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Effects of doped dialkylazobenzenes on helical pitch of cholesteric liquid crystal with medium molecular weight: utilisation for full-colour image recording

Masaya Moriyama、Soyoung Song、Hiro Matsuda 等 4 位作者2001-01-01Journal of Materials Chemistry

The effects of small amounts of achiral photochromic dopants, 4,4′-di-n-alkylazobenzenes, with various lengths of substituted alkyl chain (CnH2n + 1 ∶ n = 4, 7, 11, 12, 13, 14, 15, 16) on the helical pitch of a cholesteric liquid crystal (CLC) with ca. 1000 molecular weight were investigated in order to utilise the ch…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

In situ oxygen atom erosion study of a polyhedral oligomeric silsesquioxane-polyurethane copolymer

Gar B. Hoflund、Rene I. Gonzalez、Shawn H. Phillips2001-01-01Journal of Adhesion Science and Technology

The surface of a polyhedral oligomeric silsesquioxane-polyurethane copolymer has been characterized in situ using X-ray photoelectron spectroscopy before and after exposure to incremental fluences of oxygen atoms produced by a hyperthermal oxygen atom source. The data indicate that the atomic oxygen initially attacks…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchSilicone and Siloxane Chemistry

Kinetic aspects of superfast consolidation of silicon nitride based ceramics by spark plasma sintering

Zhijian Shen、Mats Nygren2001-01-01Journal of Materials Chemistry

A newly developed novel rapid densification process named Spark Plasma Sintering (SPS) has been successfuly applied to compact silicon nitride based ceramics. In this process the precursor powders are pressed uniaxially in a carbon die, and an on–off pulsed DC voltage is applied simultaneously. The current passes thro…

Advanced ceramic materials synthesisSemiconductor materials and devicesMXene and MAX Phase Materials

Electroactive Poly(aromatic amine) Films for Iron Protection in Sulfate Medium

Álvaro Meneguzzi、Minh Chau Pham、Jean Lacroix 等 7 位作者2001-01-01Journal of The Electrochemical Society

Polyaniline (PANi) and poly(1,5-diaminonaphthalene) (PDAN) films can be deposited on iron from aqueous sulfuric acid. The films exhibit electroactive properties similar to those of PANi and PDAN generated on platinum. Electrosynthesis performed in the presence of both monomers leads to a composite film which presents…

Electrochemical sensors and biosensorsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Crystal structures, magnetic and spectroscopic properties of manganese(II), cobalt(II), nickel(II) and zinc(II) dichloro complexes bearing two 2-pyridyl-substituted imino nitroxides †

Youhei Yamamoto、Takayoshi Suzuki、Sumio Kaizaki2001-01-01Journal of the Chemical Society Dalton Transactions

Four new complexes of formula [MCl2(IM2py)2], where M = Mn(II), Co(II), Ni(II) or Zn(II); IM2py = 4,4,5,5-tetramethyl-2-(2-pyridyl)-imidazolin-1-oxyl, have been prepared, and examined from viewpoints of the crystal structures, magnetic and spectroscopic properties. All the complexes crystallize in an isomorphous space…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Nanopore and nanoparticle catalysts

John Meurig Thomas、Robert Raja2001-01-01The Chemical Record

The design, atomic characterization, performance, and relevance to clean technology of two distinct categories of new nanocatalysts are described and interpreted. Exceptional molecular selectivity and high activity are exhibited by these catalysts. The first category consists of extended, crystallographically ordered…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisSurface Chemistry and Catalysis

Promoting Angiogenesis in Engineered Tissues

Kamal H. Bouhadir、David Mooney2001-01-01Journal of drug targeting

There is a tremendous need for organs and tissues to replace those lost due to diseases or trauma. In theory, transplanting cells on biomaterial matrices can create functional tissue. A critical question, however, is how to supply cells embedded within large cell-polymer constructs with sufficient oxygen and nutrients…

Angiogenesis and VEGF in CancerElectrospun Nanofibers in Biomedical Applications3D Printing in Biomedical Research

Microstructures and Mechanical Properties of Equal Channel Angular Pressed 5083 Al Alloy

Si‐Young Chang、Jung nbsp Guk Lee、Kyung‐Tae Park 等 4 位作者2001-01-01MATERIALS TRANSACTIONS

An ultra-fine grained (UFG) structure was introduced in a commercial 5083 Al alloy with an initial grain size of ∼ 200 \\micron using the equal channel angular pressing (ECAP) technique. ECAP was successfully conducted at 473 K on the same sample up to a total of 8 pressings through the die such that the sample was ro…

Microstructure and mechanical propertiesMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Advanced chemical deposition techniques - from research to production

Rainer Waser、Theo Schneller、Susanne Hoffmann‐Eifert 等 4 位作者2001-01-01Integrated ferroelectrics

Chemical deposition techniques show distinct advantages for research tasks as well as for microelectronic production lines. This review will summarize the state of the art of the Chemical Solution Deposition (CSD) and of the Metal-Organic Chemical Vapor Deposition (MOCVD) processes for high-permittivity, ferroelectric…

Ferroelectric and Piezoelectric MaterialsElectronic and Structural Properties of OxidesElectrophoretic Deposition in Materials Science

Investigation of carbon chemical erosion with increasing plasma flux and density

D.G. Whyte、George Tynan、R.P. Doerner 等 4 位作者2001-01-01Nuclear Fusion

The possible reduction of the chemical erosion yield of carbon Y chem with increasing hydrogenic ion flux is a critical issue for the use of carbon based plasma facing materials in future high flux confinement devices. The PISCES linear plasma device is used to assess carbon Y chem through nearly an order of magnitude…

Diamond and Carbon-based Materials ResearchPlasma Diagnostics and ApplicationsDust and Plasma Wave Phenomena

