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Trap spectroscopy by the fractional glow technique

I. Tāle1981-07-16physica status solidi (a)

A theory of the fractional glow technique (FGT) for an arbitrary heating regime and first-order recombination kinetics is developed. In order to describe a trap distribution function (TDF) its characteristics: (i) the mean activation energy, (ii) the mean frequency factor, (iii) the recombination intensity, (iv) the F…

Thermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structurethermodynamics and calorimetric analyses

Electronic structure ofTl3AsSe3

M. D. Ewbank、S. P. Kowalczyk、E. A. Kraut 等 4 位作者1981-07-15Physical review. B, Condensed matter

An experimental and theoretical investigation of the electronic structure of a ternary semiconductor, ${\mathrm{Tl}}_{3}$As${\mathrm{Se}}_{3}$, is reported. The total valence-band density of states has been measured by x-ray photoelectron spectroscopy (XPS). A simple prescription, utilizing atomic term values, is sugg…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyOptical properties and cooling technologies in crystalline materials

Self-consistent-average-phonon equation of state. Formalism and comparison with self-consistent-phonon calculations

K. Shukla、A. Paskin、D. O. Welch 等 4 位作者1981-07-15Physical review. B, Condensed matter

The self-consistent-phonon (SCP) formalism has proved valuable in calculating the anharmonic contributions to lattice-dynamic properties. It is a numerical iterative procedure for obtaining the equation of state and other thermodynamic functions. Replacing the sums over frequencies in the SCP formalism by appropriate…

High-pressure geophysics and materialsThermal properties of materialsThermal Expansion and Ionic Conductivity

Surface plasmons on a large-amplitude grating

Nina E. Glass、A. A. Maradudin1981-07-15Physical review. B, Condensed matter

Dispersion relations are obtained by two different methods for surface plasmons (in the nonretarded limit) propagating on the surface of a dielectric medium on which a large-amplitude grating has been ruled. The first method is based on the Rayleigh hypothesis; the second method is based on the extinction-theorem form…

Optical Coatings and GratingsNear-Field Optical MicroscopySurface Roughness and Optical Measurements

Magnetic Properties of a Ternary Alloy Mn0.5V0.5-yAly

Yutaka Yoshida、Masayuki Kawakami、Takurô Nakamichi1981-07-15Journal of the Physical Society of Japan

The saturation magnetization per Mn atom P s at 4.2 K was obtained with a relation P s =3.8 y µ B for y c < y <0.35 and P s =2.8 y µ B for y < y c in Mn 0.5 V 0.5- y Al y . Here y c ≈0.2 which corresponds to the concentration at the boundary between B2 and L2 1 (Heusler) structures. The 55 Mn NMR frequency at 4.2 K al…

Magnetic and transport properties of perovskites and related materialsMagnetic Properties of AlloysHeusler alloys: electronic and magnetic properties

Infrared spectra of HfS3

S. Jandl、J. Deslandes1981-07-15Physical review. B, Condensed matter

The infrared reflectivity and transmission on the quasi-one-dimensional structure Hf${\mathrm{S}}_{3}$ of light with polarizations both parallel and perpendicular to the chains are measured. They are compared with the frequencies already observed in Raman scattering indicating that the interchain coupling is very weak.

2D Materials and ApplicationsOrganic and Molecular Conductors ResearchInorganic Chemistry and Materials

Vibrational dynamics of glassy and molten ZnCl2

F. Aliotta、G. Maisano、P. Migliardo 等 7 位作者1981-07-15The Journal of Chemical Physics

Polarized Raman spectra of ZnCl2 were obtained in the liquid phase near the melting point (T = 598 K), and in the glassy phase (T = 293 K). Measurements were performed down to a very low frequency shift (2 cm−1) from the exciting line. Our analysis of the Raman data provides an interpretation of the collision-like con…

Material Dynamics and PropertiesGlass properties and applicationsPhase-change materials and chalcogenides

Optical absorption and emission spectra of Cs2NaHoCl6

J. P. Morley、Thomas Faulkner、F. S. Richardson 等 4 位作者1981-07-15The Journal of Chemical Physics

Optical absorption and emission spectra are reported for the cubic Cs2NaHoCl6 elpasolite system. Detailed energy and intensity analyses of the high-resolution, variable-temperature spectra allow characterization of the crystal field energy level structure associated with eleven of the Ho3+ term levels. The term levels…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

Theory of the Invar Effect in FeNi Alloy

Y. Kakehashi1981-07-15Journal of the Physical Society of Japan

Anomalous thermal expansion of FeNi alloy is calculated on the basis of Liberman-Pettifor's virial theorem and the full single site approximation in the functional integral method. Results explain well the Invar effect. In general, the electronic contribution to the thermal expansion consists of three terms, i.e. the…

Chemical and Physical Properties of MaterialsThermodynamic and Structural Properties of Metals and AlloysMetallurgical and Alloy Processes

The surface photoeffect

Harry Levinson、E. W. Plummer1981-07-15Physical review. B, Condensed matter

Angle-resolved photoelectron spectroscopy coupled with the polarized continuum of synchrotron radiation has been used to identify unambiguously a large enhancement in the photoexcitation from A(100) due to the surface photoeffect. This large enhancement in the cross section occurs only when the excitation field has a…

