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Density control of single-walled carbon nanotubes using patterned iron nanoparticle catalysts derived from phase-separated thin films of a polyferrocene block copolymerElectronic supplementary information (ESI) available: synthesis of PS-b-PFEMS, SWNT growth and characterization. See http://www.rsc.org/suppdata/jm/b4/b403831b/

Sarah Lastella、Yung Joon Jung、Hoichang Yang 等 8 位作者2004-01-01Journal of Materials Chemistry

Single-walled carbon nanotube (SWNT) density and bundle size has been controlled by a simple one step CVD growth process using a polyferrocenylsilane block copolymer as the pre-organized catalyst source.

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

Rotor-like ZnO by epitaxial growth under hydrothermal conditionsElectronic supplementary information (ESI) available: TEM images of the rod-like and rotor-like ZnO in the bright field and dark field. See http://www.rsc.org/suppdata/cc/b4/b403252g/

Xueping Gao、Zhanfeng Zheng、Huaiyong Zhu 等 7 位作者2004-01-01Chemical Communications

Rotor-like ZnO was grown from a mixture of rod-like ZnO powder and a saturated Zn(OH)(4)(2-) solution under moderate hydrothermal conditions at 100 degree C, in which the precursor rod-like ZnO crystal plane acts as a matrix core, and the branched nanorods showed fast epitaxial growth on the six directions around the…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Transformation of highly ordered large pore silica mesophases (Fm3m, Im3m and p6mm) in a ternary triblock copolymer–butanol–water system

Freddy Kleitz、Leonid A. Solovyov、Gopinathan M. Anilkumar 等 5 位作者2004-01-01Chemical Communications

Exceptional control of the phase behavior of highly ordered large pore mesostructured silica (with the choice of Fm3m, Im3m or p6mm symmetry) is achieved using a triblock copolymer (EO(106)PO(70)EO(106)) and butanol at low acid concentrations.

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Soft nanotubes from amphiphilic ABA triblock macromonomers

Julie Grumelard、Andreas Taubert、Wolfgang Meier2004-01-01Chemical Communications

Soft, water-filled polymer nanotubes of several tens of microm in length have been prepared via self-assembly of amphiphilic ABA-triblock macromonomers in aqueous media; the tubes are mechanically and chemically stable and can be loaded with water-soluble substances.

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesSupramolecular Self-Assembly in Materials

Designed Self‐Assembled β‐Sheet Peptide Fibrils as Templates for Silica Nanotubes

Jonathan Meegan、Amalia Aggeli、N. Boden 等 9 位作者2004-01-01Advanced Functional Materials

Abstract Sol–gel condensation of tetraethoxysilane in the presence of designed self‐assembled β‐sheet peptide fibril templates, followed by template extraction, yields hollow silica nanotubes. The nanotubes are hundreds of nanometers long and possess a central pore of ∼ 3.5 nm, determined by the fibril template diamet…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsDiatoms and Algae Research

Lanthanide selective sorbents: self-assembled monolayers on mesoporous supports (SAMMS)

Glen E. Fryxell、Hong Wu、Yuehe Lin 等 9 位作者2004-01-01Journal of Materials Chemistry

Through the marriage of mesoporous ceramics with self-assembled monolayer chemistry, the genesis of a powerful new class of environmental sorbent materials has been realized. By coating the mesoporous ceramic backbone with a monolayer terminated with a lanthanide-selective ligand, it is possible to couple high lanthan…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Advanced selective optical sensors based on periodically organized mesoporous hybrid silica thin films

Lionel Nicole、Cédric Boissière、David Grosso 等 6 位作者2004-01-01Chemical Communications

Mesoporous thin films functionalized with silylated [small beta]-diketone compounds with symmetry mesostructure dependent on the probe quantity were used as fast uranyl species sensors with high selectivity and sensitivity.

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistryAnalytical Chemistry and Sensors

Biocers: ceramics with incorporated microorganisms for biocatalytic, biosorptive and functional materials development

Horst Böttcher、Ulrich Soltmann、Michael Mertig 等 4 位作者2004-01-01Journal of Materials Chemistry

Biologically modified ceramics (biocers) are understood as a class of nanocomposites which combine biocomponents with ceramic-like matrices. Biocers containing biocomponents can be prepared as a bulk material or as coatings by sol–gel and freeze-cast techniques from inorganic nanosols or by special CVD methods. By avo…

Algal biology and biofuel productionMicrobial Community Ecology and PhysiologyDiatoms and Algae Research

Crystal structures of collagen model peptides with Pro‐Hyp‐Gly repeating sequence at 1.26 Å resolution: Implications for proline ring puckering

Kenji Okuyama、Chizuru Hongo、Rie Fukushima 等 8 位作者2004-01-01Biopolymers

Triple-helical structures of (Pro-Hyp-Gly)n (n = 10, 11) at 100 K and room temperature (RT) were analyzed at 1.26 A resolution by using synchrotron radiation data. Totals of 49 and 42 water molecules per seven triplets in an asymmetric unit were found for the structures at 100 K and RT, respectively. These water molec…

Protein Hydrolysis and Bioactive PeptidesEnzyme Production and CharacterizationCollagen: Extraction and Characterization

Mixed ligand system of cysteine and thioglycolic acid assisting in the synthesis of highly luminescent water-soluble CdTe nanorodsElectronic supplementary information (ESI) available: instrumentation, discussion of dipole attraction, XRD pattern of CdTe nanorods and TEM image of CdTe nanowires. See http://www.rsc.org/suppdata/cc/b4/b405623j/

Jun Li、Jun Li、Hong Xia 等 12 位作者2004-01-01Chemical Communications

Highly luminescent water-soluble CdTe nanorods were prepared with the assistance of the mixed ligand system of cysteine and thioglycolic acid; the aspect ratio and photoluminescence of the CdTe nanorods could be controlled by the refluxing time.

