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Nanoelectromechanical device fabrications by 3-D nanotechnology using focused-ion beams

Reo Kometani and Sunao Ishihara2009-01-01Science and Technology of Advanced Materials

Nanoelectromechanical devices, which can be used as nanotools in nanofactories, were fabricated by focused ion beam chemical vapor deposition (FIB-CVD). The devices are made of diamond-like carbon (DLC), deposited on a Si substrate using gasified phenanthrene (C14H10) as a carbon source. The Young modulus and density…

Simple preparation of silica and alumina with a hierarchical pore system via the dual-templating method

Norihiro Suzuki, Yoshio Sakka and Yusuke Yamauchi2009-01-01Science and Technology of Advanced Materials

Silica and alumina with macro-meso-type hierarchical pore systems are synthesized by dual templating using both surfactants and polystyrene (PS) spheres. After calcination, scanning electron microscope images show uniform macropores with a diameter of approximately 200 nm. This size coincides with that of the original…

Mechanical properties of Ti-6Al-4V specimens produced by shaped metal deposition

Bernd Baufeld and Omer van der Biest2009-01-01Science and Technology of Advanced Materials

Shaped metal deposition is a novel technique to build near net-shape components layer by layer by tungsten inert gas welding. Especially for complex shapes and small quantities, this technique can significantly lower the production cost of components by reducing the buy-to-fly ratio and lead time for production, dimin…

Organic metal (EDO-TTF)2PF6 with multi-instability

Hideki Yamochi and Shin-ya Koshihara2009-01-01Science and Technology of Advanced Materials

The multi-instability of the electronic structure of (EDO-TTF)2PF6, where EDO-TTF means ethylene-dioxytetrathiafulvalene, is reviewed. This complex showed the metal–insulator transition at 280 K associated with distinct molecular deformations. The mechanism is interpreted as the cooperation of Peierls transition, char…

A Novel Docetaxel-Loaded Poly (ε-Caprolactone)/Pluronic F68 Nanoparticle Overcoming Multidrug Resistance for Breast Cancer Treatment

Chen Hongli、Tian Ge、Tian Yan 等 12 位作者2009-01-01Nanoscale Research Letters

Abstract Multidrug resistance (MDR) in tumor cells is a significant obstacle to the success of chemotherapy in many cancers. The purpose of this research is to test the possibility of docetaxel-loaded poly (ε-caprolactone)/Pluronic F68 (PCL/Pluronic F68) nanoparticles to overcome MDR in docetaxel-resistance human brea…

Synthesis and Growth Mechanism of Ni Nanotubes and Nanowires

Wang Yiqian、Li Xiaoru、Song Guojun 等 7 位作者2009-01-01Nanoscale Research Letters

Abstract Highly ordered Ni nanotube and nanowire arrays were fabricated via electrodeposition. The Ni microstructures and the process of the formation were investigated using conventional and high-resolution transmission electron microscope. Herein, we demonstrated the systematic fabrication of Ni nanotube and nanowir…

Subcellular Localization of Thiol-Capped CdTe Quantum Dots in Living Cells

Chen Ji-Yao、Peng Qian、Yang Wuli 等 8 位作者2009-01-01Nanoscale Research Letters

Abstract Internalization and dynamic subcellular distribution of thiol-capped CdTe quantum dots (QDs) in living cells were studied by means of laser scanning confocal microscopy. These unfunctionalized QDs were well internalized into human hepatocellular carcinoma and rat basophilic leukemia cells in vitro. Co-localiz…

Double In Situ Approach for the Preparation of Polymer Nanocomposite with Multi-functionality

Stec Anna、Richard Hull T、Wang De-Yi 等 7 位作者2009-01-01Nanoscale Research Letters

Abstract A novel one-step synthetic route, the double in situ approach, is used to produce both TiO2nanoparticles and polymer (PET), and simultaneously forming a nanocomposite with multi-functionality. The method uses the release of water during esterification to hydrolyze titanium (IV) butoxide (Ti(OBu)4) forming nan…

Nanocasting Synthesis of Ultrafine WO3 Nanoparticles for Gas Sensing Applications

Zamani Cyrus、Kamali Heidari Elham、Marzbanrad Ehsan 等 4 位作者2009-01-01Nanoscale Research Letters

Abstract Ultrafine WO3 nanoparticles were synthesized by nanocasting route, using mesoporous SiO2 as a template. BET measurements showed a specific surface area of 700 m 2/gr for synthesized SiO2, while after impregnation and template removal, this area was reduced to 43 m 2/gr for WO3 nanoparticles. HRTEM results sho…