Advanced Chemical Physics StudiesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Spin Density Wave and Superconductivity in Highly Anisotropic Materials

Kazushige Machida1981-07-15Journal of the Physical Society of Japan

A theory for the coexistence problem of the spin density wave (SDW) and superconductivity (SC) in highly anisotropic materials is presented. On the basis of a simplified electronic band model a Hartree-Fock approximation is applied. It is concluded that the SDW state is precluded when the SC state developes at a highe…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Elastic constants and molecular association of cyano-substituted nematic liquid crystals

Hp. Schad、Maged A. Osman1981-07-15The Journal of Chemical Physics

The dielectric and elastic properties of cyano-substituted nematic liquid crystals are investigated. The results are discussed in terms of molecular properties and molecular association.

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPhotochemistry and Electron Transfer Studies

Electron Spin Resonance Study of Defects Formed in Electron-Irradiated ZnS by Room-Temperature Annealing

Y. Shono1981-07-15Journal of the Physical Society of Japan

Electron spin resonance signals due to isolated Zn vacancies decreased in intensity and new signals ( A 1 and A 2 ) increased as electron-irradiated ZnS containing Cl impurity was kept at room temperature. The features of the new signals are as follows: For the A 1 signal g // =2.0545 and g ⊥ =2.0264, where g // is ta…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Self-diffusion in chromium

J. N. Mundy、H. A. Hoff、Joshua Pelleg 等 6 位作者1981-07-15Physical review. B, Condensed matter

Self-diffusion in chromium single crystals has been measured over the temperature range 1073 to 1446 K. These data, when combined with earlier measurements from this laboratory over the range 1370-2090 K, yield a plot of $\mathrm{ln}D$ vs $\frac{1}{T}$, which is straight over ten orders of magnitude in the diffusion c…

Microstructure and mechanical propertiesCopper Interconnects and ReliabilitySemiconductor materials and interfaces

Luminescence and energy transfer in EuAl3B4O12

F. Kellendonk、G. Blasse1981-07-15The Journal of Chemical Physics

The emission and excitation spectra of the Eu3+ luminescence and the energy transfer phenomena in single crystals of Gd1−xEuxAl3B4O12 (0&amp;lt;x?1) have been investigated using time-resolved site-selection techniques. In addition, the luminescence properties of single crystals and powders have been compared. The resu…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

Local fields at the surface of noble-metal microspheres

B. J. Messinger、K.U. Von Raben、Richard K. Chang 等 4 位作者1981-07-15OpenAlex

Enhancement of the Raman scattering and fluorescence emission on noble metals (Ag, Cu, and Au) is believed to be caused in part by large local fields at the incident wavelength on the surface of metallic microstructures, such as colloidal suspensions and surface roughness on electrodes and thin films. For metallic sph…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNear-Field Optical Microscopy

Dislocation and indentation studies on potassium acid phthalate crystals

Jino George、S.K. Premachandran1981-07-14Journal of Physics D Applied Physics

Potassium acid phthalate (COOKC 6 H 4 COOH) single crystals were grown from aqueous solutions. The cleavage surfaces were examined by multiple-beam interferometry. Solvent etching was used to delineate the dislocations, and their distribution and branching were investigated. The (001), (010) and (100) faces were subje…

Metal and Thin Film MechanicsForce Microscopy Techniques and ApplicationsCrystallization and Solubility Studies

Bulk modulus of a polycrystal

Kenneth S. Mendelson1981-07-14Journal of Physics D Applied Physics

The author considers a polycrystal composed of crystallites for which the response to a hydrostatic pressure is a pure dilatation. Cubic crystals have this property, but it might also be possessed by crystals of lower symmetry. It is proved that the polycrystal also has this property and, regardless of the distributio…

Elasticity and Wave PropagationEngineering Diagnostics and ReliabilityMaterial Properties and Failure Mechanisms

Direct Nuclear-Magnetic-Resonance Measurements of Biaxiality in the Cholesteric Liquid Crystalline Phase

Z. Yaniv、Nuno A. Vaz、G. Chidichimo 等 4 位作者1981-07-06Physical Review Letters

We report what we believe is the first experimental measurement of biaxiality in a cholesteric phase. This observation is made in a selectively deuterated nematic that was twisted by the addition of a chiral compound. A theoretically predicted biaxial order parameter (measured in terms of an asymmetry in the time-aver…

Liquid Crystal Research AdvancementsForce Microscopy Techniques and ApplicationsMolecular spectroscopy and chirality

ESR STUDY OF THE CATION RADICAL OF Mn2(μ-AsPh2)2(CO)8

Shigeru Hayashida、Takashi Kawamura、Teijiro Yonezawa1981-07-01Chemistry Letters

Abstract Radiochemical oxidation of Mn2(μ-AsPh2)2(CO)8 in Freon mixture glass gives its cation radical, ESR spectra of which are most consistent with the odd electron orbital with σ*MnMn character consisting mainly of Mn 3d and As 4p atomic orbitals.

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes