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Thermisch und UV‐photochemisch initiierte hochdruckpolymerisation des ethylens, 2. Molmassen‐verteilung

Michael Buback、Chul‐Rim Choe、E. U. Franck1984-08-01Die Makromolekulare Chemie

Abstract The molar mass distribution of polyethylenes synthesized at pressures up to 2500 bar and temperatures to 255°C with thermal and partly with photochemical initiation is determined by GPC. In the limiting situation of high pressure, low temperature, and small conversion a distribution function based on a limite…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Transformation Range Viscosity of Fluorozirconate Glasses

James E. Shelby、Carlo G. Pantano、Aleta A. Tesar1984-08-01Journal of the American Ceramic Society

Transformation range viscosity was measured for multicomponent fluorozirconate glasses in the system 0.56ZrF 4 ·(0.34‐x)BaF 2 ·0.06LaF 3 ·0.04AlF 3 ·xRF, where R =Li, Na, K, or Cs . The results indicate that the viscosity of these glasses can be described by an Arrhenius equation over the viscosity range from 10 7 to…

Material Dynamics and PropertiesGlass properties and applicationsSolid-state spectroscopy and crystallography

Ungewöhnliche lineare, oligomere Anionen [GanSe2n+2](n + 4)- (n =2,4,6) in festen Selenogallaten des Cäsiums

H. J. Deiseroth1984-08-01Zeitschrift für Kristallographie - Crystalline Materials

Article Ungewöhnliche lineare, oligomere Anionen [GanSe2n+2](n + 4)- (n =2,4,6) in festen Selenogallaten des Cäsiums was published on August 1, 1984 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 166, issue 1-4).

Crystal Structures and PropertiesOrganometallic Compounds Synthesis and CharacterizationInorganic Chemistry and Materials

Effects of coupling agent on the rheological behavior and processability of polypropylene

Chang Dae Han、Tae Hoon Kwack、Hong‐Lie Luo1984-08-01Journal of Applied Polymer Science

Abstract An investigation was made into the effect of coupling agents on the rheological behavior and processability of polypropylene. For the study, each of the following three commercially available coupling agents, a titanate coupling agent (Kenrich Petrochemicals, KR‐TTS) and two silane coupling agents (Union Carb…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Über Oxostannate(II). V. Na4[SnO3] – das erste Oxostannat(II) mit „Inselstruktur”

B. Nowitzki、R. Hoppe1984-08-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Das neue Oxid Na 4 SnO 3 (hellgelbe, klare Einkristalle) aus: 1. NaO 0,45 und SnO (Na:Sn 2+ = 4,1:1; Ag‐Bömbchen; 600 bis 730°C, 7 bis 66 d); 2. NaO 0,45 , SnO 2 und Sn ±0 (Na:Sn 4+ : Sn ±0 = 8,2:1:1; Ag‐Bömbchen; 650 bis 680°C, 2 bis 66 d); 3. NaO 0,45 , Na 2 SnO 3 und Sn ±0 (Na: Na 2 SnO 3 : Sn ±0 = 6,1:1:1…

Crystal structures of chemical compoundsCrystal Structures and PropertiesChemical Synthesis and Characterization

Polycation-Cell Surface Interactions and Plasma Membrane Compartments in Mammals. Interference of Oligocation with Polycationic Condensation

S Antohi、Vlad Brumfeld1984-08-01Zeitschrift für Naturforschung C

At lower concentrations, polyarginine, polylysine, protamine, histones H1, H2A, H2B and H3 cause lysis of human erythrocytes, whereas at higher concentrations inner histones are not hemolytic but induce only surface condensation and alterations in the cell-shape. Antibody coated erythrocytes treated with polyarginine…

biodegradable polymer synthesis and properties

Orientation of the boundary faces in nylon‐11 lamellar crystals

M. Dosière、J. J. Point1984-08-01Journal of Polymer Science Polymer Physics Edition

Abstract A semicrystalline polymer having a large repeat unit, as does nylon‐11, is particularly suitable for seeking correlation between the orientation of the lattice and the basal planes of the lamellar crystals. In filter mats of nylon‐11 single crystals, the basal planes of the lamellae are parallel to (00l) crys…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Thermodynamic Study of Na-K-Ca Exchange Reactions in Vermiculite

Atsuyuki Inoue1984-08-01Clays and Clay Minerals

Abstract The exchange of Na, K, and Ca ions in vermiculite has been studied between 50 and 150°C at a total normality of 0.1. The free energy changes were negative in the Na → K, Ca → K, and Na → Ca exchange reactions, and the cation preference in the vermiculite was Na < Ca < K in the temperature range examined…

Concrete and Cement Materials ResearchClay minerals and soil interactionsIron oxide chemistry and applications

Complexes of dimolybdenum(II) with DL-amino acids

Francoise Apfelbaum-Tibika、Avi Bino1984-08-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTComplexes of dimolybdenum(II) with DL-amino acidsFrancoise Apfelbaum-Tibika and Avi BinoCite this: Inorg. Chem. 1984, 23, 18, 2902–2905Publication Date (Print):August 1, 1984Publication History Published online1 May 2002Published inissue 1 August 1984https://pubs.acs.org/doi…

Polyoxometalates: Synthesis and ApplicationsMetalloenzymes and iron-sulfur proteinsOrganometallic Compounds Synthesis and Characterization

Fatigue fracture of mother‐of‐pearl and its significance for predatory techniques

John D. Currey、K. Brear1984-08-01Journal of Zoology

Specimens of nacre from the pearl oyster Pinctada margaritifera were loaded in bending to various fractions of the load needed to cause fracture. For a small number of cycles, less than about 1000, no changes in compliance or strength were found if the load was less than about 60% of the load necessary to cause failur…

Paleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and InhibitionCephalopods and Marine Biology

Secondary structure of peptides, 14. FT‐IR and 13C NMR CP/MAS investigation of the helix stability of solid poly(L‐proline)s

Detlef Müller、Josef Stulz、Hans R. Kricheldorf1984-08-01Die Makromolekulare Chemie

Abstract Primary amine and pyridine‐initiated polymerizations of L‐proline‐ N ‐carboxyanhydride (Pro‐NCA) at 20 or 100°C yield exclusively or predominantly 10 3 ‐helices. Only primary amine‐initiated polymerizations in 1,4‐dioxane at 100°C result in partial formation of 3 1 ‐helices. The stability of both 10 3 ‐ and 3…

biodegradable polymer synthesis and propertiesChemical Synthesis and AnalysisSynthesis and properties of polymers

Behavior of Metallic Materials Between 550 and 870°C in High-Temperature Gas-Cooled Reactor Helium Under Pressures of 2 and 50 bar

M. Cappelaere、Morgann Perrot、J. Sannier1984-08-01Nuclear Technology

In order to estimate the influence of the helium pressure on the corrosion of ferritic and austenitic materials, tests were carried out under 2 absolute bar in a circuit without helium recirculation and under 50 bar in the AIDA loop. In both cases the partial pressures of impurities were 1.500, 50, 450, and 50 μatm fo…

Fusion materials and technologiesHigh-Temperature Coating BehaviorsNuclear Materials and Properties

Cobalt-59 NMR of a cobalt(III) spin-crossover compound

Gil Navon、W. Klaeui1984-08-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCobalt-59 NMR of a cobalt(III) spin-crossover compoundGil Navon and Wolfgang KlaeuiCite this: Inorg. Chem. 1984, 23, 17, 2722–2725Publication Date (Print):August 1, 1984Publication History Published online1 May 2002Published inissue 1 August 1984https://pubs.acs.org/doi/10.1…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications

Die Kristallstruktur von Na4CaSi3O9 und dessen strukturelle Beziehungen zu K4SrGe3O9 und Ca3Al2O6

R. X. Fischer、Е. Тиллманнс1984-08-01Zeitschrift für Kristallographie - Crystalline Materials

Article Die Kristallstruktur von Na4CaSi3O9 und dessen strukturelle Beziehungen zu K4SrGe3O9 und Ca3Al2O6 was published on August 1, 1984 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 166, issue 1-4).

Luminescence Properties of Advanced MaterialsNuclear materials and radiation effectsChemical Synthesis and Characterization

(755)-(757) Proposals to Designate Conserved Types for Cymbella C. Agardh and Cyclotella (Kutzing) Brebisson, and to Conserve Rhopalodia O. Muller against Pyxidicula Ehrenberg (All Bacillariophyceae)

Hannelore Håkansson、R. Ross1984-08-01Taxon

Hannelore Håkansson, R. Ross, (755)-(757) Proposals to Designate Conserved Types for Cymbella C. Agardh and Cyclotella (Kützing) Brébisson, and to Conserve Rhopalodia O. Müller against Pyxidicula Ehrenberg (All Bacillariophyceae), Taxon, Vol. 33, No. 3 (Aug., 1984), pp. 525-531

Diatoms and Algae Research

Errors in critical-angle measurement of refractive index of optically absorbing materials

G.H. Meeten、A.N. North、F M Willmouth1984-08-01Journal of Physics E Scientific Instruments

Large errors are possible in critical-angle measurements of the refractive index of optical absorbers. These arise from the dependence of the reflectivity and transmissivity of a plane optical interface on the imaginary part of the complex relative refractive index. The errors are calculated directly from the Fresnel…

Advanced Measurement and Metrology TechniquesOptical Coatings and GratingsOptical Polarization and Ellipsometry

Application of the Pseudopotential Model to Solids

Marvin L. Cohen1984-08-01Annual Review of Materials Science

▪ Abstract The phase-field method has recently emerged as a powerful computational approach to modeling and predicting mesoscale morphological and microstructure evolution in materials. It describes a microstructure using a set of conserved and ...Read More

Solidification and crystal growth phenomenaAdvanced Mathematical Modeling in Engineering

High strain‐rate shear deformation of a polyurethane elastomer subjected to impact loading

Y. M. Gupta1984-08-01Polymer Engineering and Science

Abstract Experimental techniques have been developed to produce and measure large amplitude one dimensional compression and shear waves in a polyurethane elastomer (Solithane 113). Experimental measurements consisted of time‐resolved compression and shear amplitude measurements at different distances from the impact s…

Polymer Nanocomposites and PropertiesElasticity and Material ModelingStructural Analysis of Composite Materials

Technical Note: Stress Corrosion Cracking of Brass in Aqueous Ammonia in the Absence of Detectable Anodic Dissolution

Ugo Bertocci、F. I. Thomas、E. N. Pugh1984-08-01CORROSION

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Facebook Twitter LinkedIn MailTo Tools Icon Tools Get Permissions Cite Icon Cite Search Site Citation U. Bertocci, F. I. Thomas, E. N. Pugh; Technical Note: Stress Corrosion Cracking of Brass in Aqueous Ammon…

Metallurgy and Material Science

Synproportionierung am metallischen Substrat: CsCu2Cl3 und CsCu2Br3

Gerd Meyer1984-08-01Zeitschrift für anorganische und allgemeine Chemie

Abstract CsCu 2 Cl 3 und CsCu 2 Br 3 wurden auf trockenem Wege durch Synproportionierung von Gemengen CsX/2 CuX (X = Cl, Br) bzw. CsCuCl 3 mit der Gefäßwand eines Cu‐Bömbchens als metallischem Substrat in Form von Einkristallen erhalten. Es ist für CsCu 2 Cl 3 (CsCu 2 Br 3 ): a = 950,75(9) (987,3(1)), b = 1189,8(2) (1…

Magnetism in coordination complexesSynthesis and characterization of novel inorganic/organometallic compoundsInorganic Fluorides and Related Compounds