Coupling of Semiconductor Nanowires with Neurons and Their Interfacial Structure

Rhim Hyewhon、Kim Sunoh、Park Seung-Han 等 9 位作者2009-01-01Nanoscale Research Letters

Abstract We report on the compatibility of various nanowires with hippocampal neurons and the structural study of the neuron–nanowire interface. Si, Ge, SiGe, and GaN nanowires are compatible with hippocampal neurons due to their native oxide, but ZnO nanowires are toxic to neuron due to a release of Zn ion. The inter…

Tetrathiapentalene-based organic conductors

Yohji Misaki2009-01-01Science and Technology of Advanced Materials

The synthesis, structure and properties of tetrathiapentalene-based (TTP) organic conductors are reviewed. Among various TTP-type donors, bis-fused tetrathiafulvalene, 2,5-bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene (BDT-TTP) and its derivatives afford many metallic radical cation salts stable down to low te…

Architectural Growth of Cu Nanoparticles Through Electrodeposition

Cheng Ching-Yuan、Ko Wen-Yin、Chen Wei-Hung 等 4 位作者2009-01-01Nanoscale Research Letters

Abstract Cu particles with different architectures such as pyramid, cube, and multipod have been successfully fabricated on the surface of Au films, which is the polycrystalline Au substrate with (111) domains, using the electrodeposition technique in the presence of the surface-capping reagents of dodecylbenzene sulf…

Structure and Photoluminescent Properties of ZnO Encapsulated in Mesoporous Silica SBA-15 Fabricated by Two-Solvent Strategy

Lu Qingshan、Wang Zhongying、Li Jiangong 等 5 位作者2009-01-01Nanoscale Research Letters

Abstract The two-solvent method was employed to prepare ZnO encapsulated in mesoporous silica (ZnO/SBA-15). The prepared ZnO/SBA-15 samples have been studied by X-ray diffraction, transmission electron microscope, X-ray photoelectron spectroscopy, nitrogen adsorption–desorption isotherm, and photoluminescence spectros…

Photocatalytic Degradation of Isopropanol Over PbSnO3Nanostructures Under Visible Light Irradiation

Chen Di、Ouyang Shuxin、Ye Jinhua2009-01-01Nanoscale Research Letters

Abstract Nanostructured PbSnO3photocatalysts with particulate and tubular morphologies have been synthesized from a simple hydrothermal process. As-prepared samples were characterized by X-ray diffraction, Brunauer–Emmet–Teller surface area, transmission electron microscopy, and diffraction spectroscopy. The photoacti…

Synthesis of Monodisperse Nanocrystals via Microreaction: Open-to-Air Synthesis with Oleylamine as a Coligand

Yang Hongwei、Fan Ningning、Luan Weiling 等 4 位作者2009-01-01Nanoscale Research Letters

Abstract Microreaction provides a controllable tool to synthesize CdSe nanocrystals (NCs) in an accelerated fashion. However, the surface traps created during the fast growth usually result in low photoluminescence (PL) efficiency for the formed products. Herein, the reproducible synthesis of highly luminescent CdSe N…

Monodisperse Hollow Tricolor Pigment Particles for Electronic Paper

Meng Xianwei、Tang Fangqiong、Peng Bo 等 4 位作者2009-01-01Nanoscale Research Letters

Abstract A general approach has been designed to blue, green, and red pigments by metal ions doping hollow TiO 2. The reaction involves initial formation of PS at TiO2 core–shell nanoparticles via a mixed-solvent method, and then mixing with metal ions solution containing PEG, followed calcining in the atmosphere. The…

Impact and fracture resistance of an experimental acrylic polymer with elastomer in different proportions

Fernanda de Carvalho Panzeri Pires‐de‐Souza、Heitor Panzeri、Marcelo A. C. Vieira 等 5 位作者2009-01-01Materials Research

The purpose of this study was to evaluate the impact and fracture resistance of acrylic resins: a heat-polymerized resin, a high-impact resin and an experimental polymethyl methacrylate with elastomer in different proportions (10, 20, 40 and 60%). 120 specimens were fabricated and submitted to conventional heat-polyme…

Engineering and Material Science ResearchDental materials and restorationsSurgical Sutures and Adhesives

High-temperature resistivity and thermoelectric properties of coupled substituted Ca3Co2O6

Meenakshisundaram Senthilkumar and Rajagopalan Vijayaraghavan2009-01-01Science and Technology of Advanced Materials

Polycrystalline samples of Ca3−xNaxCo2−xMnxO6 (x=0.0–0.5) have been prepared by the sol-gel cum combustion method using sucrose in order to investigate the effects of the coupled substitution of Na and Mn on Ca and Co sites on the transport properties of Ca3Co2O6(Co326). The products were characterized by Fourier tran…