Materials Literature
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We report the synthesis, characterization and structural studies of the higher homologues of N(4-n-pentyloxybenzylidene)4-n-alkylaniline compounds, viz. 5O.12, 5O.14 and 5O.16 by thermal microscopy, differential scanning calorimetry and X-ray diffraction. The compounds exhibit N–SA–SB, N–SA–SB and N–SA phase sequence…
Saccharide materials are potential candidates for frequency conversion applications. In addition to being chiral, which ensures crystallization in a space group necessary for three-wave mixing processes, they generally possess useful physical and optical properties. We have examined the powder second harmonic generati…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrochemical elaboration of thin films of poly[RuII(L)(CO)2Cl2] (L = 4-(2-pyrrol-1-ylethyl)-4'-methyl-2,2'-bipyridine or 4,4'-bis((3-pyrrol-1-ylpropyloxy)carbonyl)-2,2'-bipyridine): photochemical properties and photoimagingMarie Noelle Collomb-Dunand-Sauthier, Alain Deron…
Dislocations in an ${\mathrm{Al}}_{62}$${\mathrm{Cu}}_{25.5}$${\mathrm{Fe}}_{12.5}$ face-centered icosahedral quasicrystal were studied by means of the contrast experiment and defocus convergent-beam electron diffraction technique. The indices of the six-dimensional Burgers vector of the dislocations were determined t…
Stacking fault energies in dilute Cu(Al) alloys and across the composition range of PdAg alloys are calculated from first principles using the layer Korringa-Kohn-Rostoker method and treating the compositional disorder within the coherent potential approximation. In Cu(Al), rigid-band behaviour results in a sharp redu…
Abstract Changes caused by pressures between 0 and 20 K bar on two samples of kaolinite have been studied. Increased pressure causes the samples to lose crystallinity, shown by a decrease in the Hinckley, Lietard and reference intensity ratio indices, as well as by the crystallite size measured from the 001 reflection…
Abstract A nonlinear conservation equation for the fluid concentration field during onedimensional viscoelastic diffusion is derived by retaining the concentration dependencies of physical properties in the fluid flux expression from the nonequilibrium thermodynamic treatment of Durning and Tabor (1986). The result is…
Abstract As a means of developing the most accurate possible Mark‐Houwink relationship possible for PVC, the literature Mark‐Houwink coefficients for the weight average molecular weight ( M W ) of PVC in THF are plotted and the derived “grand average” Mark‐Houwink relationship ( K = 15.56 × 10 −3 ml/g, a = 0.7690) is…
Plastic crystals, such as neopentylglycol, 2, 2-dimethyl-1,3-propanediol, that exhibit polymorphic behavior are emerging materials for thermal energy storage. The energy is stored isothermally in the γ phase, FCC, during solid-state phase transformations. This γ phase of NPG has been determined as an orientational dis…
Abstract A set of mathematical models as a thermoplastic pultrusion process is evaluated. The predictions of the models are compared to experimentally obtained data in terms of composite temperature and pressure and process pulling force. The comparisons between predictions and experiments are made for two different m…
The effect of the valence state of copper in copper metaphosphate glass on the crystallization behavior and glass transition temperature has been investigated. The crystallization of copper metaphosphate is initiated from the surface and its main crystalline phase is copper metaphosphate (Cu(PO) 3 ), independent of th…
A slender type diatom is observed. The settling behavior and surface electrostatic situation of the diatom are discussed through the consideration of physiological activity and observation by SEM. By considering the settling behavior, one side of slender type diatoms such as Nitzschia and Synedra is heavier than the o…
Abstract Small‐angle light‐scattering (SALS), Polarized light microscopy (PLM), differntial scanning calorimetry (DSC), and small‐angle x‐ray scattering (SAXS) were used to study morphological changes in segmented polyurethanes with 4,4′‐diphenylmethane diisocyanate (MDI) and 1,4‐butanediol (BD) as the hard segment. I…
It is customary in the physicochemical literature to define the static transverse dielectric function of a polar fluid according to the relation εT(k) = 1 + 4πβST(k), where β=(kBT)−1 and ST(k) is a measure of the static fluctuations of the Fourier components of the transverse part of the electric polarization field in…
Abstract Trichloroacetic acid catalyzed condensation of an aldehyde carrying more than two formyl groups and 3,5-di-tert-butylbenzaldehyde with bis(3-ethyl-4-methyl-2-pyrrolyl)-methane in acetonitrile followed by p-chloranil oxidation gave oligomeric porphyrins in good yield via multiple porphyrin-cyclization.
A theory of the energy exchange between valence electrons and ions in the dense displacement cascades in metals is proposed. It is shown that the theory based on the relaxation of the nonequilibrium electron-ion system gives a common basis for the electronic stopping power of slow ions due to valence electrons and for…
In order to assess the aluminium binding ability of humic and fulvic acids, important organic soil constituents, a pH-potentiometric study was made of the proton and aluminium(III) complexes of various bi-, tri- and tetradentate catechol and salicylic acid derivatives at 25°C and at an ionic strength of 0.20moldm−3 (K…
Surface hydrophobicity has recently been emphasized as an important parameter for functional correlation of proteins. However, evaluations of the parameter by different experimental techniques often do not correlate well with each other. In this paper we have compared surface hydrophobicity of a basic protein with tho…
Polymerizations of racemic- and meso-d,l-lactide were conducted at 120°C in xylylene or in bulk. Lead oxide (PbO), zinc stearate, antimony(III) 2-ethylhexanoate, and bismuth(III) 2-ethylhexanoate were used as initiators. With PbO and Zn stearate, bulk polymerizations were also conducted at 150°C. High yields (⩾90%) we…
Abstract A method for the synthesis of well‐defined poly(alkyl vinyl ether–2‐ethyl‐2‐oxazoline) diblock copolymers with hydrolytically stable block linkages has been developed. Monofunctional poly(alkyl vinyl ether) oligomers with nearly Poisson molecular weight distributions were prepared via a living cationic polyme…