Materials Literature
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The behaviour of metal‐free phthalocyanine‐tetrasulfonate and some metal derivatives in aqueous solution has been investigated. It was found that most of these compounds dimerize in diluted aqueous solution. The stabilities of these dimers have been determined by spectrophotometric measurements.
M. Whalley, J. Chem. Soc., 1961, 866 DOI: 10.1039/JR9610000866
Une étude par diffraction de neutrons a montré que la structure de MnAu 2, quadratique centrée, peut être considérée comme un empilement, normalement à l'axe c, de feuillets de manganèse séparés par deux feuillets d'or. MnAu2 est d'autre part un hélimagnétique : tous les atomes de manganèse d'un même feuillet ont leur…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSn1 Nuclear Magnetic Resonance Spectra1John J. Burke and Paul C. LauterburCite this: J. Am. Chem. Soc. 1961, 83, 2, 326–331Publication Date (Print):January 1, 1961Publication History Published online1 May 2002Published inissue 1 January 1961https://pubs.acs.org/doi/10.1021/j…
The kinetics of the dissolution of iron in sulfuric acid was investigated by polarizaton measurements in the presence of iodide ions or carbon monoxide as an inhibitor. The measurements included an oscillographic study of transient phenomena as well as steady states. The adsorption of iodide ions on iron was measured…
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Several species of blue-green algae were studied in thin sections with the electron microscope. Our electron micrographs confirm the view that the cell of blue-green algae is different and simpler in organization than the typical plant or animal cell. On the other hand, the general pattern of ultrastructure is the sam…
J. Lewis, R. S. Nyholm and P. W. Smith, J. Chem. Soc., 1961, 4590 DOI: 10.1039/JR9610004590
The abnormal intensity of some `forbidden' hyperfine transitions in the paramagnetic resonance spectra of ions with S = 1 or more is shown to be due to cross terms in the spin Hamiltonian. These arise from off-diagonal terms in the electronic and nuclear interactions, and the computed transition intensities agree clos…
The Hartree-Fock method is discussed with emphasis placed on the transformation properties of the Hartree-Fock equation. It is emphasized that the Hartree-Fock equation may be solved in terms of non-orthogonal one-electron functions, and that in some cases it may be more convenient to choose such solutions. Equations…
The laws governing thermal radiation are briefly reviewed and methods of measuring emissivity are described. The apparatus used by the author is described and an account of possible sources of error is given. Results of other workers are quoted wherever available, and the thermal emissivity over the useful working tem…
Studies were made of the influence of humidity on the breakdown voltage of gaps in air. The voltages were measured for gaps between uniform-field electrodes and between spheres. The sphere-gaps comprised 2, 6.25, 12.5 and 25cm-diameter spheres which were enclosed in an air-tight chamber in which the humidity was varie…
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In the second part of this article, concluded from the October issue of ‘Platinum Metals Review’, a short account is given of changes in the physical properties of palladium following absorption of hydrogen. The behaviour of certain palladium alloys is compared with that of palladium and alternative methods of approac…
ALTHOUGH UNSATISFACTORY PERFORMANCE OF LIMESTONE AND DOLOMITE AGGREGATES IN CONCRETE IS RELATIVELY RARE, CERTAIN CARBONATE ROCKS HAVE BEEN FOUND TO EXPAND RAPIDLY IN SOLUTIONS OF THE ALKALI METAL HYDROXIDES. THESE REACTIVE ROCKS CAN BE CATEGORIZED ON THE BASIS OF MINERAL COMPOSITION AND TEXTURE, ALL BEING ARGILLACEOUS…
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B. N. Figgis, J. Lewis and F. E. Mabbs, J. Chem. Soc., 1961, 3138 DOI: 10.1039/JR9610003138
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTREACTION BETWEEN SILICA AND CALCIUM HYDROXIDE SOLUTIONS. I. KINETICS IN THE TEMPERATURE RANGE 30 TO 85°1S. A. GreenbergCite this: J. Phys. Chem. 1961, 65, 1, 12–16Publication Date (Print):January 1, 1961Publication History Published online1 May 2002Published inissue 1 Januar…
The Seebeck coefficient α, electrical conductivity σ, and thermal conductivity K data are given for a number of Ag2Te specimens measured at room temperature. The maximum value observed for the figure of merit α2σ/K was 1.3×10−3°C−1. The relationship between K and σ was linear, and Kel could be expressed approximately…