated by exposing the polymer to an environment of fluorine under atmospheric pressure and at ambient temperature. Fluorine content, infrared spectra, thermal properties, and solubilities in the polar solvents were investigated for the f…
The rate of decomposition of PVDC is sensitive to differences in the method of preparation of the polymer. Polymers prepared by mass polymerization of very pure monomer were most stable. Emulsion polymerized PVDC degraded the fastest. The activation energy for the latter was 34.4 kcal/mole. Over the range of 130°–190°…
Ultrasonic interferometry was used to measure elastic‐wave velocities and moduli in six Na 2 O‐TiO 2 ‐SiO 2 glasses; three glasses contained 20 mol% TiO 2 and three 25 mol% TiO 2 . The elastic moduli and their pressure derivatives varied systematically with the SiO 2 /Na 2 O molar ratio of the glasses. In the group of…
Estimates have been made from electrode potential measurements of the composition and stability constants of the complexes formed by tin with citric, malic, oxalic and tartaric acids in solutions of the concentration range appropriate to canned fruits. The stability constants suggested are highest for oxalic acid, smu…
A neutron diffraction study of orthorhombic L‐histidine, C 6 H 9 N 3 O 2 , has been carried out. The structure belongs to space group P2 1 2 1 2 1 , with four molecules per unit cell. Cell parameters are: a = 5.175 (5) Å, b = 7.315 (8) Å and c = 18.75 (2) Å. A total of 618 unique reflections were used in the least‐squ…
β eucryptite, Li 2 O · Al 2 O 3 · 2SiO 2 , has a high-quartz-like structure. It crystallizes in the space group P 6 2 22. X-ray diffraction photographs of single crystals show, besides the main reflections of a high-quartz-like subcell, superstructure reflections which lead to doubling of the lattice constants of the…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOut-of-plane interactions in parallel-planar copper(II) dimers. Structure and magnetic properties of dibromobis(2-methylpyridine)copper(II)Phirtu Singh, David Y. Jeter, William E. Hatfield, and Derek J. HodgsonCite this: Inorg. Chem. 1972, 11, 7, 1657–1661Publication Date (P…
One unsymmetricly p,p′-disubstituted trans-stilben and more than 60 new phenylbenzoates are described (Tab. 1). These compounds show partly enantiotropic, partly monotropic nematic behaviour. Some low melting substances and especially eutectic mixtures of this class of compounds are useful as room-temperature nematic,…
The continuum approximation replaces a group of discrete dislocations by a continuous dislocation density. It is shown that this formalism possesses similarity solutions of the equations of motion with an arbitrary power law stress-velocity relationship in parallel with the similarity motions of the discrete group. Th…
The superstructure of β eucryptite shows an alternating sequence of Si and Al layers. For a Si-Al ratio of 1:1 only in this arrangement each AlO 4 or SiO 4 tetrahedron can be surrounded by four SiO 4 or AlO 4 tetrahedra, respectively. The Li atoms also have an ordered distribution. The following mean values of bond di…
The pair-production energy Ep for free carriers in silicon and germanium is measured using low-energy electrons (10–24 keV) as ionizing sources. The number of carriers generated is measured via a modified Haynes-Shockley technique with a pn junction collector and a super-posed drift field. Experimental values for Ep o…
The pitting of pure iron, and its alloys with chromium and copper, in neutral chloride solutions, has been studied using microscopy and time-lapse photography, and measurements have been made of local variations of pH value and electrode potential using micro-electrodes. Primary pitting at a few discrete points is fol…
Abstract Secondary nucleation in the potassium sulfate‐water system occurs by micro‐attrition processes over the entire 1.3‐26 μ size range of this study. Experimental nucleation rates were correlated with power‐law kinetics expressions in terms of supersaturation, the fourth moment of the parent seed‐crystal distribu…