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Spectroscopic characterization of Er3+in stabilized zirconia single crystals

R.I. Merino、V. M. Orera、R. Cases 等 4 位作者1991-10-28Journal of Physics Condensed Matter

Erbium-doped yttria-stabilized zirconia (YSZ) single crystals of 84ZrO 2 /16YO 1.5 composition have been studied by electron paramagnetic resonance (EPR), optical absorption and photoemission techniques at temperatures between 10 and 680 K. At 10 K the Stark-structure of the 4 I 15/2 and 4 S 3/2 multiplets has been re…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

Direct observation of the pressure developed in a liquid during cavitation-bubble collapse

Barry Ward、D. C. Emmony1991-10-28Applied Physics Letters

A Mach–Zehnder interferometer with a pulsed dye-laser light source is used to observe the collapse of laser-produced cavitation bubbles in water near a rigid transparent polymeric boundary. Vapor bubbles with a maximum radius of about a millimeter are formed using a Q-switched Nd:YAG laser operating at 1.06 μm with a…

Ultrasound and Cavitation PhenomenaNuclear Physics and ApplicationsElectrohydrodynamics and Fluid Dynamics

Nonlinear optical study of quasi-one-dimensional platinum complexes: Two-photon excitonic resonance effect

Yoshihiro Iwasa、Eiichi Funatsu、Tatsuo Hasegawa 等 5 位作者1991-10-28Applied Physics Letters

Third-harmonic generation measurements have been made for the first time on oriented films of halogen-bridged mixed-valence platinum complexes for the pump wavelength region from 0.6 to 1.0 μm. The ‖χ(3)(−3ω;ω,ω,ω)‖ spectra obtained by the Maker’s fringe method show a distinct peak at about 1.8 eV with the peak value…

Nonlinear Optical Materials ResearchPhotorefractive and Nonlinear OpticsNonlinear Optical Materials Studies

Chemical vapor deposition of copper from 1,5-cyclooctadiene copper(I) hexafluoroacetylacetonate

Scott Reynolds、Christopher J. Smart、E. Baran 等 6 位作者1991-10-28Applied Physics Letters

We have studied the chemical vapor deposition of copper from 1,5-cyclooctadiene Cu(I) hexafluoroacetylacetonate, a moderately volatile yellow cystalline solid. It yields pure copper by pyrolytic decomposition at 150–250 °C, produces copper films with near bulk resistivity, and has the advantage of being air stable at…

Copper Interconnects and Reliability

Interpreting the near edges of O 2 and O 2 − in alkali-metal superoxides

M. W. Ruckman、Jie Chen、S. L. Qiu 等 6 位作者1991-10-28Physical Review Letters

Depositing alkali metal into a molecular oxygen layer dispersed on a Kr film produces alkali-metal superoxides containing the ${\mathrm{O}}_{2}^{\mathrm{\ensuremath{-}}}$ species for photoemission and near-edge study. The O K-edge spectrum of ${\mathrm{LiO}}_{2}$, ${\mathrm{KO}}_{2}$, and ${\mathrm{CsO}}_{2}$ is in go…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Experimental evidence for excitonic mechanism of defect generation in high-purity silica

T. E. Tsai、David L. Griscom1991-10-28Physical Review Letters

Direct evidence for the creation of oxygen-vacancy, oxygen-interstitial pairs in ${\mathrm{SiO}}_{2}$ glasses by an excitonic mechanism is developed from an electron-spin-resonance study of high-purity fused silicas exposed to highly focused 6.4-eV excimer laser light.

Glass properties and applicationsThin-Film Transistor TechnologiesPhase-change materials and chalcogenides

Thermal budget of multicomponent porous ices

Gerhard Steiner、Norbert I. Kömle1991-10-25Journal of Geophysical Research Atmospheres

A relation for the temperature evolution of multicomponent porous ices is derived from the energy equation of multicomponent systems. It is demonstrated that the predominant energy transfer mechanisms can be incorporated into an effective thermal conductivity (λ e ƒƒ ), which is strongly temperature dependent, and tha…

Thermal properties of materialsCO2 Sequestration and Geologic InteractionsComposite Material Mechanics

Elemental and structural changes in illite/smectite mixed-layer clay minerals during diagenesis in Kimmeridgian- Volgian (- R yazanian) clays in the Central Trough, North Sea and the Norwegian Danish Basin

Holger Lindgreen1991-10-25Bulletin of the Geological Society of Denmark

. The literature on the diagenetic conversion of smectite layers to illite layers in mixed-layer illite/smectite is reviewed. According to this smectite layers are converted to illite layers during diagenesis at temperatures above 55°C and illite/smectites become IS ordered at about 100°C and at illite percentages of…

Soil and Unsaturated FlowClay minerals and soil interactionsTherapeutic Uses of Natural Elements

Amorphous carbon/crystalline silicon high voltage heterojunction diode prepared by photochemical vapour deposition

S.B. Hwang、Y.K. Fang、K.H. Chen 等 5 位作者1991-10-24Electronics Letters

A high reverse breakdown voltage hydrogenated amorphous carbon (a-C:H)/crystalline silicon (c-Si) heterojunction diode has been successfully prepared by the photochemical vapour deposition (photo-CVD) method. This method has the advantage of being free from RF radiation. There is a lower density of fixed charges at th…

Silicon Carbide Semiconductor TechnologiesSemiconductor materials and devicesDiamond and Carbon-based Materials Research

ChemInform Abstract: Synthesis and Characterization of the First Water‐Soluble Closely Interspaced Cofacial Porphyrin Dimer.

