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STRUCTURAL AND PHASE TRANSFORMATIONS IN CONDENSED SELENIUM

В. С. Минаев、С. П. Тимошенков、В. В. Калугин2005-01-01Journal of Optoelectronics and Advanced Materials

At normal pressure selenium exists in several forms of condensed state: crystalline (hexagonal Se n , α-, β-, γ-monoclinic Se 8 , monoclinic Se 8 ), rhombohedral Se 6 , α- and β-cubic Se, amorphous Se (red, brown and black Se), 4 liquid modifications, vitreous selenium. Structural and phase transformations taking plac…

Phase-change materials and chalcogenidesMineralogy and Gemology StudiesMaterial Science and Thermodynamics

Switchable rewritability of Ag–TiO 2 nanocomposite films with multicolor photochromism

Kenji Naoi、Yoshihisa Ohko、Tetsu Tatsuma2005-01-01Chemical Communications

The photochromism and rewritability of Ag-TiO2 films were deactivated by modification with thiols to make it possible to retain color images displayed on the films (for more than 3 days under white fluorescent lamps), while the deactivated properties were fully reactivated by UV-irradiation.

Advanced Photocatalysis TechniquesGold and Silver Nanoparticles Synthesis and ApplicationsPhotochromic and Fluorescence Chemistry

Oxygen Transport Kinetics in SrFeO[sub 3−δ], La[sub 0.5]Sr[sub 0.5]FeO[sub 3−δ], and La[sub 0.2]Sr[sub 0.8]Cr[sub 0.2]Fe[sub 0.8]O[sub 3−δ] Measured by Electrical Conductivity Relaxation

Jiho Yoo、Atul Verma、Shuangyan Wang 等 4 位作者2005-01-01Journal of The Electrochemical Society

The chemical diffusion and surface exchange coefficients were measured for and at and atm by electrical conductivity relaxation. Values of the chemical diffusion and surface exchange coefficients were obtained by monitoring the variation of electrical conductivity after an abrupt change in oxygen partial pressure. The…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

In vitro endothelialized ePTFE prostheses: clinical update 20 years after the first realization.

Laurence Bordenave、Ph. Fernandez、M. Rémy-Zolghadri 等 6 位作者2005-01-01PubMed

The replacement of arteries with synthetic vascular prostheses often leads to failure when small-diameter or low-flow locations are concerned, due in part to the thrombogenicity of the graft surface. In order to improve long-term patency of these grafts, the concept of endothelial cell seeding has been suggested, the…

Electrospun Nanofibers in Biomedical Applications

From well defined star-microgels to highly ordered honeycomb films

Luke A. Connal、Paul A. Gurr、Greg G. Qiao 等 4 位作者2005-01-01Journal of Materials Chemistry

Star-microgels were prepared in a two-step process known as the arm first approach by Atom Transfer Radical Polymerization (ATRP). Living linear poly(methyl methacrylate) (PMMA), with molecular weight (Mn) of 10000 and 20000, was reacted with ethylene glycol dimethacrylate (EGDMA) as crosslinker and varying amounts of…

Surface Modification and SuperhydrophobicityAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

A surfactant-free route to single-crystalline CeO2 nanowires

Bo Tang、Linhai Zhuo、Jiechao Ge 等 6 位作者2005-01-01Chemical Communications

A surfactant-free route was successfully established to synthesize CeO2 single-crystalline nanowires using H2O2 as oxidizer and template agent.

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Immobilization of a layer of carbon nanofibres (CNFs) on Ni foam: A new structured catalyst support

Nabeel Jarrah、Fahong Li、J.G. van Ommen 等 4 位作者2005-01-01Journal of Materials Chemistry

This work describes the preparation of new materials based on immobilizing carbon nanofibres (CNFs) on the surface of Ni foam. CNFs were catalytically synthesized by decomposition of ethene over the Ni foam. The influence of formation conditions on the morphology of the CNFs, on the mechanical stability of the CNFs–Ni…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

First-principles study of OH-stretching modes in kaolinite, dickite, and nacrite

Etienne Balan、Michele Lazzeri、A. Marco Saitta 等 6 位作者2005-01-01American Mineralogist

The OH-stretching modes of kaolinite group minerals, namely kaolinite, dickite, and nacrite, are investigated within the density functional theory framework. Good agreement between theoretical and experimentally derived structures is obtained. The total energy of the three polymorphs is found to be similar within 1 kJ…

Geological and Geochemical AnalysisSoil and Unsaturated FlowClay minerals and soil interactions

Layered solids as a “molecular container” for pharmaceutical agents: l -tyrosine-intercalated layered double hydroxides

Min Wei、Qi Yuan、David G. Evans 等 5 位作者2005-01-01Journal of Materials Chemistry

L-Tyrosine has been intercalated into NiAl, MgAl and ZnAl layered double hydroxides by coprecipitation. The structure and composition of the intercalated materials have been characterized by X-ray diffraction (XRD) and elemental analysis. It is found that intercalation can inhibit racemization of L-tyrosine under the…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and Materials

An easy and economically viable route for the decoration of carbon nanotubes by magnetite nanoparticles, and their orientation in a magnetic field

François Stoffelbach、Abdelhafid Aqil、Christine Jérôme 等 5 位作者2005-01-01Chemical Communications

A simple, cheap and tunable approach for the decoration of carbon nanotubes by magnetite nanoparticles and their orientation in a magnetic field is reported.

Carbon Nanotubes in CompositesGraphene research and applicationsNanotechnology research and applications

AFM study of cationically charged polymer brushes: switching between soft and hard matter

Tamer Farhan、Omar Azzaroni、Wilhelm T. S. Huck2005-01-01Soft Matter

AFM studies on cationic polymer brushes in water (a good solvent) show that brushes in an extended conformation can be easily deformed or indented by an AFM tip. Experiments on polymer brushes in a more collapsed conformation, using methanol-water as a 'poor solvent' environment, show similar properties. Conversely, t…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

Gas permeation properties of polyethylene-layered silicate nanocomposites

Maged A. Osman、J�rg E. P. Rupp、Ulrich W. Suter2005-01-01Journal of Materials Chemistry

The inorganic cations of clays with different cation exchange capacities (CECs) have been exchanged with alkyl ammonium ions, in which 1–4 octadecyl chains are attached to the nitrogen atom. In this way, organo-montmorillonites (OMs) with different surface coverage and alkyl chain packing density were obtained. Nanoco…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Experimental Studies on the Mechanism of Wet Chemical Etching of Silicon in HF∕HNO[sub 3] Mixtures

Marco Steinert、J. Acker、Antje Henßge 等 4 位作者2005-01-01Journal of The Electrochemical Society

A detailed kinetic study was performed to elucidate the mechanism of wet chemical etching of silicon in a HF-rich mixture. In contrast to earlier studies, the etch rates were determined by dissolution of only a few milligrams of silicon in carefully thermostatted acid mixtures in order to avoid a change in composition…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Use of Fluorophore-Conjugated Lectins To Study Cell-Cell Interactions in Model Marine Biofilms

Barbara Wigglesworth‐Cooksey、Keith E. Cooksey2005-01-01Applied and Environmental Microbiology

Biofilms dominated by pennate diatoms are important in fields as diverse as ship biofouling and marine littoral sediment stabilization. The architecture of a biofilm depends on the fact that much of its mass consists of extracellular polymers. Although most illuminated biofilms in nature are dominated by phototrophs,…

Marine and coastal ecosystemsDiatoms and Algae ResearchMarine Biology and Environmental Chemistry

Biofunctionalization of fluorescent-magnetic-bifunctional nanospheres and their applications

Guoping Wang、Erqun Song、Hai‐Yan Xie 等 9 位作者2005-01-01Chemical Communications

Hydrazide-containing bifunctional nanospheres were covalently coupled on the surface with IgG, avidin, and biotin, to generate novel fluorescent-magnetic-biotargeting trifunctional nanospheres, which can be used in a number of biomedical applications, including visual sorting and manipulation of apoptotic cells as dem…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesMicro and Nano Robotics

Dynamic sol–gel interconversion by reversible cation binding and release in G-quartet-based supramolecular polymers

Assaad Ghoussoub、Jean‐Maríe Lehn2005-01-01Chemical Communications

The bis-guanine monomer G-G forms highly cross-linked, K+ stabilized, polymeric hydrogels that can be reversibly interconverted between gel and sol state via sequential binding and release of K+ by a cryptand undergoing protonation/deprotonation.

Supramolecular Chemistry and ComplexesLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

High temperature glass melt property database for process modeling

Thomas P. Seward、Terese Vascott2005-01-01American Ceramic Society eBooks

Commercial and Statistically Designed Glass Composition (T. Vascott and T.P. Seward III). Gas Solubility and Water Diffusion in Glasses and Melts of Commercial Compositions (J.E. Shelby). Water Diffusion (J.E. Shelby). Solubility and Diffusion of SO3 in Soda-Lime-Silicate Glass Melts at High Temperatures (O.A. Prokhor…

Glass properties and applicationsRecycling and utilization of industrial and municipal waste in materials productionMaterial Science and Thermodynamics

Infrared Spectroscopy and the Chemistry of Dioctahedral Smectites

Will P. Gates2005-01-01Clay Minerals Society eBooks

Abstract In our understanding of the structural chemistry of clay minerals, two problems have yet to be satisfactorily dealt with: (a) to accurately assign cations to available octahedral and tetrahedral sites within the 2:1 layer structure of smectites, and (b) to determine the precise distribution of these cations i…

Clay minerals and soil interactions

Partial discharge characteristics of inverter-fed motor coil samples under ac and surge voltage conditions

Naoki Hayakawa、H. Ōkubo2005-01-01IEEE Electrical Insulation Magazine

This work investigates the partial discharge (PD) characteristics of twisted pair samples for inverter-fed motor coil under ac and surge voltage conditions. It also discusses the difference in the PD inception characteristics of a twisted pair under 60-Hz voltage and surge voltages with a steep wave front. The PDIV un…

High voltage insulation and dielectric phenomenaPlasma Diagnostics and ApplicationsElectrostatic Discharge in Electronics