Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMonolayer of polystyrene monomolecular particles on a water surface studied by Langmuir-type film balance and transmission electron microscopyJiro KumakiCite this: Macromolecules 1988, 21, 3, 749–755Publication Date (Print):March 1, 1988Publication History Published online1…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSpectroscopy of transition region speciesPhilip R. BrooksCite this: Chem. Rev. 1988, 88, 2, 407–428Publication Date (Print):March 1, 1988Publication History Published online1 May 2002Published inissue 1 March 1988https://pubs.acs.org/doi/10.1021/cr00084a004https://doi.org/10…
Time-resolved fluorescence and fluorescence anisotropy measurements have been performed on solutions of high molecular weight polysilane materials. The physical processes responsible for the decay of the anisotropy are discussed.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProperties of neutral clusters from scattering experimentsUdo BuckCite this: J. Phys. Chem. 1988, 92, 5, 1023–1031Publication Date (Print):March 1, 1988Publication History Published online1 May 2002Published inissue 1 March 1988https://pubs.acs.org/doi/10.1021/j100316a008htt…
The effect of rare‐earth oxide additives on the densification of silicon nitride by pressureless sintering at 1600° to 1700°C and by gas pressure sintering under 10 MPa of N 2 at 1800° to 2000°C was studied. When a single‐component oxide, such as CeO 2 , Nd 2 O 3 , La 2 O 3 , Sm 2 O 3 , or Y 2 O 3 , was used as an add…
Aluminosilicate gels with compositions Al 2 O 2 /SiO 2 and 2 were prepared by gelling a mixture of colloidal pseudo‐boehmite and a silica sol prepared from acid‐hydrolyzed Si(OC 2 H 5 ) 4 . Upon heating the pseudo‐boehmite transforms to γ‐Al 2 O 3 around 400°C, then to δ‐Al 2 O 3 at 1050°C, and at 1200°C reacts with a…
The role that bacterial surface hydrophobicity (surface tension) plays in determining the extent of adhesion of polymer substrates and phagocytic ingestion is reviewed. The early attachment phase in bacterial adhesion is shown to depend critically on the relative surface tensions of the three interacting phases; i.e.,…
Chromogranin A (CGA) is the major protein of the secretory granule from chromaffin cells and also is found in a variety of endocrine cells. Although the sequence of this acidic glycoprotein has been elucidated recently, its biological function is unknown. Here we have purified CGA from chromaffin granules; the final p…
The energies of IR active A 2u modes in both HfSe 2 and HfS 2 are not known, since it is experimentally difficult to perform IR spectroscopy measurements for E || c . The experimental results of our first and second order resonance Raman measurements show that A 2u (TO) = 180cm −1 and A 2u (LO) = 295cm −1 in HfS 2 ; i…
A comprehensive literature review on the thermal decomposition products and combustion toxicity of acrylics is presented. The types of products produced by the thermal decomposition of acrylic polymers vary widely. At lower temperatures, simple methacrylate polymers are degraded almost entirely to monomer, whereas sim…
This report presents a comprehensive literature review of the thermal decomposition products of polypropylene evolved under pyrolytic and oxidative conditions and the acute toxicity of combustion products of this polymer. Generally, the pyrolysis products of polypropylene (300–700°C) were aliphatic saturated and unsat…
The crystal structure of ${\mathrm{Li}}_{2}$${\mathrm{FeS}}_{2}$ has space group P3\ifmmode\bar\else\textasciimacron\fi{}m1 with a=3.902(1) A\r{}, c=6.294(2) A\r{}, U=83.00 A${\r{}}^{3}$, and Z=1. The structure refinement gives a final residual ${R}_{f}$=0.043 for 283 observations and nine variables (from single-cryst…
Evidence is presented that will establish the role of mechanical strain in promoting surface absorption of hydrogen by rupturing surface films on AISI(1) 4340 steel in alkaline 3.5% sodium chloride solution. Such bare surface generation is shown to substantially influence the alloy’s hydrogen cracking susceptibility.…
This article describes how principles of electronegativity can be applied to explain not only the bonding but also the physical and chemical properties of elements and molecules, their structure, and their energy.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudy of viscoelastic relaxation in amorphous polypropylene near Tg by dynamic light scattering and shear creepG. Fytas and K. L. NgaiCite this: Macromolecules 1988, 21, 3, 804–811Publication Date (Print):March 1, 1988Publication History Published online1 May 2002Published i…
Abstract Fifteen reference patterns of oxides, nitrides, borides, carbides, silicides, and sulfides are included in this report. The general methods of producing these X-ray powder diffraction reference patterns are described in this Journal, Vol. 1, No. 1, pg. 40(1986). Samples were mixed with one or two internal sta…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInfluence of the dehydrochlorination rate on the degradation mechanism of poly(vinyl chloride)T. Hjertberg, E. Martinsson, and E. SoervikCite this: Macromolecules 1988, 21, 3, 603–609Publication Date (Print):March 1, 1988Publication History Published online1 May 2002Publishe…
The structure of amorphous partially oxidized nickel tetrathiolato polymers has been studied by EXAFS and LAXS (large angle X-ray scattering).These polymers are the following: (i) the poly(nickel ethylenetetrathiolates) with different countercations, referred to as [(Ni-ett)Na0.j1]"(la), [(Ni-ett)Ko2J]" (lb), [(Ni-ett…
The crystallographic concepts of lattice and space group are extended to describe materials with crystallographically forbidden point groups, and a complete classification of all two-dimensional space groups with rotational order less than 23 is given.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTXPS characterization of glassy-carbon surfaces oxidized by O2, CO2, and HNO3S. R. Kelemen and H. FreundCite this: Energy Fuels 1988, 2, 2, 111–118Publication Date (Print):March 1, 1988Publication History Published online1 May 2002Published inissue 1 March 1988https://pubs.ac…