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Synthesis and characterization of novel aromatic polyamides derived from 2,2′‐bis( p ‐phenoxyphenyl)‐4, 4′‐diaminodiphenyl ether

Hossein Behniafar、Saeed Khosravi‐borna2009-08-14Polymer International

Abstract BACKGROUND: Wholly aromatic polyamides (aramids) are high‐performance polymeric materials with outstanding heat resistance and excellent chemical stabilities due to chain stiffness and intermolecular hydrogen bonding of amide groups. Synthesis of structurally well‐designed monomers is an effective strategy to…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersTribology and Wear Analysis

A Bioinspired Wet/Dry Microfluidic Adhesive for Aqueous Environments

Abhijit Majumder、Ashutosh Sharma、A. K. Ghatak2009-08-14Langmuir

A pressure-sensitive, nonreacting and nonfouling adhesive which can perform well both in air and underwater is very desirable because of its potential applications in various settings such as biomedical, marine, and automobile. Taking a clue from nature that many natural adhesive pads have complex structures underneat…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesAdhesion, Friction, and Surface Interactions

The Evaluation of Miscibility of Poly(vinyl Chloride) and Poly(ethylene Oxide) Blends by DSC, Refractive Index and XRD Analyses

S. Ramesh、A.K. Arof2009-08-14International Polymer Processing

Abstract The miscibility of poly(vinyl chloride) (PVC) and poly(ethylene oxide) (PEO) blends was investigated by using differential scanning calorimetry (DSC), refractive index measurements and x-ray diffraction (XRD) analysis. The negative Flory-Huggins interaction parameter, χ 12 from the melting point depression of…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer Science and PVC

Comparing the Continuous Chaotic and Shear Mixing-Induced Morphology Development of Polyblend and its Nanocomposites

Ke Li、Han‐Xiong Huang、Guo Jiang2009-08-14Polymer-Plastics Technology and Engineering

Continuous chaotic and shear mixing-induced morphology development of 60/40 w/w polypropylene/polyamide 6 (PP/PA6) blend and its nanocomposite with 5 wt% clay was investigated. PP and PP nanocomposite were mixed with PA6 in a single-screw extruder, respectively. Two screw geometries were used to induce chaotic and she…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Multiaxis Three-Dimensional Flat Woven Preforms - Tube Carrier Weaving

Kadir Bilişik、Mansour H. Mohamed2009-08-14Textile Research Journal

A multiaxis three-dimensional (3D) flat woven preform and a weaving method have been developed. The structure has five yarn sets, which are bias(+) and bias(—), warp, filling and Z-yarns. The weaving method has been introduced to form the structure. An experimental prototype was constructed to trial the method. In thi…

Mechanical Behavior of CompositesAdditive Manufacturing and 3D Printing TechnologiesTextile materials and evaluations

Helices, Chirality and Interpenetration: the Versatility and Remarkable Interconversion of Silver−Copper Cyanide Frameworks

Ann M. Chippindale、Simon J. Hibble2009-08-14Journal of the American Chemical Society

The structural transformations between cesium silver-copper cyanides under modest conditions, both in solution and in the solid state, are described. Three new cesium silver(I) copper(I) cyanides with three-dimensional (3-D) framework structures were prepared as single crystals from a one-pot reaction initially heated…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchInorganic Chemistry and Materials

Effect of Clay Types on the Mechanical, Dynamic Mechanical and Morphological Properties of Polypropylene Nanocomposites

Sanjay K. Nayak、Smita Mohanty、Sushanta K. Samal2009-08-14Polymer-Plastics Technology and Engineering

In the present investigation Polypropylene–Maleic anhydride grafted polypropylene–organically modified MMT (PP-MAPP-OMMT) nanocomposites were prepared by melt mixing in a twin screw extruder followed by injection molding. The effect of clay chemistry and compatibilizer on the properties of the nanocomposites has been…

Polymer Nanocomposites and PropertiesTribology and Wear AnalysisPolymer Nanocomposite Synthesis and Irradiation

Mathematical and computational modelling of correlations in dislocation dynamics

Jie Deng、Anter El–Azab2009-08-14Modelling and Simulation in Materials Science and Engineering

This work focuses on the mathematical and computational modelling of dislocation correlation in the context of dislocation dynamics modelling of mesoscale plasticity. A hierarchical system of kinetic equations describing the evolution of dislocation densities of various orders is presented to illustrate the role of co…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesHigh Temperature Alloys and Creep

Grain growth in thin films with a fibre texture studied by phase-field simulations and mean field modelling

Nele Moelans、F. Spaepen、Patrick Wollants2009-08-14The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

The evolution of fibre textured structures is simulated in two dimensions using a generalised phase field model assuming two forms for the misorientation dependence of the grain boundary energy. In each case, a steady-state regime is reached after a finite amount of grain growth, where the number and length weighted m…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaFluid Dynamics and Thin Films

Whispering gallery modes in single triangular ZnO nanorods

Xinzheng Zhang、Xuejin Zhang、Jia-Bin Xu 等 6 位作者2009-08-14Optics Letters

Whispering gallery modes in ZnO nanorods with equilateral triangular cross sections were studied for the first time, to our knowledge. Photoluminescence following excitation with 325 nm radiation was observed at discrete wavelengths and thereby indicated the excitation of whispering gallery modes of triangular ZnO nan…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsAcoustic Wave Resonator Technologies

Quantum dots-based multiplexed immunohistochemistry of protein expression in human prostate cancer cells

