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Intramolecular Energy Transfer in Rare Earth Chelates. Role of the Triplet State

G. A. Crosby、R. E. Whan、R.M. Alire1961-03-01OpenAlex

Results of luminescence studies on chelates of La3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, Tm3+, Yb3+, and Lu3+ are reported. It is shown that the intramolecular energy transfer efficiency is a sensitive function of the relative positions of the resonance energy levels of the ions and the metastable triplet states of the comp…

Luminescence Properties of Advanced MaterialsRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Nucleation and growth of twins in dislocation-free zinc crystals

P. B. Price1961-02-21Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract Zinc whiskers and platelets with their largest faces in the basal plane and thin enough (~½μ) to be transparent to 100 kV electrons were strained in tension inside the electron microscope and the nucleation and growth of twins observed by the transmission technique. These observations were then related to the…

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesAdvanced Welding Techniques Analysis

Effect of Electron Exchange on the Dispersion Relation of Plasmons

Oldwig von Roos、J. Žmuidzinas1961-02-15Physical Review

A calculation of the influence of electron exchange on the dispersion relation of a high-density electron gas at 0\ifmmode^\circ\else\textdegree\fi{}K is described. The result is compared with those obtained by various authors using different methods.

Electron and X-Ray Spectroscopy TechniquesVacuum and Plasma ArcsSurface and Thin Film Phenomena

Surface Structures and Properties of Diamond-Structure Semiconductors

D. Haneman1961-02-15Physical Review

Low-energy electron-diffraction and secondary electron-emission measurements have been made on (111) and ($11\overline{1}$) surfaces of GaSb and (100) surfaces of InSb. To account for the diffraction patterns observed both for these materials and previously for Ge and Si, a general model for (111) surfaces of diamond-…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Chloritized Weathering Products of a New England Glacial Till

R. M. Quigley、Robert T. Martin1961-02-01Clays and clay minerals (National Conference on Clays and Clay Minerals)

Abstract The clay mineralogy of a soil profile developed in a New England glacial till has been studied to a depth of 55 in. Degraded soil micas, probably produced by weathering, have been chloritized by both iron and aluminum hydroxide complexes. Aluminum and iron determinations and X-ray analyses indicate that iron…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

High‐Temperature Energy Relations in the Alkali Borates: Binary Alkali Borate Compounds and Their Glasses

G. SHERWOOD SMITH、Guy E. Rindone1961-02-01Journal of the American Ceramic Society

The energy relations existing between the congruently melting compounds Li 2 O ‐2B 2 O 3 , Na 2 O–2B 2 O 3 , Na 2 O‐4B 2 O 3 , and K 2 O‐4B 2 O 3 and their glasses have been determined for the temperature range 25° to 1100°C. High‐temperature heat‐content, entropy, and heat of solution data are given for both the glas…

Glass properties and applicationsThermal and Kinetic AnalysisChemical Synthesis and Characterization

Twisting of bundles of bacterial cellulose microfibrils

J. Ross Colvin1961-02-01Journal of Polymer Science

Abstract The majority of, but not all, bundles of bacterial cellulose microfibrils show a characteristic left‐handed twist which has a pitch of about 1 μ. The remainder show no apparent coiling. The twist must reflect an internal strain in the component microfibrils which may be due to a slight progressive molecular a…

Advanced Cellulose Research StudiesPolysaccharides and Plant Cell WallsEnzyme Production and Characterization

Part 1—Electrochemical Studies of Tin, Iron-Tin Alloy, and Steel in Air-Free Acid Media: Corrosion Resistance of Electrolytic Tin Plate

G. G. Kamm、A. R. Willey1961-02-01CORROSION

Several types of failure observed in tin plate containers are described in terms of tin-steel potential and current relationships. The effect of Sn++ on potentials and polarization of tin and steel electrodes in deaerated 1N HCl and 0.1M citrate buffer is shown to be important to proper design of electrochemical test…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Origin of the Green Bands in the Boron-Oxygen System

W.E. Kaskan、J. D. Mackenzie、Roger C. Millikan1961-02-01The Journal of Chemical Physics

A study has been made of the effect of oxygen on the intensity of absorption in the green or ``fluctuation'' bands by the gas phase in equilibrium with B2O3(l). The reaction which forms the substance responsible for the bands from B2O3(l) in the presence of oxygen was found to be 70 kcal/mole endothermic, in the range…

Zeolite Catalysis and SynthesisSilicon and Solar Cell TechnologiesBoron and Carbon Nanomaterials Research

Thermionic and Photoelectric Emission from Magnesium Oxide

Jàmes R. Stevenson、Eugene B. Hensley1961-02-01Journal of Applied Physics

Measurements of the thermionic emission as a function of temperature and the photoelectric yield as a function of the photon energy in the range from 2.5 ev to 11.5 ev have been made on magnesium oxide in the form of thin films, powders, and single crystals. The thermionic emission measurements indicate that the posit…

Luminescence Properties of Advanced MaterialsGa2O3 and related materialsElectronic and Structural Properties of Oxides

Some Theoretical Considerations of Cellulose Cross-Linking

John L. Garden、Richard Steele1961-02-01Textile Research Journal

Much available chemical evidence supports the hypothesis that covalent cross-linking is the best way to improve the resilience of cellulosic fabrics. This paper reviews the theories relating physical properties to cross-linking in rubbery polymers and shows that they apply in some qualitative aspects to cellulose. Par…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Crystal Structure and Entropy of Sodium Sulfate Decahydrate

Helena Ruben、David H. Templeton、R. D. Rosenstein 等 4 位作者1961-02-01Journal of the American Chemical Society

The crystal structure of Na 2 504 .10H 200, has been determined to explain the entropy which remains at low temperatures.This substance is monoclinic, space group P2 1 /c, with a =I.1.51 A. , b 10. 38 A. , c 12. 83 A,, each 0.01 A., 3 = 107 0 4511± 10 1 , Z = 4.The corresponding compounds with S replaced by Cr, Se, Mo…

Crystallization and Solubility Studies

STRUCTURE OF THE CONCHIOLIN CASES OF THE PRISMS IN MYTILUS EDULIS LINNE

Charles Grégoire1961-02-01The Journal of Cell Biology

The prisms in the shell of Mytilus edulis Linné are calcite needles. Their small size and their thin conchiolin cases distinguish them from the prisms of many other species of mollusks. These Mytilus prisms have been studied with the electron microscope. The material consisted of positive replicas of surfaces of the p…

Calcium Carbonate Crystallization and InhibitionMarine Biology and Environmental ChemistryCephalopods and Marine Biology

A Familial Tubular Absorption Defect of Glucose and Amino Acids

W. Sheldon、J. Lüder、Barbara Webb1961-02-01Archives of Disease in Childhood

The above title was used (Luder and Sheldon, 1955) to describe a family in which a renal tubular reabsorption defect involving glucose and amino acids appeared in three successive generations (female twins then aged 5, their father and his father). The purpose of this communication is to correct the impression given i…

Enzyme Structure and Function

'Conservative climb' of a dislocation loop due to its interaction with an edge dislocation

F. Kroupa、P. B. Price1961-02-01Philosophical magazine

A new type of dislocation motion, called 'conservative climb', has been observed in zinc platelets deformed in tension inside an electron microscope. Circular, prismatic dislocation loops are often forced to climb out of their glide cylinders by their repulsive interaction with edge dislocations. It is observed that t…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsSurface and Thin Film Phenomena

Energy Dissipation and Secondary Electron Emission in Solids

H. Kanter1961-02-01Physical Review

Experimental evidence is presented for the proportionality between secondary electron yield and the energy dissipated by electrons near the surface of a solid. Using measurements of the energy carried away by electrons transmitted and reflected from thin foils of aluminum and carbon, the energy dissipated in an increm…

X-ray Spectroscopy and Fluorescence AnalysisNuclear Physics and ApplicationsElectron and X-Ray Spectroscopy Techniques

Contribution of Backscattered Electrons to Secondary Electron Formation

H. Kanter1961-02-01Physical Review

It is shown experimentally that backscattered electrons emitted from solids under electron bombardment contribute significantly to the observed secondary yield, even for the case of low backscattering coefficients. Thus, it was found that in Al with a backscattering coefficient of only 0.14, about 40% of all secondari…

Nuclear Physics and ApplicationsElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Heats of Mixing in Liquid Alkali Nitrate Systems

O. J. Kleppa、L. S. Hersh1961-02-01The Journal of Chemical Physics

The enthalpies of mixing in binary liquid alkali nitrate systems have been measured, and are all negative. It is found that the magnitude of the molar mixing enthalpy (ΔHM) increases in a regular fashion with increasing difference in size between the two participating cations, according to the following approximate re…

Thermodynamic properties of mixturesSolid-state spectroscopy and crystallographyChemical Thermodynamics and Molecular Structure

Ferroelectricity in Mixed Bismuth Oxides with Layer-Type Structure

E. C. Subbarao1961-02-01The Journal of Chemical Physics

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation E. C. Subbarao; Ferroelectricity in Mixed Bismuth Oxides with Layer‐Type Structure. J. Chem. Phys…

Physics of Superconductivity and MagnetismZeolite Catalysis and SynthesisSolid-state spectroscopy and crystallography

Statistics of Electron Multiplication

Francis J. Lombard、F. A. Martin1961-02-01Review of Scientific Instruments

The pulse-height distribution at the output of an electron multiplier structure for a single electron input has been calculated assuming a Poisson distribution at each stage. Graphs are given which illustrate the change in pulse-height distribution as a function of the number of stages. This has been done for intersta…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesQuantum-Dot Cellular Automata