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Large scale, templateless, surfactantless route to rapid synthesis of uniform poly(o-phenylenediamine) nanobelts

Xuping Sun、Shaojun Dong、Erkang Wang2004-01-01Chemical Communications

We reported the interesting finding that large scale uniform poly(o-phenylenediamine) nanobelts with several hundred micrometers in length, several hundred nanometers in width, and several ten nanometers in height can be rapidly yielded from an o-phenylenediamine–HAuCl4 aqueous solution without the additional introduc…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

Elasticity of polyelectrolyte multilayer microcapsules

Lulevich, V. V.、Andrienko, D.、Olga I. Vinogradova2004-01-01Max Planck Institute for Plasma Physics

We present a novel approach to probe elastic properties of polyelectrolyte multilayer microcapsules. The method is based on measurements of the capsule load-deformation curves with the atomic force microscope. The experiment suggests that at low applied load deformations of the capsule shell are elastic. Using elastic…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Crystal morphology control of AFI type molecular sieves with microwave irradiation

Sung Hwa Jhung、Jong‐San Chang、Young Kyu Hwang 等 4 位作者2004-01-01Journal of Materials Chemistry

AFI type molecular sieves with various morphologies such as aggregated sphere, plate, rod, prism and barrel were synthesized under varying reaction conditions under microwave irradiation. Hexagonal plate-like crystals with an aspect ratio of about 0.2 were obtained in the presence of silica under alkaline conditions.…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisChemical Synthesis and Characterization

Spontaneous template-free assembly of ordered macroporous titania

Andrew Collins、Daniel Carriazo、Sean A. Davis 等 4 位作者2004-01-01Chemical Communications

Spontaneous formation of ordered macroporous titania is achieved by dropwise addition of titanium alkoxides to aqueous ammonia in the absence of auxiliary organic templates.

Advanced Photocatalysis TechniquesMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Synthesis, photoluminescence and thermostimulated-luminescence properties of novel red long-lasting phosphorescent materials β-Zn 3 (PO 4 ) 2 :Mn 2+ ,M 3+ (M = Al and Ga)

Jing Wang、Shubin Wang、Qiang Su2004-01-01Journal of Materials Chemistry

Novel red long-lasting phosphorescent materials β-Zn3(PO4)2:Mn2+,M3+ (M = Al and Ga) were synthesized by means of high-temperature solid-state reaction. Photoluminescence (PL) excitation and emission, long-lasting phosphorescent (LLP) emission, decay curves, brightness and chromaticity coordination, and thermostimulat…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics Synthesis

Benzo-2,1,3-thiadiazole-based, highly dichroic fluorescent dyes for fluorescent host–guest liquid crystal displays

Xuelong Zhang、Hideki Gorohmaru、M. Kadowaki 等 7 位作者2004-01-01Journal of Materials Chemistry

The highly dichroic fluorescent dyes 4,7-bis(p-alkoxyphenyl)-, 4,7-bis(p-alkoxymethylphenyl)-, and 4,7-bis(p-alkoxycarbonylphenyl)-2,1,3-benzothiadiazoles have been synthesized and their dichroic properties evaluated. A solution of the former dye dispersed in the commercial liquid crystalline MLC-2039 host phase showe…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Optical properties of metal nanoparticle coated silica spheres: a simple effective medium approach

Isabel Pastoriza‐Santos、Daniel E. Gómez、Jorge Pérez‐Juste 等 5 位作者2004-01-01Physical Chemistry Chemical Physics

The preparation of gold particle coated silica microspheres is described and the optical absorption spectra for various surface coverages of gold particles are presented. Onion-shell particles with the structure silica-gold-silica are also described. An effective medium model is used to quantify the surface plasmon sh…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchQuantum Dots Synthesis And Properties

A posteriorierror control for the Allen–Cahn problem: circumventing Gronwall's inequality

Daniel Kessler、Ricardo H. Nochetto、Alfred Schmidt2004-01-01ESAIM Mathematical Modelling and Numerical Analysis

Phase-field models, the simplest of which is Allen–Cahn's problem, are characterized by a small parameter ε that dictates the interface thickness. These models naturally call for mesh adaptation techniques, which rely on a posteriori error control. However, their error analysis usually deals with the underlying non-mo…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaAdvanced Mathematical Modeling in Engineering

Transparent Ferroelectric Glass-Ceramics

Himanshu Jain2004-01-01Ferroelectrics

In recent years, there has been a resurgence of interest in transparent ferroelectric glass-ceramics (TFGCs), which are a special class of glass-ceramic composites that combine the low cost of fabrication and forming of transparent glass with the superior nonlinear optical and electro-optical properties of ferroelectr…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsMicrowave Dielectric Ceramics Synthesis

Endothelial cell seeding of polymeric vascular grafts

Julia Kristin2004-01-01Frontiers in bioscience

Pioneers in the field of small diameter graft development sought to promote graft endothelialization and, thereby, increase patency by transplanting a varying degree of autologous endothelial cells onto vascular grafts prior to implantation. This process has become known as endothelial cell seeding. The underlying hyp…

Membrane Separation TechnologiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies