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Linearized inversion of scatterometric data to obtain surface profile information

Emmanuel M. Drège2002-01-01Optical Engineering

Optical diffraction has been demonstrated to be a useful method with which to noninvasively examine materials and structures that result from lithographic processes used in the semiconductor indus- try to create integrated circuits. The process of inferring the geometry of the lithographically created structures from…

Photonic and Optical DevicesOptical Coatings and GratingsNear-Field Optical Microscopy

Surface structure study of biological calcium phosphate apatite crystals from human tooth enamel

Étienne F. Brès、J. L. Hutchison2002-01-01Journal of Biomedical Materials Research

A surface-structure study of human tooth enamel crystals has been carried out by high-resolution electron microscopy (HREM). The surfaces of several crystals have been examined and the surfaces of a single crystal are described here. The observations made on this crystal are similar to the observations made on the oth…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

Low-Temperature Properties of Pb(Zr 1− x Ti x )O 3 Solid Solutions near the Morphotropic Phase Boundary

L. Bellaïche、Alberto Garcı́a、David Vanderbilt2002-01-01Ferroelectrics

A first-principles-derived approach is used to study structural, piezoelectric and dielectric properties of Pb(Zr 1 m x Ti x )O 3 (PZT) solid solutions near the morphotropic phase boundary at low temperature. Three ferroelectric phases are found to exist: a tetragonal phase for larger x compositions, a rhombohedral ph…

Ferroelectric and Piezoelectric MaterialsPerovskite Materials and ApplicationsMicrowave Dielectric Ceramics Synthesis

Viscoelasticity of radiation-formed PVA/PVP hydrogel

Zainuddin Zainuddin、Justin J. Cooper‐White、David J. Hill2002-01-01Journal of Biomaterials Science Polymer Edition

The dynamic rheological behaviour of gamma-irradiated 12.8 wt% poly(vinyl alcohol) (PVA), 12.8 wt% poly(vinyl pyrrolidone) (PVP), and a blend of 8 wt% PVA and 4.8 wt% PVP aqueous solutions have been studied pre- and post-gelation. The non-irradiated solutions displayed rheological behaviour typical of dilute to semi-d…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer Nanocomposite Synthesis and Irradiation

Anti-inflammatory Activity of Decoctions of Leaves and Stems of Anisomeles indica at Preflowering and Flowering Stages

M.G. Dharmasiri、W.D. Ratnasooriya、M.I. Thabrew2002-01-01Pharmaceutical Biology

A decoction of leaves and stems of Anisomeles indica (Lamiaceae) is claimed to possess anti-inflammatory activity in Sri Lankan traditional medicine. The plants at both preflowering and flowering stages are used as an anti-inflammatory agent. However, the anti-inflammatory activity of the plant has not been scientific…

Natural product bioactivities and synthesisPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

Characterization of optical diffraction gratings by use of a neural method

Stéphane Robert、Alain Mure-Ravaud、Dominique Lacour2002-01-01Journal of the Optical Society of America A

Optical scatterometry by use of a neural network is now recognized as an efficient method for retrieving dimensions of gratings in semiconductors or glasses. For an on-line control, a small number of measurements and a rapid data treatment are needed. We demonstrate that these requirements can be met by combining data…

Advanced Fiber Optic SensorsPhotonic and Optical DevicesOptical Coatings and Gratings

Environmental Staility of EMI Shielding PET Fabric/Polypyrrole Composite

Han Kyun Kim、Sung Weon Byun、Sung Hoon Jeong 等 8 位作者2002-01-01Molecular Crystals and Liquid Crystals

PET fabric/polypyrrole composites with high electrical conductivity were prepared by polymerization of polypyrrole on a PET fabric through both chemical and electrochemical oxidation of pyrrole monomer. We investigated environmental stability of the composite and measured activation energy using the Arrhenius Equation.

Conducting polymers and applicationsAdvanced Battery Technologies ResearchSmart Materials for Construction

Titania–silica doped with transition metals via flame synthesis: structural properties and catalytic behavior in epoxidation

Wendelin J. Stark、Reto Strobel、Detlef Günther 等 5 位作者2002-01-01Journal of Materials Chemistry

The influence of trace amounts of transition metals (Cr, Mn, Fe, Co) on the structural and catalytic properties of silica and 1 wt% titania–silica nanoparticles prepared by flame synthesis has been investigated. The transition metal concentration was varied from 40 to about 2000 ppm by admixing the corresponding trans…

Catalytic Processes in Materials ScienceEnvironmental remediation with nanomaterialsThermal and Kinetic Analysis

A Review of Study on Thermal Energy Transport System by Synthesis and Decomposition Reactions of Methanol

Qiusheng Liu、Akira Yabe、Shiro Kajiyama 等 4 位作者2002-01-01JSME International Journal Series B

The study on thermal energy transport system by synthesis and decomposition reactions of methanol was reviewed. To promote energy conservation and global environment protection, a two-step liquid-phase methanol synthesis process, which starts with carbonylation of methanol to methyl formate, then followed by the hydro…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingHeat and Mass Transfer in Porous Media

Mesh Smoothing by Adaptive and Anisotropic Gaussian Filter

Yutaka Ohtake、Alexander Belyaev、Hans‐Peter Seidel 等 7 位作者2002-01-01Max Planck Institute for Plasma Physics

In this paper, we develop a fully automatic mesh filtering method that adaptively smoothes a noisy mesh and preserves sharp features and features consisting of only few triangle strips. In addition, it outperforms other conventional smoothing methods in terms of accuracy.

Optical measurement and interference techniquesAdvanced Numerical Analysis TechniquesTextile materials and evaluations

Thermogravimetry and X-Ray Absorption Spectroscopy Study of Heated V[sub 2]O[sub 5]⋅nH[sub 2]O Aerogels and Ambigels

Azzam N. Mansour、S. Dallek、Patricia H. Smith 等 4 位作者2002-01-01Journal of The Electrochemical Society

We have used thermogravimetry and X-ray absorption spectroscopy to examine the water content, oxidation state, and local structure of V for V 2 O 5 ⋅ n H 2 O aerogels and ambigels in the pristine state and after heating under vacuum (100 μTorr) at 114 and 220°C for 25 h. On the basis of thermogravimetric analysis, the…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsCatalysis and Oxidation Reactions

The Synthesis of 2,2-Disubstituted-3-nitrochromenes from Salicylaldehyde and 2,2-Disubstituted-1-nitroalkenes

Ching‐Fa Yao、Ming‐Chung Yan、Yeong‐Jiunn Jang 等 8 位作者2002-01-01Heterocycles

Reactions of salicylaldehyde (1) with β-nitrostyrenes (2), ( 4), and (6) in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) without the use of solvent at 40 ℃ gave high yields of the corresponding 3-nitrochromenes, respectively.Other conjugated nitroalkenes were also used to react with salicylaldehyde under the…

Magnetism in coordination complexesChemical Synthesis and ReactionsOxidative Organic Chemistry Reactions

Ionic to molecular transition in AlCl3: an examination of the electronic structure

Leonardo Bernasconi、Paul A. Madden、Mark Wilson2002-01-01PhysChemComm

AlCl 3 crystallizes as an ionic solid but melts to form a molecular liquid consisting of Al 2 Cl 6 units. In order to see if this transition involves a major change in electronic structure, the dimer and crystal of AlCl 3 are examined with the aid of generalized gradient corrected density functional theory (GGC-DFT) c…

Boron and Carbon Nanomaterials Research

Synthesis of New Hydrides in Mg-Y Systems by Using High Pressure

Yasuyuki Goto、Atsunori Kamegawa、Hitoshi Takamura 等 4 位作者2002-01-01MATERIALS TRANSACTIONS

A new hydride in the MgH2–YH3 system was found by using a high pressure of 5 GPa, and their crystal structure, thermal stability and hydrogen content were studied. The high-pressure synthesis was carried out at 1073 K for 2 h under 5 GPa by using an anvil-type apparatus. In the MgH2–xat%YH3 system (x=33–100), novel hy…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsNuclear Materials and Properties

Analytical derivatives, π bonding and d–s mixing in the ligand field molecular mechanics method

Robert J. Deeth、D. L. Foulis2002-01-01Physical Chemistry Chemical Physics

Expressions are presented for the analytical energy derivatives of the ligand field stabilisation energy (LFSE) within the angular overlap model formalism. In addition to the σ-bonding contributions already incorporated in the ligand field molecular mechanics (LFMM) code, explicit contributions from π-bonding and d–s…

Magnetism in coordination complexesPhotochemistry and Electron Transfer StudiesLanthanide and Transition Metal Complexes

Effect of Fiber Properties on Neutron Irradiated SiC/SiC Composites

Tatsuya Hinoki、Yutai Katoh、Akira Kohyama2002-01-01MATERIALS TRANSACTIONS

The use of SiC/SiC composites for nuclear application has recently been considered because of intrinsic low activation and superior high temperature mechanical properties of SiC. The property of SiC fiber is a key issue in order to improve mechanical properties of SiC/SiC composites following irradiation. SiC/SiC comp…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

An All-Solid-State Electrochemical Supercapacitor Based on Poly3-(4-fluorophenylthiophene) Composite Electrodes

Jung Yong Kim、In Jae Chung2002-01-01Journal of The Electrochemical Society

Poly3-(4-fluorophenylthiophene), which can be both n- and p-doped, has been chemically synthesized by using as an oxidant and is used as an electrode-active material in composite electrodes. To fabricate an all-solid-state electrochemical capacitor, a liquid electrolyte solution was replaced by a gel polymer electroly…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Phase transition and magnetic anisotropy of (La,Sr)MnO3 thin films

Zhihong Wang、H. Kronmüller、O. I. Lebedev 等 7 位作者2002-01-01Physical review. B, Condensed matter

The magnetic properties and their correlation with the microstructure and electrical transport are investigated in ${\mathrm{La}}_{0.88}{\mathrm{Sr}}_{0.1}{\mathrm{MnO}}_{3}$ films grown on $(100){\mathrm{SrTiO}}_{3}$ single crystal substrates with thickness ranging from 100 to 2500 \AA{}. The ultrathin film $(t=100 \…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Laser surface alloying of an Mg alloy with Al + Mn to improve corrosion resistance

Jyotsna Dutta Majumdar、Thorsten Maiwald、R. Galun 等 5 位作者2002-01-01Lasers in Engineering

In the present study, an attempt has been made to enhance the corrosion resistance of a Mg alloy (MEZ) by laser surface alloying with Al + Mn. Laser surface alloying has been carried out with a 10 kW continuous wave CO 2 laser by melting and simultaneous feeding of a powder mixture of Al and Mn in the ratio of 3 : 1 a…

Magnesium Alloys: Properties and ApplicationsHigh-Temperature Coating BehaviorsHigh Entropy Alloys Studies

Synthesis, Structure and Magnetic Susceptibility of two 5-Nitro-2-Aminopyridinium Cuprates: (5-NAP) 2 CuCl 4 and the Quantum Magnetic Ladder (5-NAP) 2 CuBr 4 ·H 2 O

Mark M. Turnbull、Călin Galeriu、J. Giantsidis 等 4 位作者2002-01-01Molecular Crystals and Liquid Crystals

The synthesis, x-ray crystal structures and magnetic susceptibilities for two tetrahalocuprate salts are reported. Bis(2-amino-5-nitropyridinium) tetrabromocuprate monohydrate [(5-NAP) 2 CuBr 4 ·H 2 O], 1 is triclinic, P-1. The tetrabromocuprate ions pack to form quasi-Heisenberg, S=½ quantum antiferromagnetic ladders…

Crystal structures of chemical compoundsMagnetism in coordination complexesMolecular spectroscopy and chirality