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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIntramolecular environmental effects on the bonding of cyanide and carbonylRichard F. Fenske, Roger L. DeKock, and Allen C. SarapuCite this: Inorg. Chem. 1971, 10, 1, 38–43Publication Date (Print):January 1, 1971Publication History Published online1 May 2002Published inissue…
Abstract X‐ray, differential scanning calorimeter, and density measurements of the degree of crystallinity have been made on ethylene—propylene copolymers which range in composition from 60 to 100 mole‐% ethylene. At 23°C the degree of crystallinity was found to vary from zero to approximately 75 wt‐% in a regular man…
A scanning electron microscope study of oxide replicas of aluminum electrolytic capacitor foils has provided information on tunneling produced by a given etch. Tunnel morphology depends on microstructure of the aluminum and on etching conditions. With increasing current density in an electrochemical etch, the number o…
The structures of Hg2F2, Hg2Cl2, and Hg2Br2 have been reinvestigated on the basis of single crystal data; the intermetallic distances differ from those earlier reported and show no correlation with the electronegativity of the halogen.
Abstract Synergism in poly(vinyl chloride) stabilization has been studied by measuring rates of hydrogen chloride evolution from samples of polymer in the presence of stabilizers in di‐(2‐ethylhexyl) phthalate solution in an inert atmosphere. Barium, cadmium, calcium, and zinc laurates, when used alone, allow escape o…
Abstract The forces of repulsion generated in the steric barriers of a series of monodisperse spherical polymer particles, varying in diameter, have been measured using a surface balance. The particles were stabilized using a graft copolymer with a poly(methyl methacrylate) backbone and heptane soluble poly(12 hydroxy…
The crystal and molecular structure of bis-phthalocyaninatouranium(IV), the first complex of an actinide element with the phthalocyaninato-ion, has been determined by X-ray diffraction analysis.
The oxygen growth laws of anodic oxide films on aluminum and tantalum were studied using the nuclear microanalysis of the O 16 and O 18 isotopes. The influence of current density and surface preparation on the growth laws has been demonstrated. The correlation of the results of nuclear microanalysis of O 16 and of cou…
ABSTRACT The protein in the oothecal glands of praying mantids (Sphodromantis tenuidentata, Mio mantis monacha) exists in the form of lamellar liquid crystalline spherulites, which coalesce asthey flow out of a punctured gland tubule. Electron micrographs of sections of these spherulites after fixation show parabolic…
The liquid crystalline properties of several series of phenyl, ω-phenylalkyl and branched chain alkyl esters of 4-p-substituted-benzylideneaminocinnamic acids have been examined by optical microscopy and differential thermal analysis. The incidence of smectic polymorphism in these esters is high. Three distinct smecti…
Murine amyloid has been produced by four different induction methods ( Mycobacterium butyricum, casein, casein plus Freund's adjuvant and endotoxin-induced mouse amyloidosis) in several strains and obtained from mice with "spontaneous" amyloidosis. The amyloid fibrils have been concentrated from spleen and liver. Elec…
Conference International Symposium on the Chemistry of Natural Products, International Symposium on the Chemistry of Natural Products, ISCNP, Natural Products, VIIth, Riga, USSR, 1970-06-21–1970-06-27 Published Online: 2009-01-01 Published in Print: 1971-01-01 © 2013 Walter de Gruyter GmbH, Berlin/Boston
Abstract not Available.
Abstract Previous theories valid for polymer chains with large loops protruding into the solvent are developed. Interaction in various layers parallel to the interface is calculated according to the Flory‐Huggins theory. Excluded volume effects are shown to be so small that they can be neglected. The adsorption isothe…
The synthesis and the molecular structure of [NN′-o-phenylenebis(salicylideneiminato)UO2(EtOH)] are reported together with i.r. and relative stability data for similar complexes.
Thin foils of nickel have been electron-irradiated with the beam of a high-voltage electron microscope. In specimens previously ion-bombarded, voids are observed to grow at temperatures between 280°C and 480°C. The results are compared with those for neutron irradiation and are found to be basically similar. Differenc…
The permeation of H through iron and an iron‐nickel alloy as a function of time is reported. Below a certain critical H overpotential η, the H permeation occurs as a function of time in a simple way; and can be repeated indefinitely on the same specimen. But, when , the permeation‐time transient attains a new and char…
Abstract Ce(IV)‐induced polymerization of acrylonitrile and methyl methacrylate with acetylated cotton having different acetyl contents was investigated. The extent of interaction between the cotton and monomer is dependent upon the acetyl content of the former as well as on the reaction conditions. Increasing the ace…
The corrosion process for two iron samples of different purities in a molar solution of sulfuric acid has been studied by means of a rotating disk electrode. This study supports the previously formulated hypothesis which assigns the hysteresis, observed when corrosion is low, to the partial coverage (Θ) of the electro…
Barium titanate (BaTiO3) was deposited onto Pt foil, and onto thin-film Pt and Pt-Rh electrodes on sapphire, and counterelectroded to complete metal-dielectric-metal structures. Dielectrics (5000–60 000 Å) were deposited at substrate temperatures from 23 ° to 1000 °C, some fired in air at temperatures to 1400 °C after…