Materials Literature
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The oxidation kinetics of a single crystal of SrTiO 3 were measured with a tensivolumetric system over the temperature range 700°–975° at 0.03 atm oxygen pressure. The oxidation was found to be oxygen diffusion limited with an activation energy of 14.9 ± 1.3 kcal / mole . Combining the kinetic data with relative defec…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInductively coupled plasma-optical emission spectrometry. Application to the determination of alloying and impurity elements in low and high alloy steelsConstance C. Butler, Richard N. Kniseley, and Velmer A. FasselCite this: Anal. Chem. 1975, 47, 6, 825–829Publication Date…
1. A specimen of stereospecifically 2-tritiated 3-hydroxybutyric acid was prepared by hydroboration of ethyl crotonate. It was assumed that the hydroboration reaction took a syn course and hence that (2R,3S) plus (2S,3R)-3-hydroxy[2 minus 3H1]butyric acid was formed after oxidation and hydrolysis. 2. 3RS-3-Hydroxy[2 m…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTManganese(II) porphyrins. Synthesis, structures, and preference for five-coordinationBarbara Gonzalez, Jay Kouba, Sharon Yee, Christopher A. Reed, John F. Kirner, and W. Robert ScheidtCite this: J. Am. Chem. Soc. 1975, 97, 11, 3247–3249Publication Date (Print):May 1, 1975Pub…
Abstract Two component interpenetrating polymer networks (IPN) of the SIN type (simultaneous interpenetrating networks), composed of a polystyrene network (crosslinked with divinyl benzene) and a polyester‐polyurethane network (crosslinked with trimethylolpropane), were made. Electron microscopy and glass‐transition m…
The emission angular distribution, total energy distribution, noise spectrum, and emitter life have been measured for the W/Zr thermal-field cathode. The results give an emitter life in excess of 1000 h at T=1350 to 1450 K, P?2×10−8 Torr, and a total current of ∼100 μA. A low-noise highly confined beam long the (100)…
The simple infinite-aperture charge-density approximation to lattice imaging is extended to include the effects of finite aperture and objective-lens spherical aberration. Images computed using these approximations are compared with images computed by the accurate N-beam technique and with experiment in order to estab…
A new technique for measuring the spectral distribution of photoionization cross sections in photoconductors is presented. The method makes use of the fact that the occupancy of an impurity level is not changed during illumination with photons of different energy if the photocurrent is kept constant. A constant photoc…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemistry of silica supported chromium ions. I. Characterization of the samplesA. Zecchina, E. Garrone, G. Ghiotti, C. Morterra, and E. BorelloCite this: J. Phys. Chem. 1975, 79, 10, 966–972Publication Date (Print):May 1, 1975Publication History Published online1 May 2002Pub…
Several aqueous dispersions of charged polystyrene spheres (mean radius =250 aa) have been studied at very low ionic strength by conventional light scattering and photon correlation spectroscopy. Plotted as a function of scattering angle, the mean scattered intensity exhibited maxima similar to those found in the stru…
Abstract Cobalt(II and III) complexes including Vitamin B12 have been investigated by X-ray photoelectron spectroscopy. Cobalt(II) and cobalt (III) complexes show the 2p1⁄2–2p3⁄2 peak separation of 16.0±0.3 eV and 15.1±0.3 eV, respectively. The data of the binding energies for Co 2p1⁄2, Co 2p3⁄2, N ls and S 2p in coba…
Phase equilibria in the system MgO‐B 2 O 3 were investigated using DTA and quenching techniques. The system contains 4 invariant points. The compounds MgO·2B 2 O 3 and 2MgO·B 2 O 3 melt incongruently at 995° and 1312°C, respectively, whereas 3MgO·B 2 O 3 melts congruently at 1410°C. A eutectic occurs at 1333°C and 71%…
A new analytic approximation to atomic incoherent X-ray scattering intensities is proposed. Unlike other approximations in the literature, the present function has the correct asymptotic behaviour at both large and small values of s. Fits to the incoherent intensities calculated by Cromer are presented for all atoms f…
Some of the limitations inherent in the use of directly measured contact angles for.the determination of filament wetta bility are discussed, and an alternate approach based on the Wilhelmy balance principle is presented. Mathematical interpretation of data obtained allows for determination of wettable cross-sectional…
When vanadium dioxide, VO2, undergoes its semiconductor-to-metal transition at 68 °C its reflectivity decreases by about a factor of 2 throughout the visible range. By using a thin VO2 film on a vanadium substrate we were able to achieve a much higher contrast between the reflectivities of the two VO2 phases. The VO2…
Crystallization sequences of glasses with compositions in the tridymite primary phase field of the MgO‐Al 2 O 3 ‐SiO 2 system were studied by DTA, X‐ray diffraction, and other techniques. Crystallization was catalyzed by the addition of 7 wt% of either ZrO 2 or TiO 2 . Up to 10 wt% CeO 2 was also added to some glasses…
Abstract Various aspects of polyphosphazene chemistry are reviewed. Stable poly (organophosphazenes) can be prepared from an inorganic precursor, poly(dichlorophosphazene), by careful control of polymerization and substitution reaction conditions. The bulk structure and properties of polyphosphazenes are discussed, an…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTX-ray photoelectron spectroscopy of inorganic and organometallic compounds of molybdenumSamuel O. Grim and Luis J. MatienzoCite this: Inorg. Chem. 1975, 14, 5, 1014–1018Publication Date (Print):May 1, 1975Publication History Published online1 May 2002Published inissue 1 May…
A study of the phase transitions in WO3 crystals by Raman and absorption spectroscopy reveals that WO3 possesses two stable (or metastable) modifications at room temperature, differing slightly but definitely in their physical properties. Measurements of electrical conductivity show that both are insulators at low tem…
Preface Symbols used Abbreviations 1. Giant cells as experimental material 2. Two hundred years: early physiology 3. Water relations 4. Permeability to nonelectrolytes 5. Compartments and ionic concentrations 6. Ionic fluxes and kinetic models 7. Electrical properties of membranes 8. Action potentials in charophyte ce…