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The applied electric field at the onset of polarization reversal during switching of a triglycine sulphate single crystal with a sinusoidal applied field has been measured as a function of crystal thickness. In contrast to the sinusoidal coercive field measurements of Pulvari and Kuebler (1958), this field is frequenc…
Abstract The author has shown the effect of various inorganic ions on the polymorphic crystallization of calcium carbonate from a bicarbonate solution. No definite conclusion regarding the mechanism to give calcite, aragonite or vaterite can yet be made, but these data help to give a pattern of the influence of inorga…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTurbostratic1 Boron Nitride, Thermal Transformation to Ordered-layer-lattice Boron NitrideJ. Thomas, N. E. Weston, and T. E. O'ConnorCite this: J. Am. Chem. Soc. 1962, 84, 24, 4619–4622Publication Date (Print):December 1, 1962Publication History Published online1 May 2002Pub…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA THEORY OF THE LOW-FREQUENCY DIELECTRIC DISPERSION OF COLLOIDAL PARTICLES IN ELECTROLYTE SOLUTION1,2Gerhard SchwarzCite this: J. Phys. Chem. 1962, 66, 12, 2636–2642Publication Date (Print):December 1, 1962Publication History Published online1 May 2002Published inissue 1 Dec…
Abstract A discussion is commenced in which the electronic properties of tetrahedral intermetallic compounds are described in terms of localized molecular-orbital bonds. The correct definitions of covalency and polarity of these bonds are linked with the netionicity of the atoms of the crystal. Detailed non-empirical…
An analytical investigation is made of the geometry of an edge dislocation in a simple atomic model of an infinite crystal, and the effect on the dislocation of externally applied shear stress. This study indicates that in dislocation theory significant results may be obtained from the discrete model, on which accurat…
The absorption and fluorescence spectra of SmCl3 have been studied at 4°K and the Zeeman effects of many lines obtained in a magnetic field of 35 100 G. The lower group of levels obtained chiefly from the fluorescence spectrum can be unambiguously identified as the multiplet components of the 6H and 6F levels. The sit…
A new type of luminescence in nominally pure alkali halide crystals was studied. At room temperature the excitation was most efficient in the wavelength region that has been associated with band-to-band transitions. It is suggested that the emission results from the capture of a hole by an $F$ center. In agreement wit…
Fluorescence-polarization data on porphyrins are reported. The results can be readily interpreted in terms of the theory of polarization spectroscopy and the theory of the electronic and vibrational structure of these molecules. It is shown how these two theories combine to interpret most of the data, but some anomali…