Chunmeng Shi、Guoheng Zhou、Ying Zhu 等 7 位作者2009-08-14European Journal of Histochemistry

Semiconductor quantum dots (QDs) are bright fluorescent nanoparticles that have been successfully used for the detection of biomarker expression in cells. The objective of the present study is to use this technology in a multiplexing manner to determine at a single cell level the expression of a cell-specific bio-mark…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Rheology and Processing of HDPE/Wood Flour Composites

Cristiano Ribeiro de Santi、Elias Hage、J. Vlachopoulos 等 4 位作者2009-08-14International Polymer Processing

Abstract Rheological and mechanical properties of extruded wood plastic composites have been investigated for the purpose of providing a better understanding of processing conditions in profile extrusion for this novel class of thermoplastics composites. The basic formulations prepared for the study were comprised of…

Natural Fiber Reinforced CompositesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Oxidative Dehydrogenation of Methanol to Formaldehyde by Isolated Vanadium, Molybdenum, and Chromium Oxide Clusters Supported on Rutile TiO2(110)

Hyun You Kim、Hyuck Mo Lee、Raj Ganesh S. Pala 等 4 位作者2009-08-14The Journal of Physical Chemistry C

We use density functional theory to examine some of the important aspects of methanol oxidation to formaldehyde catalyzed by isolated MO 3 (M = V, Mo, and Cr) clusters supported on rutile, TiO 2 (110). Thermodynamic analysis led us to conclude that in the presence of oxygen, the M (M = V, Mo, and Cr) atom takes three…

Catalytic Processes in Materials ScienceTransition Metal Oxide NanomaterialsCatalysis and Oxidation Reactions

Magnetic oxide nanowires with strain-controlled uniaxial magnetic anisotropy direction

M. Mathews、R. Jansen、Guus Rijnders 等 5 位作者2009-08-14Physical Review B

While magnetic nanowires generally have a preferential magnetization direction along the wire axis to minimize magnetostatic energy, it is shown here for epitaxial magnetic oxide nanowires that substrate-induced strain can be used to tailor the magnetic easy axis in any direction. ${\text{La}}_{0.67}{\text{Sr}}_{0.33}…

Magnetic properties of thin filmsZnO doping and propertiesMagnetic and transport properties of perovskites and related materials

The Molecular Basis of Nacre Formation

Nils Kröger2009-08-14Science

A protein complex guides the process of nacre formation in mollusk shells.

Bone Tissue Engineering MaterialsPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition

Identification, Biosynthesis, and Characterization of Polyhydroxyalkanoate Copolymer Consisting of 3-Hydroxybutyrate and 3-Hydroxy-4-methylvalerate

Nuttapol Tanadchangsaeng、Asahi Kitagawa、Tetsuya Yamamoto 等 5 位作者2009-08-14Biomacromolecules

In this study, we found that Ralstonia eutropha strain PHB(-)4 expressing the polyhydroxyalkanoate (PHA) synthase 1 (PhaC1(Ps)) from Pseudomonas sp. 61-3 synthesized a PHA copolymer containing a 3-hydroxybutyrate (3HB) and small amounts of 3-hydroxy-4-methylvalerate (3H4MV) and 3-hydroxyvalerate (3HV) from fructose as…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Effect of mixing and spatial dimension on the glass transition

David Hajnal、J. M. Brader、R. Schilling2009-08-14Physical Review E

We study the influence of composition changes on the glass transition of binary hard disk and hard sphere mixtures in the framework of mode coupling theory. We derive a general expression for the slope of a glass transition line. Applied to the binary mixture in the low concentration limits, this method allows a fast…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Well‐Controlled Microcellular Biodegradable PLA/Silk Composite Foams Using Supercritical CO2

Dong Jin Kang、Xu Deng、Zhen Xiu Zhang 等 6 位作者2009-08-14Macromolecular Materials and Engineering

Abstract PLA biodegradable composites reinforced with various silk fibroin powder contents (0, 1, 3, 5 and 7 wt.‐%) were prepared by solution processing technique using CH 2 Cl 2 as solvent. After that the composites and virgin PLA were foamed by using supercritical CO 2 . The influence of silk contents on PLA/silk fi…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingPolymer Foaming and Composites

Control Oriented Modeling of Solid Oxide Fuel Cell Auxiliary Power Unit for Transportation Applications

Marco Sorrentino、Cesare Pianese2009-08-14Journal of Electrochemical Energy Conversion and Storage

This paper reports on the development of a control-oriented model for simulating a hybrid auxiliary power unit (APU) equipped with a solid oxide fuel cell (SOFC) stack. Such a work is motivated by the strong interest devoted to SOFC technology due to its highly appealing potentialities in terms of fuel savings, fuel f…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsCatalysis and Oxidation Reactions

A 13C{31P} REDOR NMR Investigation of the Role of Glutamic Acid Residues in Statherin- Hydroxyapatite Recognition

Moise Ndao、Jason T. Ash、Nicholas F. Breen 等 6 位作者2009-08-14Langmuir

The side chain carboxyl groups of acidic proteins found in the extra-cellular matrix (ECM) of mineralized tissues play a key role in promoting or inhibiting the growth of minerals such as hydroxyapatite (HAP), the principal mineral component of bone and teeth. Among the acidic proteins found in the saliva is statherin…

Bone Tissue Engineering MaterialsNanoparticle-Based Drug DeliverySupramolecular Self-Assembly in Materials