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Infrared Spectroscopy and X-ray Diffraction Studies of Thermal Behavior and Lamella Structures of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (P(HB-co-HV)) with PHB-Type Crystal Structure and PHV-Type Crystal Structure

Harumi Sato、Yuriko Ando、Hiroshi Mitomo 等 4 位作者2011-03-16Macromolecules

Thermal behavior and lamella structures of poly(3-hydroxybutyrate- co -3-hydroxyvalerate), hereafter P(HB- co -HV) (HV = 9, 15, 21, 28.8, 58.4, 73.9, and 88.6 mol %), were investigated using infrared (IR) spectroscopy, wide-angle X-ray diffraction (WAXD), and differential scanning calorimetry (DSC). Temperature-depend…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

A Metallocorrole with Orthogonal Pyrrole Rings

Kolle E. Thomas、Jeanet Conradie、Lars Kristian Hansen 等 4 位作者2011-03-16European Journal of Inorganic Chemistry

Abstract In contrast to sterically hindered metalloporphyrins, which are almost always strongly nonplanar, similarly substituted metallocorroles are generally relatively planar. A crystal structure of a copper β‐octakis(trifluoromethyl)‐ meso ‐triarylcorrole, however, has revealed a corrole macrocycle with an unpreced…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistrySurface Chemistry and Catalysis

Characterization of Dynamic Tensile Testing Using Aluminum Alloy 6061-T6 at Intermediate Strain Rates

Deju Zhu、Barzin Mobasher、Subramaniam Rajan 等 4 位作者2011-03-16Journal of Engineering Mechanics

Dynamic tensile tests are conducted on aluminum alloy (AA) 6061-T6 using a high-speed servohydraulic machine at intermediate strain rates to validate the testing technique and to investigate the strain-rate effect on the material’s stress-strain behavior and failure mode. We present the experimental procedures and res…

Metal Forming Simulation TechniquesHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

A Supramolecular Heteropolyoxopalladate {Pd15} Cluster Host Encapsulating a {Pd2} Dinuclear Guest: [PdII2⊂{H7PdII15O10(PO4)10}]9−

Feng Xu、Rachel A. Scullion、Jun Yan 等 9 位作者2011-03-16Journal of the American Chemical Society

A high-nuclearity polyoxopalladate compound, [Pd(II)(2)⊂{H(7)Pd(II)(15)O(10)(PO(4))(10)}](9-) {Pd(II)(17)}, comprising a {Pd(15)} host occupied by a {Pd(2)} guest and the parent pristine "empty" [H(7)Pd(II)(15)O(10)(P(V)O(4))(10)](13-) {Pd(15)} cluster have both been prepared and characterized by single-crystal X-ray…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

Suspension of Water Droplets on Individual Pillars

Teodor Tóth、Davide Ferraro、Enrico Chiarello 等 7 位作者2011-03-16Langmuir

We report results of extensive experimental and numerical studies on the suspension of water drops deposited on cylindrical pillars having circular and square cross sections and different wettabilities. In the case of circular pillars, the drop contact line is pinned to the whole edge contour until the drop collapses…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferNanomaterials and Printing Technologies

A Modular Phase Transfer and Ligand Exchange Protocol for Quantum Dots

Joshua Zylstra、Jennifer Amey、Nathaniel J Miska 等 8 位作者2011-03-16Langmuir

In this paper, we describe a quantum dot (qdot) phase transfer protocol using ligand exchange and the amino acid histidine. The phase transfer from nonpolar solvents to aqueous buffers is homogeneous, and no appreciable precipitation occurs. The molecule histidine was chosen in order to first displace the organic enca…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsMolecular Junctions and Nanostructures

Computational studies of doped nanostructures

James R. Chelikowsky、M. M. G. Alemany、T-L Chan 等 4 位作者2011-03-16Reports on Progress in Physics

One of the most challenging issues in materials physics is to predict the properties of defects in matter. Such defects play an important role in functionalizing materials for use in electronic and optical devices. As the length scale for such devices approaches the nano-regime, the interplay of dimensionality, quantu…

Quantum Dots Synthesis And PropertiesNanowire Synthesis and ApplicationsElectronic and Structural Properties of Oxides

A predictive interatomic potential for He in Cu and Nb

A. Kashinath、Michael J. Demkowicz2011-03-16Modelling and Simulation in Materials Science and Engineering

First principles calculations show that two-body forces are sufficient to describe interactions of He with fcc Cu and bcc Nb. This property is explained directly from calculated charge density distributions and used to construct a Cu?Nb?He interatomic potential that predicts accurate He impurity energies despite not b…

Advanced Chemical Physics StudiesFusion materials and technologiesSuperconducting Materials and Applications

Carrier recombination dynamics in individual CdSe nanowires

Felix Vietmeyer、Pavel A. Frantsuzov、Boldizsár Jankó 等 4 位作者2011-03-16Physical Review B

Carrier dynamics in single CdSe nanowires (NWs) have been studied using various techniques. They include measurements of single wire emission intensities as a function of pump fluence, excitation intensity-dependent emission quantum yields, and excited-state lifetimes. Ensemble transient differential absorption studie…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Antimicrobial Edible Apple Films Inactivate Antibiotic Resistant and Susceptible Campylobacter jejuni Strains on Chicken Breast

Rita M. Mild、L A Joens、Mendel Friedman 等 7 位作者2011-03-16Journal of Food Science

UNLABELLED: Campylobacter jejuni is the leading cause of bacterial diarrheal illness worldwide. Many strains are now becoming multidrug resistant. Apple-based edible films containing carvacrol and cinnamaldehyde were evaluated for bactericidal activity against antibiotic resistant and susceptible C. jejuni strains on…

