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The Incommensurately Modulated Structures of the Perovskites NaCeMnWO6 and NaPrMnWO6

Susana García‐Martín、Graham King、Gwilherm Nénert 等 5 位作者2012-03-02Inorganic Chemistry

The structures of the doubly ordered perovskites NaCeMnWO(6) and NaPrMnWO(6), with rock salt ordering of the Mn(2+) and W(6+)B-site cations and layered ordering of the Na(+) and (Ce(3+)/Pr(3+)) A-site cations, have been studied by transmission electron microscopy, electron diffraction, neutron and synchrotron X-ray po…

Perovskite Materials and ApplicationsMultiferroics and related materialsSolid-state spectroscopy and crystallography

Interaction of l‐leucyl‐l‐leucyl‐l‐leucine thin film with water and organic vapors: receptor properties and related morphology

Марат А. Зиганшин、I. G. Efimova、Valery V. Gorbatchuk 等 7 位作者2012-03-02Journal of Peptide Science

The ability of highly ordered tripeptide structures to keep or change their morphology in contact with organic vapors was studied. A thin film of tripeptide L-leucyl-L-leucyl-L-leucine (LLL) was prepared having microcrystals and nanocrystals on its surface, which are stable upon vacuum drying but become objects of sel…

Lipid Membrane Structure and BehaviorSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Maximizing Field‐Effect Mobility and Solid‐State Luminescence in Organic Semiconductors

Afshin Dadvand、Andrey G. Moiseev、Kosuke Sawabe 等 9 位作者2012-03-02Angewandte Chemie

Organische Transistoren aus dem gezeigten Styrylanthracen zeigen hohe Ladungsträgermobilitäten und Lumineszenz-Quantenausbeuten, was dem Fehlen eines strahlungslosen Zerfalls des Singulettzustands zugeschrieben wird; demnach wäre es fraglich, dass die für eine hohe Mobilität benötigten effizienten π-Wechselwirkungen s…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsLuminescence and Fluorescent Materials

A new oxamido-bridged dinuclear copper(II) complex with large antiferromagnetic exchange interactions

Lihua Xu、Haixian Wang、Li‐Na Zhu2012-03-02Journal of Coordination Chemistry

A new oxamido-bridged dinuclear compound [Cu2(µ-pmox)(DMF)4] · 2ClO4 (1) (H2pmox = N,N′-bis-(2-methylpyridyl)oxalamide, DMF = dimethylformamide) was synthesized and structurally characterized. The five-coordinate Cu(II) is bridged by oxamido groups and further cross-linked by C–H···O hydrogen bonds between the uncoord…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Modification of Branched Polyethylene by Aerosol‐assisted Dielectric Barrier Discharge

Renate Mix、Joerg F. Friedrich、N. Inagaki2012-03-02Plasma Processes and Polymers

Abstract Three polyethylene (PE) types with different branching structures were subjected to air, water and ethanol aerosol‐assisted dielectric barrier discharges (DBD) for surface modification. Using the air DBD the incorporated oxygen concentration was found to be independent on the branching of PE in contrast to th…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPlasma Applications and Diagnostics

Ba 0.6 Sr 0.4 TiO 3 – MgO Ceramic Powders with Uniform Microstructures Prepared by Aqueous Gelcasting‐Assisted Solid‐State Method

Jia‐Min Wu、Wen Lei、Xiao‐Hong Wang 等 5 位作者2012-03-02Journal of the American Ceramic Society

A novel forming method–aqueous gelcasting was used to assist conventional solid‐state method to prepare 45 wt% Ba 0.6 Sr 0.4 TiO 3 –55 wt% MgO ( BSTM ) ceramic powders. For comparison purpose, conventional solid‐state method was also used to synthesize the same powders. It is found that the BSTM ceramic powders prepar…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisMagnesium Oxide Properties and Applications

Effects of high pressure on the magnetism of ErCo2

Martin Míšek、Ján Prokleška、V. Sechovský 等 8 位作者2012-03-02Journal of Applied Physics

This paper presents the results of a high pressure study on the ferrimagnetic compound ErCo2, which exhibits at ambient pressure magnetic ordering below TC = 33 K, where the localized Er magnetic moments order ferromagnetically, and the itinerant moments in the Co sublattice, align antiparallel to the Er moments. In t…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Comparative study of the thermal and mechanical properties of nanocomposites prepared by in situ polymerization of ε‐caprolactone and functionalized carbon nanotubes

Víctor H. Antolín‐Cerón、Sergio Gómez‐Salazar、M. Rabelero 等 7 位作者2012-03-02Polymer Composites

Abstract As an effort to compare the influence of several types of functionalized carbon nanotubes (CNTs) upon the mechanical and thermal properties of nanocomposites prepared with a poly(ε‐caprolactone) (PCL) as matrix and functionalized CNTs as fillers; nanocomposites of PCL–CNTs were studied in this study. CNTs wer…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Ablation Capability of Flake Graphite Reinforced Barium-phenolic Resin Composite under Long Pulse Laser Irradiation

Qingchun Yu、Hong Wan2012-03-02Journal of Inorganic Materials

The carbon fiber reinforced phenolic resin composite is widely used as a thermal protection material because of its excellent thermal ablation. A novel flake graphite reinforced barium-phenolic resin composite was made by roller coating technology and its thermal ablation capability under long pulse laser irradiation…

Electromagnetic wave absorption materialsElectrical Contact Performance and AnalysisSilicone and Siloxane Chemistry

Ageing resistance and corrosion resistance of silicone‐epoxy and polyurethane topcoats used in sea splash zone

Z. F. Wang、F. C. Liu、En–Hou Han 等 4 位作者2012-03-02Materials and Corrosion

Abstract The silicone‐epoxy and polyurethane topcoats applied in a simulated sea splash environment were studied according to ISO20340 standard, and their properties were analyzed by differential scanning calorimetry (DSC), scanning electron microscopy (SEM), X‐ray photoelectron spectroscopy (XPS), and electrochemical…

Corrosion Behavior and InhibitionPolymer composites and self-healingSilicone and Siloxane Chemistry

Synthesis and characterization of polyacrylamide‐calcium carbonate and polyacrylamide‐calcium sulfate nanocomposites

Manoj K. Pal、Gautam Jaiswar2012-03-02Polymer Composites

Abstract Polyacrylamide‐calcium carbonate (PAM/CaCO 3 ) and polyacrylamide‐calcium sulfate (PAM/CaSO 4 ) nanocomposites were prepared via solution‐mixing technique. The resulting PAM‐based nanocomposites with various CaCO 3 and CaSO 4 nanoparticles contents (0–4% w/w) were investigated. Nanoparticles of CaCO 3 and CaS…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Nonlinear behavior of three-terminal graphene junctions at room temperature

Wonjae Kim、Pirjo Pasanen、Juha Riikonen 等 4 位作者2012-03-02Nanotechnology

We demonstrate nonlinear behavior in three-terminal T-branch graphene devices at room temperature. A rectified nonlinear output at the center branch is observed when the device is biased by a push-pull configuration. Nonlinearity is assumed to arise from a difference in charge transfer through the metal–graphene conta…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Electrical transport properties of single wall carbon nanotube/polyurethane composite based field effect transistors fabricated by UV-assisted direct-writing technology

Brahim Aïssa、Daniel Therriault、Rouhollah D. Farahani 等 5 位作者2012-03-02Nanotechnology

We report on the fabrication and transport properties of single-walled carbon nanotube (SWCNT)/polyurethane (PU) nanocomposite microfiber-based field effect transistors (FETs). UV-assisted direct-writing technology was used, and microfibers consisting of cylindrical micro-rods, having different diameters and various S…

Carbon Nanotubes in CompositesGraphene research and applicationsAdvanced Sensor and Energy Harvesting Materials