Rafik Karaman、Thomas C. Bruice1991-10-22ChemInform

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Understanding liquid structures

R L McGreevy1991-10-21Journal of Physics Condensed Matter

It has often been said that 'the structure factors of all liquids (and glasses) look the same'. Those working in the field know that there is a certain truth to this, as many of the basic features are determined by hard sphere packing. However they also know that there are differences, sometimes subtle, which depend o…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

X-ray reflectivity measurements of the expansion of carbon films upon annealing

C. A. Lucas、Tai D. Nguyen、Jeffrey B. Kortright1991-10-21Applied Physics Letters

Measurements have been made of the x-ray reflectivity from ultrathin, amorphous carbon films both before and after annealing. Analysis of the x-ray results indicates that annealing causes an increase in film thickness with a corresponding decrease in density. Such behavior is uncharacteristic of amorphous thin films a…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchPhase-change materials and chalcogenides

Phonon-defect scattering in high thermal conductivity diamond films

Donald T. Morelli、T. Hartnett、Clifford J. Robinson1991-10-21Applied Physics Letters

We have investigated the thermal conductivity of large diamond samples grown by both hot filament and microwave plasma assisted chemical vapor deposition in order to study in detail the processes limiting heat conduction in this system. For samples containing nearly 100% diamond material and no apparent defects, the t…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchThermal properties of materials

Crystal structure of hevein at 2.8 Å resolution

Adela Rodríguez‐Romero、Kirubhagaran Ravichandran、M. Soriano-Garcı́a1991-10-21FEBS Letters

The three-dimensional structure of hevein, a low molecular weight protein isolated from the latex of Hevea brasiliensis, has been determined by X-ray diffraction at 2.8 A resolution. The protein crystallizes in space group P2(1)2(1)2(1), with lattice constants a = 21.78, b = 31.86, c = 51.12 A. The structure was solve…

Protein Structure and DynamicsGlycosylation and Glycoproteins ResearchEnzyme Structure and Function

CuO: X-ray single-crystal structure determination at 196 K and room temperature

Stig Åsbrink、A. Waśkowska1991-10-21Journal of Physics Condensed Matter

An X-ray single-crystal determination of the CuO structure has been made at 196 K, i.e. below the Neel temperature 230 K, and, as a check, the crystal structure at room temperature was also determined. The correct space group for the structure at both temperature was found to be Cc. Earlier results of magnetic and neu…

Physics of Superconductivity and MagnetismAdvanced Condensed Matter PhysicsCopper-based nanomaterials and applications

A structural model for the relaxor PbMg1/3Nb2/3O3at 5 K

Nicolas de Mathan、E. Husson、G Calvarn 等 6 位作者1991-10-21OpenAlex

The perovskite structure of the relaxor PbMg 1/3 Nb 2/3 O 3 (PMN) is studied using X-ray and neutron powder diffraction data. The static diffuse scattering (SDS) observed in the diffraction patterns at low temperatures is interpreted using a two-phase Rietveld analysis. The structural model is based on a long-range st…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Interactions between polymeric containers and their contained solution: Modeling of polymer‐water solute partitioning via coupled solvent‐water partition coefficients

Dennis Jenke、Richard A. Kenley、Denise S. Hayward1991-10-20Journal of Applied Polymer Science

Abstract The interaction between several polymeric materials, typical of those that have application as parenteral product containers, and 16 marker solutes was evaluated. Polymers used included polypropylene, polyvinyl chloride, ethylenevinyl acetate, an olefin rubber, a polyester ether block copolymer, and various c…

Advanced Polymer Synthesis and CharacterizationCrystallization and Solubility StudiesPolymer Science and PVC

Ultrasonic investigation of some rubber blends

M.A. Sidkey、A. M. Abd El Fattah、A. A. Yehia 等 4 位作者1991-10-20Journal of Applied Polymer Science

Abstract Compression ultrasonic velocity, longitudinal ultrasonic absorption, and heat of mixing for NR‐BR, NR, NBR, and NR‐IIR rubber blends were measured. Results show the applicability of examining the compatibility degree by using longitudinal ultrasonic absorption techniques. Results showed that NR‐BR blends are…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Polyimides synthesized from siloxane‐equilibrated 1,3‐bis (3,4‐dicarboxyphenyl)‐1,1,3,3‐tetramethyldisiloxane dianhydride

Susan A. Nye、S. A. Swint1991-10-20Journal of Applied Polymer Science

Abstract Silicone polyimides were made with siloxane‐equilibrated 1,3‐bis (3,4‐dicarboxyphenyl) ‐ 1,1,3,3‐tetramethyldisiloxane dianhydride (PADS) as the soft portion and [(1‐methylethylidene) bis (4,1‐phenyleneoxy)] bis‐1,3‐isobenzofurandione (BPADA) as the hard portion in combination with either para or meta ‐phenyl…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Slow‐gelling Cr+3/polyacrylamide solutions for reservoir profile modification: Dependence of the gelation time on pH

Thomas P. Lockhart、Paola Albonico、Giovanni Burrafato1991-10-20Journal of Applied Polymer Science

Abstract Systematic studies of the gelation of both buffered and unbuffered aqueous Cr +3 /polyacrylamide solutions show that the gelation time is a strong function of pH, increasing by about one order of magnitude per unit decrease in pH for polyacrylamides less than about 7.5% hydrolyzed. The gelation rate also depe…

Pickering emulsions and particle stabilization