Photochromism of spiropyran in molecular sieve voids: effects of host–guest interaction on isomer status, switching stability and reversibility

Carsten Schomburg、Michael Wark、Yven Rohlfing 等 5 位作者2001-01-01Journal of Materials Chemistry

Spiropyran or its preferred configurational isomers, respectively, are incorporated in faujasite (NaY, HY and DAY) cages by in situ synthesis, and in Si-MCM-41 channels by wetness impregnation. Luminescence spectra of the colored isomers indicate the non-aggregated incorporation of merocyanine forms. High quantum yiel…

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

The Performance of Vanadium Oxide Nanorolls as Cathode Material in a Rechargeable Lithium Battery

Sara Nordlinder、Kristina Edström、Torbjörn Gustafsson2001-01-01Electrochemical and Solid-State Letters

Vanadium oxide nanorolls have for the first time been successfully used as cathode material in a rechargeable lithium battery. The rolls consist of vanadium oxide sheets arranged in a scroll-like manner. The layers are separated by structure directing templates ( e.g. , primary amines) which can be readily exchanged b…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Oxygen Permeation Through Cobalt-Containing Perovskites: Surface Oxygen Exchange vs. Lattice Oxygen Diffusion

Kevin Huang、John B. Goodenough2001-01-01Journal of The Electrochemical Society

The oxygen permeation fluxes from to across cobalt-containing perovskite ceramic membranes and were measured by gas chromatography as functions of oxygen chemical potential gradient, temperature, thickness, and catalytic activity on the surface. Power indexes for uncatalyzed and for were obtained when vs. was plotted…

Ferroelectric and Piezoelectric MaterialsAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides

A Grand Canonical Monte Carlo study of argon adsorption/condensation in mesoporous silica glasses

Roland J.‐M. Pellenq、B. Rousseau、Pierre Levitz2001-01-01Physical Chemistry Chemical Physics

We have studied adsorption of argon in a mesoporous silica controlled porous glass (CPG) over a wide range of temperatures by means of Grand Canonical Monte Carlo (GCMC) simulation. A numerical sample of the CPG adsorbent has been obtained by using an off-lattice reconstruction method recently introduced to reproduce…

Phase Equilibria and ThermodynamicsTheoretical and Computational PhysicsMesoporous Materials and Catalysis

Competitive Adsorption Reaction Mechanism of Ni/Yttria-Stabilized Zirconia Cermet Anodes in H[sub 2]-H[sub 2]O Solid Oxide Fuel Cells

Manabu Ihara、Takeshi Kusano、Chiaki Yokoyama2001-01-01Journal of The Electrochemical Society

The reaction mechanism of the most commonly used anode material, Ni/yttria-stabilized zirconia (YSZ) cermets, in solid oxide fuel cells (SOFCs) was investigated. Because the reaction mechanism for the Ni/YSZ anode in has not been conclusively determined, we investigated the detailed dependence of dc polarization and i…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsChemical Looping and Thermochemical Processes

Syntheses and properties of PI/clay hybrids

Aijuan Gu、Shiao‐Wei Kuo、Feng‐Chih Chang2001-01-01Journal of Applied Polymer Science

A new organomontmorillonite (CM) for PI hybrids has been developed by ion-exchange reaction of cetyl pyridum chloride with Na+ montmorillonite (MMT). Polyimide/clay hybrids have been synthesized by employing two methods. Method I is by first blending a dimethylacetamide (DMAC) solution of 4,4′-oxydianiline diamine (OD…

Polymer Nanocomposites and PropertiesDielectric materials and actuatorsSynthesis and properties of polymers

Analysis of interior permanent magnet synchronous motor designed for flux weakening operation

Bojan Štumberger、Anton Hamler、M. Trlep 等 4 位作者2001-01-01IEEE Transactions on Magnetics

The paper presents a finite element method (FEM) based analysis of interior permanent magnet synchronous motor, designed for flux-weakening operation. Flux-weakening performance determined from the FEM analysis on the proposed permanent magnet motor structure is presented in order to verify the suitability of the desi…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsInduction Heating and Inverter Technology

Formation of porous poly(ethylene-co-vinyl alcohol) membrane via thermally induced phase separation

Hideto Matsuyama、Tomofumi Iwatani、Yoshiro Kitamura 等 5 位作者2001-01-01Journal of Applied Polymer Science

Crystalline poly(ethylene-co-vinyl alcohol) (EVOH) membranes were prepared by a thermally induced phase separation (TIPS) process. The diluents used were 1,3-propanediol and 1,3-butanediol. The dynamic crystallization temperature was determined by DSC measurement. No structure was detected by an optical microscope in…

Polymer crystallization and propertiesFuel Cells and Related MaterialsBlock Copolymer Self-Assembly

Spin Coupling Interactions in Transition Metal Complexes Containing Radical o-Semiquinone Ligands. A Review

Cortlandt G. Pierpont、Attia S. Attia2001-01-01Collection of Czechoslovak Chemical Communications

Transition metal complexes of o -semiquinone (SQ) ligands have been studied extensively over the past 25 years. A particularly interesting aspect of this coordination chemistry concerns magnetic interactions between paramagnetic metal ions and the radical anionic ligands. In this review we begin with a survey of relat…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Vascularized three-dimensional skeletal muscle tissue-engineering.

Amulya K. Saxena、G. H. Willital、Joseph P. Vacanti2001-01-01PubMed

Medical science continues to battle against the loss or failure of organs or tissues. Since, skeletal muscle loss lead not only to the functional compromise of the affected site, but also a structural deformation; tissue engineering of skeletal muscle attempts to provide solutions to replace loss of tissue contour and…

Muscle Physiology and DisordersElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine