Materials Literature
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The three-dimensional structure of hevein, a low molecular weight protein isolated from the latex of Hevea brasiliensis, has been determined by X-ray diffraction at 2.8 A resolution. The protein crystallizes in space group P2(1)2(1)2(1), with lattice constants a = 21.78, b = 31.86, c = 51.12 A. The structure was solve…
An X-ray single-crystal determination of the CuO structure has been made at 196 K, i.e. below the Neel temperature 230 K, and, as a check, the crystal structure at room temperature was also determined. The correct space group for the structure at both temperature was found to be Cc. Earlier results of magnetic and neu…
The perovskite structure of the relaxor PbMg 1/3 Nb 2/3 O 3 (PMN) is studied using X-ray and neutron powder diffraction data. The static diffuse scattering (SDS) observed in the diffraction patterns at low temperatures is interpreted using a two-phase Rietveld analysis. The structural model is based on a long-range st…
Abstract The interaction between several polymeric materials, typical of those that have application as parenteral product containers, and 16 marker solutes was evaluated. Polymers used included polypropylene, polyvinyl chloride, ethylenevinyl acetate, an olefin rubber, a polyester ether block copolymer, and various c…
Abstract Compression ultrasonic velocity, longitudinal ultrasonic absorption, and heat of mixing for NR‐BR, NR, NBR, and NR‐IIR rubber blends were measured. Results show the applicability of examining the compatibility degree by using longitudinal ultrasonic absorption techniques. Results showed that NR‐BR blends are…
Abstract Silicone polyimides were made with siloxane‐equilibrated 1,3‐bis (3,4‐dicarboxyphenyl) ‐ 1,1,3,3‐tetramethyldisiloxane dianhydride (PADS) as the soft portion and [(1‐methylethylidene) bis (4,1‐phenyleneoxy)] bis‐1,3‐isobenzofurandione (BPADA) as the hard portion in combination with either para or meta ‐phenyl…
Abstract Systematic studies of the gelation of both buffered and unbuffered aqueous Cr +3 /polyacrylamide solutions show that the gelation time is a strong function of pH, increasing by about one order of magnitude per unit decrease in pH for polyacrylamides less than about 7.5% hydrolyzed. The gelation rate also depe…
Abstract The objective of this study was to improve the durability and stability of urea‐formaldehydebonded wood products by decreasing the internal stress developed during resin cure and by improving the ability of the cured system to withstand cyclic stresses. Urea‐formaldehyde resins were modified by (i) incorporat…
We have studied the influence of flexibility on liquid water properties for two different potentials of intramolecular motion. Care has first been taken to explore thoroughly the simulation conditions to obtain reliable results free from artificial influences. Grafting an intramolecular potential on top of an original…
A series of Li–Cd mixed ferrites are prepared by the well-known double sintering ceramic technique. From the X-ray diffraction studies lattice parameters are calculated and their variation with composition is explained on the basis of tetrahedral ionic radius. The longitudinal and shear wave velocities as a function o…
FeTiO3 powder is prepared from aqueous solution (wet method). Magnetic properties of the sample are the same as those of FeTiO3 prepared by calcination. Dielectric properties of the powder are investigated from 4.2 K to room temperature. There are two dielectric relaxations in the low temperature region. One is observ…
A series of Li–Zn mixed ferrites with composition formula Li0.5–0.5xZnxFe2.5–0.5xO4 is prepared by the solid-state reaction method. The variation of lattice parameter with composition is explained on the basis of tetrahedral ionic radius. Thermopower studies are undertaken over a temperature range 300 to 750 K by the…
Kinematical studies of glass transition and crystallization in glassy Se80−xTe20Inx are made using DSC technique. From the heating rate dependence of the glass transition and crystallization temperatures the activation energy, ΔEt, for the relaxation time controlling the structural enthalpy as well as the activation e…
Magnetostriction and magnetomechanical coupling coefficient have been measured on Ho0.85Tb0.15Fe2−xCox (x=0, 0.5, and 1.2) alloys. The alloys were prepared by arc melting as well as by arc melting followed by zoning using induction furnace. Saturation magnetostriction (λs) and magnetomechanical coupling coefficient ar…
On the basis of our recently suggested fan-shaped scattering model [J. Chem. Phys. 92, 5099 (1990)], a method to calculate the translational order parameter τ for the uniaxially oriented liquid crystalline smectic phase is suggested. Using this method, τ is determined from the scattering profiles of the two-dimensiona…
Analytical and numerical calculations of threshold behavior and electro-optical characteristics in twisted chiral nematic layers are presented, when weak anchoring in the tilt and twist angle of the director is assumed. An analytical expression for the effective twist angle and the Fréedericksz threshold voltage is de…
Stable compounds in microwave plasmas of various source gases for vapor-phase diamond growth have been measured by using in situ Fourier transform infrared spectroscopy. Each gas mixture of CH4+H2, C2H2+H2, C2H4+H2, CH3OH+H2, C2H5OH+H2, CO+H2, CCl4+H2, and CH4+O2+H2 was introduced into the plasma discharge region as a…
The ground-state as well as the excited-state absorption and fluorescence properties of single crystals of Cr3+ doped nonstoichiometric green spinels MgO–2.6Al2O3 have been studied at various temperatures and in a broad spectral range (300–1700 nm). Evidence is found of the existence of four distinct classes of Cr3+ s…
The Si2C ground state has been reinvestigated using various basis sets at the Hartree–Fock level as well as with the use of many-body perturbation theory to second order. In agreement with previous theoretical investigations, the ground state is found to be a closed-shell C2v symmetry structure, whereas a linear D∞h s…
Time-resolved OH(X 2Πi,v=1–9) populations have been measured and analyzed to determine parameters relating to formation mechanisms and vibrational relaxation. OH(v) was formed in electron-irradiated Ar/H2/O3 mixtures containing added O2 or CO2 as relaxer species. OH(v→v−1,v−2) emission was observed using time-resolved…