Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRhenium formyl and carboxy complexes derived from the cyclopentadienyl(dicarbonyl)nitrosylrhenium(1+) cation: models for the Fischer-Tropsch and water gas shift reactionsCharles P. Casey, Mark A. Andrews, and James E. RinzCite this: J. Am. Chem. Soc. 1979, 101, 3, 741–743Pub…
Tackification of block copolymers of the linear ABA or radial (AB) x type, in which the center block (B) is in the rubbery state at use temperature, follows principles established for other rubbery polymers except for peculiarities of the systems introduced by the block polymer domain structure. Successful pressure-se…
Image profiles obtained in the scanning electron microscope operating in the charge-collection mode are calculated for a dislocation perpendicular to a surface barrier. The image resolution is not limited by the minority-carrier diffusion length in the semiconductor, but only determined by the generation volume, in ag…
The pathway of acetate assimilation in Methanosarcina barkeri was determined from analysis of the position of label in alanine, aspartate, and glutamate formed in cells grown in the presence of [14C]acetate and by measurement of enzyme activities in cell extracts. The specific radioactivity of glutamate from cells gro…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyoxomolybdate-hydrocarbon interactions. Synthesis and structure of the CH2Mo4O15H3- anion and related methylenedioxymolybdatesV. W. Day, M. F. Fredrich, W. G. Klemperer, and R. S. LiuCite this: J. Am. Chem. Soc. 1979, 101, 2, 491–492Publication Date (Print):January 1, 197…
Abstract The anisotropic emission of the K‐X‐radiation of boron and nitrogen in hexagonal boron nitride BN permits the determination of the π‐ and s̀‐subbands of the two X‐ray spectra. Together with the X‐ray photoelectron spectrum a consistent picture of the valence band of BN is obtained. Position and width of the s…
The attachment of small glass spheres (<50 µm diameter) to the air–water interface is studied by micro-photography on a pendant drop in the presence of a cationic surfactant. The angle of wetting on the attached particles can be estimated from the photographs. Increasing the surfactant concentration increases this ang…
The pretransitional behaviour of a homologous series of mesomorphic compounds, the alkyl cyanobiphenyls (CNρρC n H 2n + 1) for n = 5–12, has been studied as a function of temperature by light scattering in the isotropic phase. The higher homologues, n = 8–12, exhibit a smectic A phase that becomes increasingly importa…
ОБЪЕМНЫЕ ВЗАИМОДЕЙСТВИЯ В СТАТИСТИЧЕСКОЙ ФИЗИКЕ ПОЛИМЕРНОЙ МАКРОМОЛЕКУЛЫИ, М, Дифгииц, А
A strong blue fluorescence has been observed following orange-yellow laser excitation in the 1D2 multiplet of Pr3+ : LaF3. This blue fluorescence has different time evolution depending on the excitation wavelength within the absorption line. Time resolved excitation techniques have been used to study this time evoluti…
Adiabatic elastic moduli for a NaCl single-crystal under high pressures up to 80kbar at room temperature were determined through ultrasonic sound velocity measurements in a cubic anvil-type high pressure apparatus with a solid pressure transmitter. Ultrasonic measurements far both the longitudinal and transverse waves…
Naturally occurring segment-long-spacing crystallites of procollagen collagen have been found in the culture medium of fibroblasts from chick embryo tendon, human skin, and dermatosparaxic calf skin; in whole-mount preparations of cultured human skin fibroblasts; in homogenates of lathyritic chick embryo tendon, carti…
The reentrant, nematic to smectic A phase transition is shown to follow from the Landau theory if one assumes the existence of an optimum density for smectic ordering. The shape of the coexistence line in the P-T plane is fit exactly by this theory. The effects of concentration on reentrant behaviour are also explaine…
In the course of investigations of organic metals we have investigated the cation-radical series TMTTF2-X′ with X′ = BF4, ClO4, PF6, SCN and Br. On this isomorphous series a large range of physical properties have been studied: electrical conductivity, magnetic susceptibility, EPR, optical reflectivity and specific he…
Abstract Adsorption of fibrinogen and albumin from solutions of the proteins singly and in mixtures was studied. A variety of surfaces with varying degrees of hydrophilicity and thrombogenicity was investigated. Adsorption behavior shows a strong dependence on surface properties. All surfaces show a preference for fib…
The photoluminescent and reflectance spectra of MgO smoke have been compared with the spectra of MgO ex-hydroxide and ex-carbonate. Parallel studies by electron microscopy have shown that a strong correlation exists between the optical spectra and the different morphology of the particles obtained by the different rou…
The inducible, mannitol-specific Enzyme II of the phosphoenolpyruvate:sugar phosphotransferase system has been purified approximately 230-fold from Escherichia coli membranes. The enzyme, initially solubilized with deoxycholate, was first subjected to hydrophobic chromatography on hexyl agarose and then purified by se…
Thermal expansion of γ-Mg2SiO4 was measured with X-ray powder diffraction method up to 750°C at atmospheric pressure. The data are analyzed in terms of Gruneisen's theory of thermal expansion and Gruneisen's parameter is obtained to be 1.27. Volume thermal expansion coefficient is 19 at 20°C and 27 at 500°C in unit of…
Nous avons mesuré les variations d'atténuation et de vitesse ultrasonores dans un gel acrylique. En comparant ces résultats avec ceux obtenus dans le solvant pur (H2O), nous avons pu en déduire la constante élastique propre du gel et le coefficient de friction entre le réseau et le solvant. Une étude en fonction de la…
A number of continuous random lattices can be classified as specific one-to-one mappings of ordered lattices of spaces of constant curvature onto the usual 3-dimensional euclidean space. These mappings put emphasis on two types of lattice defects : surface defects for spaces of constant positive curvature (i.e. spheri…