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Tetrahedrally-coordinated trivalent iron has been found to be a common impurity in flux-grown crystals of zinc oxide. The room temperature paramagnetic resonance spectrum of isolated ions may be described by a conventional axial spin Hamiltonian with parameters: $g=2.0060\ifmmode\pm\else\textpm\fi{}0.0005$, $D=\ensure…
The structure of the interrnetallio compound Co4Al,a is similar to that of 'FeA1 a' with which it forms a complete series of solid solutio~m. Refinement of the structure reveals certain differences in detail.
Changes in the structure of PTFE produced by different cooling rates from the sintering temperature and following permanent mechanical deformation have been studied with the electron microscope. Slow cooling rates resulted in longer and wider striated bands (which constitute the PTFE) than fast cooling rates, however,…
Chair conformation of Ring 8 Ring C 3 2 1 1 2 3 4A 1 2 3 4 5A "C ~C Fig. 8. Chairconfiguration of ring B and C.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTHE OXIDATION OF COPPER FILMS TO CuO0.67Harold Wieder and A. W. CzandernaCite this: J. Phys. Chem. 1962, 66, 5, 816–821Publication Date (Print):May 1, 1962Publication History Published online1 May 2002Published inissue 1 May 1962https://pubs.acs.org/doi/10.1021/j100811a010ht…
The effect of adding the rare-earth elements to cobalt, iron, and nickel has been investigated. Antiferromagnetic coupling was found to exist in the cobalt and iron rare-earth compounds. The moment per formula unit of the compound Co5Y is increased when Sm, Pr, and Nd are substituted for yttrium and decreased when Tm,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSpecies Equilibria in Nickel(II) Porphyrin Solutions: Effect of Porphyrin Structure, Solvent and TemperatureWinslow S. Caughey, Ralph M. Deal, Byron D. McLees, and James O. AlbenCite this: J. Am. Chem. Soc. 1962, 84, 9, 1735–1736Publication Date (Print):May 1, 1962Publicatio…
The locus of points on the (α,κ/σT) plane for a two-band (electrons and holes) semiconductor as the concentration of doping agent is changed, is a curve that forms a closed loop, where α is the Seebeck coefficient, κ the thermal conductivity, σ the electrical conductivity, and T the absolute temperature. The value of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of Boron NitrideT. E. O'ConnorCite this: J. Am. Chem. Soc. 1962, 84, 9, 1753–1754Publication Date (Print):May 1, 1962Publication History Published online1 May 2002Published inissue 1 May 1962https://pubs.acs.org/doi/10.1021/ja00868a065https://doi.org/10.1021/ja0086…
The thermodielectric converter, a device employing a ferroelectric material as the active element in converting thermal to electrical energy, is analyzed. The efficiency and power-handling capacity are calculated for operation of a ferroelectric material in the induced-ferroelectric region on the basis of an idealizat…
The infrared transmission of degenerate arsenic-doped germanium was measured at liquid-helium and at room temperature. The 4.2\ifmmode^\circ\else\textdegree\fi{}K data were used to calculate the energy gap of the degenerate material. For this, two operations were necessary: (1) to subtract the large effect of free car…
In order to obtain some informations on the electronic structure of Mn 4 N, the magnetic properties of Mn 4 N compounds, partially substituted by In and Sn respectively, are studied by a newly devised magnetic torsion balance. These compounds show very complicated temperature- and composition-dependences of saturation…
Some ferroelectric and crystallographical properties of the compound ${\mathrm{Ba}}_{2}$${\mathrm{Bi}}_{4}$${\mathrm{Ti}}_{5}$${\mathrm{O}}_{18}$ are presented. The compound represents a new structure with the unit cell consisting of one ${\mathrm{Bi}}_{2}$${\mathrm{O}}_{2}^{2+}$ layer and five perovskite layers. From…
Abstract It was reported in a preceding paper7) that the Ando soils from Uemura, Choyo, and Kawanishi contained an unknown mineral colloid which was distinctly different in some respects from coexisting allophane. In the Uemura soil, this clay fraction made up more than 20 per cent of the total clay and more than 6 pe…
Moderately strong, very broad absorption bands observed in dilute lanthanide bromide solutions in nearly anhydrous ethanol are interpreted as electron transfer from the highest filled M.O. to the partly filled 4f shell in the case of Nd(III), Sm(III), Eu(III), Tm(III) and Yb(III). Good agreement is obtained with a the…
Abstract The dynamic shear modulus at very high strains, ( G ∞ ), of carbon black filler loaded vulcanizates is regarded as due to the product of two factors: ( a ) a hydrodynamic interaction due to filler particles, and ( b ) a second factor for which evidence is given suggesting that it arises from a few strong link…
On the basis of 190 runs made up to 1860°C in sealed noble‐metal containers the following revisions have been made in the equilibrium diagram for the system A1 2 O 3 –SiO 2 . Mullite melts congruently at 1850°C. The extent of equilibrium solid solution in mullite at solidus temperature is from approximately 60 mole %…
A set of best values for t he te mperatures a nd enthalpies of fusion alld transition for the n-paraffins is presented. From a n a nalysis of these data a general qualitative t heory of the phase behavior of the n-paraffins is developed. Four di stinct. crystal structures-h exagonal, t riclinic, monoclinic, and orthor…
Trap depths and densities can be determined from the analysis of the dependence of space-charge-limited currents on applied electric field in insulators. Values obtained from space-charge-limited current measurements are compared with those obtained from thermally stimulated currents and from photocurrent decay on the…
In Hartree-Fock theory and its various generalizations, it is customary to solve an eigenvalue problem involving an effective one-body Hamiltonian. The eigenvectors determine the Fock-Dirac density matrix, which also appears in the effective Hamiltonian, and solution proceeds iteratively until self-consistency is achi…