Essential Oils and Antimicrobial ActivityNanocomposite Films for Food PackagingAntimicrobial agents and applications

Stepwise Neutral−Ionic Phase Transitions in a Covalently Bonded Donor/Acceptor Chain Compound

Hitoshi Miyasaka、Natsuko Motokawa、T. Chiyo 等 7 位作者2011-03-16Journal of the American Chemical Society

Neutral (N)-ionic (I) transitions in organic donor (D)/acceptor (A) charge-transfer complexes are intriguing because a 'reservoir of functions' is available. For systematically controlling N-I transitions, tuning the ionization potential of D and the electron affinity of A is extremely important. However, the effect o…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryOrganic and Molecular Conductors Research

Revealing the Interface in Polymer Nanocomposites

Mauro Zammarano、Paul H. Maupin、Li‐Piin Sung 等 7 位作者2011-03-16ACS Nano

The morphological characterization of polymer nanocomposites over multiple length scales is a fundamental challenge. Here, we report a technique for high-throughput monitoring of interface and dispersion in polymer nanocomposites based on Förster resonance energy transfer (FRET). Nanofibrillated cellulose (NFC), fluor…

Polymer Nanocomposites and PropertiesAdvanced Cellulose Research StudiesDielectric materials and actuators

Biodegradability studies on natural fibers reinforced polypropylene composites

S. K. Chattopadhyay、Sanjay Singh、Nilay Pramanik 等 7 位作者2011-03-16Journal of Applied Polymer Science

Abstract Various composites of polypropylene (PP) produced using natural fibers such as pineapple leaf fiber, banana fiber, and bamboo fiber were studied for their degree and rate of aerobic biodegradation. Composites used contained 10, 15, and 50% volume fractions of pineapple leaf fiber, banana fiber, and bamboo fib…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies

Facile Synthesis of Polysulfoaminoanthraquinone Nanosorbents for Rapid Removal and Ultrasensitive Fluorescent Detection of Heavy Metal Ions

Mei‐Rong Huang、Shaojun Huang、Xin‐Gui Li2011-03-16The Journal of Physical Chemistry C

Poly(5-sulfo-1-aminoanthraquinone) nanoparticles were facilely synthesized by a chemical oxidative polymerization of 5-sulfo-1-aminoanthraquinone. The polymerization parameters such as oxidant species, acid species, acid concentration, oxidant/monomer ratio, polymerization time, and temperature were systematically stu…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Anomalously Large Polarization Effect Responsible for Excitonic Red Shifts in PbSe Quantum Dot Solids

Abraham Wolcott、Vincent Doyeux、Cory A. Nelson 等 10 位作者2011-03-16The Journal of Physical Chemistry Letters

The formation of solid thin films from colloidal semiconductor quantum dots (QDs) is often accompanied by red shifts in excitonic transitions, but the mechanisms responsible for the red shifts are under debate. We quantitatively address this issue using optical absorption spectroscopy of two-dimensional (2D) and three…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Enhanced Photoluminescence and Field-Emission Behavior of Vertically Well Aligned Arrays of In-Doped ZnO Nanowires

Mashkoor Ahmad、Hongyu Sun、Jing Zhu2011-03-16ACS Applied Materials & Interfaces

Vertically oriented well-aligned Indium doped ZnO nanowires (NWs) have been successfully synthesized on Au-coated Zn substrate by controlled thermal evaporation. The effect of indium dopant on the optical and field-emission properties of these well-aligned ZnO NWs is investigated. The doped NWs are found to be single…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Phyllotactic Description of Hard Sphere Packing in Cylindrical Channels

A. Mughal、Ho-Kei Chan、D. Weaire2011-03-16Physical Review Letters

We develop a simple analytical theory that relates dense sphere packings in a cylinder to corresponding disk packings on its surface. It applies for ratios R=D/d (where d and D are the diameters of the hard spheres and the bounding cylinder, respectively) up to R=1+1/sin(π/5). Within this range the densest packings ar…

Granular flow and fluidized bedsBlock Copolymer Self-AssemblyPickering emulsions and particle stabilization

Advances in Composite Materials - Ecodesign and Analysis

Brahim Attaf2011-03-16InTech eBooks

By adopting the principles of sustainable design and cleaner production, this important book opens a new challenge in the world of composite materials and explores the achieved advancements of specialists in their respective areas of research and innovation. Contributions coming from both spaces of academia and indust…

Material Properties and Applications

Observation of Dynamic Strain Hardening in Polymer Nanocomposites

Brent J. Carey、Prabir K. Patra、Lijie Ci 等 5 位作者2011-03-16ACS Nano

Most materials respond either elastically or inelastically to applied stress, while repeated loading can result in mechanical fatigue. Conversely, bones and other biomechanical tissues have the ability to strengthen when subjected to recurring elastic stress. The cyclic compressive loading of vertically aligned carbon…

Carbon Nanotubes in CompositesCellular Mechanics and InteractionsNanotechnology research and applications

Influence of Chain Topology on Polymer Dynamics and Crystallization. Investigation of Linear and Cyclic Poly(ε-caprolactone)s by 1H Solid-State NMR Methods

Kerstin Schäler、Elena Ostas、Klaus Schröter 等 6 位作者2011-03-16Macromolecules

High Resolution Image Download MS PowerPoint Slide We report on the investigation of cyclic and comparable linear poly(ε-caprolactone)s (PεCL) with molecular weight between 50 and 80 kg/mol with regard to chain mobility in the melt and crystallinity using low-field solid-state 1 H NMR. Our results from NMR Hahn echo a…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesAdvanced NMR Techniques and Applications