Oxygen-vacancy effect on structural, magnetic, and ferroelectric properties in multiferroic YMnO3 single crystals

D. P. Chen、Yi Du、Xiaolin Wang 等 8 位作者2012-03-02Journal of Applied Physics

We have investigated the structural, magnetic, and ferroelectric properties of magnetically frustrated multiferroic YMnO3 single crystals. The ferroelectric domain structures of YMnO3 samples were studied by piezoresponse force microscopy. Instead of domain vortex structure in stoichiometric crystals, YMnO3−δ exhibits…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Fabrication of superhydrophobic surfaces on Mg alloy substrates via primary cell corrosion and fluoroalkylsilane modification

Jinlong Song、Wei Xu、Yao Lu 等 5 位作者2012-03-02Materials and Corrosion

Abstract The present work reports a simple and safe two‐step process to render magnesium (Mg) alloy surfaces superhydrophobic via primary cell corrosion and subsequently cover it with a fluoroalkylsilane (FAS) film. The surfaces were characterized by scanning electron microscopy (SEM), optical microscopy, energy‐dispe…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesAdhesion, Friction, and Surface Interactions

A Study of Trimethylsilane (3MS) and Tetramethylsilane (4MS) Based α-SiCN:H/α-SiCO:H Diffusion Barrier Films

Sheng-Wen Chen、Yusheng Wang、Shao-Yu Hu 等 6 位作者2012-03-02Materials

Amorphous nitrogen-doped silicon carbide (α-SiCN:H) films have been used as a Cu penetration diffusion barrier and interconnect etch stop layer in the below 90-nanometer ultra-large scale integration (ULSI) manufacturing technology. In this study, the etching stop layers were deposited by using trimethylsilane (3MS) o…

Silicon Carbide Semiconductor TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

A Multichannel Magnetic Flux Controller for Periodic Magnetizing Conditions

Steven White、Thomas W. Krause、L. Clapham2012-03-02IEEE Transactions on Instrumentation and Measurement

International standards for testing soft magnetic materials require that the magnetic flux density remain sinusoidal with respect to time. Traditionally, this has been achieved via control of the magnetic flux using either analog feedback, which provides real-time control, or iterative digital feedback, which yields m…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Field Sensors Techniques

Cell membrane integrity and internalization of ingested TiO2 nanoparticles by digestive gland cells of a terrestrial isopod

Sara Novak、Damjana Drobne、Janez Valant 等 10 位作者2012-03-02Environmental Toxicology and Chemistry

The present study was motivated by the paucity of reports on cellular internalization of ingested titanium dioxide (TiO(2)) nanoparticles (nano-TiO(2)). The model invertebrate (Porcellio scaber, Isopoda, Crustacea) was exposed to food dosed with nano-TiO(2) containing 100, 1,000, 3,000, or 5,000 µg nano-TiO(2) per gra…

Nanoparticles: synthesis and applicationsEnvironmental Toxicology and EcotoxicologyMercury impact and mitigation studies

Influences of the three‐phase boundary on the electrochemical corrosion characteristics of carbon steel under droplets

Yu-xin Wang、Y. Y. Liu、W. Wang 等 5 位作者2012-03-02Materials and Corrosion

Abstract The potential/current distributions of carbon steel were investigated under 0.001 M sodium chloride droplets of various sizes using a wire beam electrode. During the corrosion process, carbon steel exhibited heterogeneous electrochemical characteristics with the major anodes located near the edge of the dropl…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Mechanisms of Microstructure Control in Conventional Sintering

Adriana Scoton Antônio Chinelatto、Elria Maria de Jesus Agnolon Pallone、Ana Maria de Souza 等 6 位作者2012-03-02InTech eBooks

The manner and mechanisms involved on the sintering process are essential investigation to achieve the required microstructure and final properties in solids. During the conventional sintering of a compacted powder, densification and grain growth occur simultaneously through atomic diffusion mechanisms. Many researche…

Advanced ceramic materials synthesisInjection Molding Process and PropertiesAdvanced materials and composites