Materials Literature
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Experimental determinations of the mineral/liquid partition coefficients of REE (La, Sm, Eu, Gd, Tb, Yb and Lu), Sc and Sr are reported for the minerals perovskite, spinel and melilite in synthetic systems. Perovskite concentrates light REE with respect to the residual liquid but shows no preference for heavy REE. Spi…
The crystal structures of the intercalation compounds of Li x TiS 2 are investigated by neutron diffraction for x = 0.12, 0.33, 0.67, and 1.0. The Li atoms are shown to preferentially occupy the octahedral sites in the van der Waals gaps of the host TiS 2 lattice for all values of x and no evidence for three-dimension…
Abstract Mean free paths for inelastic scattering (λ) of low energy electrons in poly(methylmethacrylate) (PMMA) have been determined by measuring Al Kα excited C 1s and Si 2s photoelectron signal intensities as a function of ellipsometrically determined thicknesses of PMMA overlayers on silicon substrates. The λ valu…
Effects of electrolytic bubbles on the IR drop of caustic soda solution in a vertical cell of one meter height were studied under both free and forced convection. Three pairs of Luggin‐Haber probes were positioned near the anode and the cathode to determine the solution IR drop during electrolysis. A sectioned electro…
High pressures were generated using a diamond indentor technique. The phase transition in silicon loaded in the [100] direction and silicon loaded in the [111] direction under high pressure was studied. From the behavior of electrical resistance of silicon loaded in the [100] direction, it was found that it becomes me…
Abstract The morphology of poly(butylene terephthalate) (PBT) crystallized from the melt at various temperatures was studied by small‐angle light scattering, polarizing microscopy, and wide‐angle x‐ray diffraction. Spherulites with a maltese cross at 45° to the polars formed at lower temperatures while spherulites hav…
The glass-forming region was determined for the system Ge-Bi-Se; 13 at.% Bi was found to be incorporated at its maximum content into glasses, the Ge content of which was 20 at.%. Electrical resistivity, thermoelectric power, and optical absorption coefficient were measured mainly on a series of Ge20BixSe80−x glasses (…
Abstract Investigations of morphological changes which are induced in segmented elastomers by annealing and quenching are reported. Four different polymers were studied each based on the same soft segment—1000 or 2000 molecular weight poly(tetramethylene oxide). The hard segments were 4,4′‐diphenylmethane diisocyanate…
The mechanism of formation of porous silicon layer (PSL) has been studied according to the following experimental results. PSL is formed by the local dissolution of silicon which occurs only at the base of the pores. The concentration of the electrolyte in the pores of PSL is constant during anodization and the anodic…
Abstract A complete assignment for the modes obtained from resonance Raman scattering on cis‐ and trans‐polyacetylene is reported. The Raman lines in the cis‐isomer indicate a well expressed one dimensional behaviour of the chain. From the line profile and line position of the resonance enhanced CC stretch modes in t…
Because of their small particle sizes and v~riable degrees of crystal perfection, it is not surprisi4g that clay minerals proved extremely difficult to characterize adequately prior to the development of ~odem analytical techniques. Problems in charactetization led quite naturally to problems in nomenclatute, undoubte…
"Optical Crystallography." Optica Acta: International Journal of Optics, 27(2), p. 145
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPorphyrins. 40. Electronic spectra and four-orbital energies of free-base, zinc, copper, and palladium tetrakis(perfluorophenyl)porphyrinsP. J. Spellane, M. Gouterman, A. Antipas, S. Kim, and Y. C. LiuCite this: Inorg. Chem. 1980, 19, 2, 386–391Publication Date (Print):Febru…
Transverse and longitudinal elastic strain have been measured for electric fields applied along the 〈100〉 direction in single crystals of lead magnesium niobate [Pb(Mg1/3Nb2/3)03], using a bonded strain gauge technique. A quadratic electrostrictive relation holds between induced elastic strain and electric polarizatio…
Thermal density fluctuations within phases and finite interphase widths lead to systematic deviations from Porod's law. The validity of present methods used to analyze these deviations and determine diffuse-boundary widths is determined. In view of the inadequacies found in these methods, a simple yet accurate method…
Structural phase transitions can be studied by a variety of techniques; macroscopic fields, X-ray, light and neutron diffraction, and resonance methods. The information which can be obtained by these different techniques about the order parameter and susceptibility at structural phase transitions is described and comp…
Abstract Hydrotalcite solid solutions were prepared by coprecipitation followed by hydrothermal treatment between 150° and 250°C. Based on the structural formula [Mg 1−x Al x (OH) 2 ] x+ [(CO 3 ) x/2 • mH 2 O] x− , pure solid solutions were formed in the range A1/(A1 + Mg) = 0.2 to 0.33, where m = (1 − 3x/2). Maximum…
A systematic exposition is given of a recently developed theory of the low-frequency spin dynamics of any magnetic material in which the magnetic order is caused by exchange forces that considerably exceed the relativistic interactions. The proposed approach does not use any model representations of the state of the m…
Administration of cis-dichlorodiammineplatinum(II) may be associated with a number of serious side effects, including nephrotoxicity, gastroeintestinal side effects (nausea, vomiting, and diarrhea), myelosuppression, and occasional transient elevations in liver function tests. In addition, ototoxicity (tinnitus and he…
Abstract Polarized neutron diffraction has been used to investigate the spin delocalization from the high‐spin Fe(III) sites to the low‐spin Fe(II) in deuteriated Prussian Blue, Fe 4 [Fe(CN) 6 ] 3 · xD 2 O. Measurements of the 111, 200, and 400 reflections were made on a powdered sample at 3 K and 4.8 T using a neutro…