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Comparison of various methods for the determination of specific surfaces of sub soils

G. Jock Churchman、C. M. Burke、R. L. Parfitt1991-09-01Journal of Soil Science

SUMMARY Retention of ethylene glycol monoethylether (EGME) and ethylene glycol (EG), and sorption of nitrogen and water vapour, were studied on a wide range of soils from New Zealand and Fiji. EGME retention was mainly affected by the amount of EGME liquid present in the desiccator, the interaction with the desiccant…

Groundwater and Isotope GeochemistrySoil and Unsaturated FlowClay minerals and soil interactions

A van der Waals theory of nematic liquid crystals: a ‘convex peg in a round hole’ potential

Broto Tjipto-Margo、Glenn T. Evans1991-09-01Molecular Physics

The convex peg potential has been incorporated into a van der Waals theory of the (uniaxial) nematic to isotropic liquid crystal transition. In the convex peg model, molecules are envisioned to have a hard (here biaxial) core embedded in a spherically symmetric square well. Anisotropies in the potential are derived fr…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesAdvanced Materials and Mechanics

Zwei Formen von Dy2OS2

Thomas Schleid1991-09-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Die Oxidation von DyCl 2 mit Schwefel in Gegenwart von NaCl (Tantal‐Kapsel, 800°C, 7 d) liefert Einkristalle von Dy 2 S 3 im U 2 S 3 ‐Typ als Hauptprodukt. Oxidische Verunreinigungen (z. B. DyOCl) werden dabei zu Dy 2 OS 2 umgesetzt, das in zwei verschiedenen einkristallinen Formen anfällt: fast farblose Nade…

Rare-earth and actinide compoundsCrystal Structures and PropertiesInorganic Chemistry and Materials

Mehrstufige reversible Redoxsysteme, LV. Kristallstruktur des CT‐Komplexes 2,5‐Me2‐DCNQI/TTF aus N,N′‐Dicyan‐2,5‐dimethyl‐1,4‐benzochinondiimin und Tetrathiafulvalen sowie des Acceptors 2,5‐Me2‐DCNQI

Alexander Aumüller、Peter Erk、Siegfried Hünig 等 6 位作者1991-09-01Chemische Berichte

Multi‐Step Redox Systems, LV. – Crystal Structure of the CT Complex 2,5‐Me 2 ‐DCNQI/TTF from N,N′‐Dicyano‐2,5‐dimethyl‐1,4 ‐benzoquinone Diimine and Tetrathiafulvalene and of the Acceptor 2,5‐Me 2 ‐DCNQI The crystal structure of the title compound is described and discussed in terms of a neutral non‐conducting mixed‐s…

Magnetism in coordination complexesCrystallography and molecular interactionsOrganic and Molecular Conductors Research

Heteroepitaxial Growth of LiTaO3 Single-Crystal Films by RF Magnetron Sputtering

Yasuyoshi Saito Shiosaki1991-09-01Japanese Journal of Applied Physics

Lithium tantalate (LiTaO 3 ) thin films were deposited on sapphire-C substrates by rf magnetron sputtering at various substrate temperatures. The crystallinity was examined by X-ray diffraction and reflection high-energy electron diffraction (RHEED), and the refractive indices were determined by the prism coupling m-l…

Photonic and Optical DevicesPhotorefractive and Nonlinear OpticsOptical Coatings and Gratings

Studies of adhesion of metal films to polyimide

David L. Pappas、Jerome J. Cuomo、Krishna G. Sachdev1991-09-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Bonding of Cu/Cr films to several polyimides has been studied as a function of polymer surface modification by ion beam and chemical pretreatment. The effects of the metal deposition method and parameters have also been examined. The materials of interest include a low thermal expansion polyimide derived from 3,3′,4,4…

Synthesis and properties of polymersTribology and Wear AnalysisPolymer Nanocomposite Synthesis and Irradiation

Multiple labeling and time-resolvable fluorophores

Eleftherios P. Diamandis1991-09-01Clinical Chemistry

A new time-resolved fluorescence immunoassay system involving use of the europium chelate of 4,7-bis(chlorosulfophenyl)-1,10-phenanthroline-2,9-dicarboxylic acid as label is reviewed. This stable chelate by itself is not very fluorescent but, used in multiple labeling strategies, improves the achievable detection limi…

Advanced Polymer Synthesis and CharacterizationLanthanide and Transition Metal ComplexesClick Chemistry and Applications

Synthesis and characterization of potassium copper telluride (K4Cu8Te11): a novel solid-state chalcogenide compound with a dodecahedral cluster as a building block

Younbong Park、Mercouri G. Kanatzidis1991-09-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and characterization of potassium copper telluride (K4Cu8Te11): a novel solid-state chalcogenide compound with a dodecahedral cluster as a building blockYounbong Park and Mercouri G. KanatzidisCite this: Chem. Mater. 1991, 3, 5, 781–783Publication Date (Print):Sept…

Chalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesNanocluster Synthesis and Applications

Altered phosphorylation of Bacillus subtilis DegU caused by single amino acid changes in DegS

Toshihiro Tanaka、M Kawata、Kuniaki Mukai1991-09-01Journal of Bacteriology

The Bacillus subtilis sacU locus consists of the degS and degU genes, which play a major role in controlling the production of degradative enzymes including extracellular proteases. DegS has been shown to be autophosphorylated and to transfer the phosphoryl group to DegU. In this study, we partially purified the DegS…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionEnzyme Production and Characterization

Calculation of infrared intensities of highly excited vibrational states of HCN using Van Vleck perturbation theory

Anne B. McCoy、Edwin L. Sibert1991-09-01The Journal of Chemical Physics

Canonical Van Vleck perturbation theory (CVPT) is used to calculate electric dipole intensities for one-, two-, and three-dimensional models of HCN and a six-dimensional model of H2CO. Lehmann and Smith [J. Chem. Phys. 93, 6140 (1990)] have shown that the intensities of overtone transitions are sensitive to the detail…

Quantum and electron transport phenomenaAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Morphology and mechanical performance of polyphenylenesulfide carbon fiber composite

L. Caramaro、B. Chabert、J. Chauchard 等 4 位作者1991-09-01Polymer Engineering and Science

Abstract This paper presents the influence of fibers on crystallization kinetics and on matrix morphology for poly(phenylene sulfide)/carbon composite. The following parameters were also considered: thermal stability, fusion/crystallization conditions and surface treatment of carbon fibers. In order to correlate these…

Polymer crystallization and propertiesFiber-reinforced polymer compositesTribology and Wear Analysis

Transition of β to α phase in isotactic polypropylene

F. Rybnikář1991-09-01Journal of Macromolecular Science Part B

In samples of isotactic polypropylene, the influence of the nucleation agent chinacridine permanent red E3B on the crystallization rate and content of α and β modifications and on the rate and mechanism of the β → α transition was investigated using x-ray diffraction, DSC microcalorimetry, and electron microscopy. It…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Effects of Organic Dispersants on the Dispersion, Packing, and Sintering of Alumina

Shigekazu SUMITA、Wendell E. Rhine、H. Kent Bowen1991-09-01Journal of the American Ceramic Society

The effects of water‐soluble polymers and benzoic acid derivatives on green and sintered Al 2 0 3 compacts were studied for two types of alumina powder. The percent of theoretical density achieved by each Al 2 0 3 sediment was dependent primarily on the concentration of water‐soluble polymeric dispersant rather than o…

Advanced ceramic materials synthesisDielectric materials and actuatorsBauxite Residue and Utilization

A comparison of spreading and motility behaviour of 8701 -BC breast carcinoma cells on type I, I-trimer and type V collagen substrata evidence for a permissive effect of type I-trimer collagen on cell locomotion

Claudio Luparello、Peter Sheterline、Ida Pucci‐Minafra 等 4 位作者1991-09-01Journal of Cell Science

Ductal infiltrating carcinoma (d.i.c.) of human breast is a highly invasive neoplasm characterized by enhanced deposition of collagen. Paradoxically, enhanced collagen deposition is not correlated with inhibition of the migration of tumour cells into the host tissue. d.i.c. is characterized by the reappearance of 'emb…

Cell Adhesion Molecules ResearchTGF-β signaling in diseasesCollagen: Extraction and Characterization

Crystallochemistry, properties and organization of soil clays derived from major sedimentary rocks in France

M. Robert、M. Hardy、Françoise Elsass1991-09-01Clay Minerals

Abstract The nature, crystallochemistry, organization and surface properties of soil clays derived from the most representative sedimentary formations of France are described, using qualitative and quantitative mineralogical methods and high resolution transmission microscopy (HRTEM). The main results show that soil c…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Line shape and lifetimes ofCr3+luminescence in silicate glasses

M. Yamaga⋆、B. Henderson、K.P. O’Donnell 等 4 位作者1991-09-01Physical review. B, Condensed matter

This paper describes experimental and theoretical studies of the distribution of crystal-field sites occupied by ${\mathrm{Cr}}^{3+}$ ions in silicate glasses. The effects of this site-to-site disorder on the optical band shape of $^{4}$${\mathit{T}}_{2}$${\ensuremath{\rightarrow}}^{4}$${\mathit{A}}_{2}$ and $^{2}$E${…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsQuantum optics and atomic interactions

Crystallization behavior of polyphenylenesulfide

D.R. Budgell、Michael Day1991-09-01Polymer Engineering and Science

Abstract The crystallization behavior of poly(phenylene sulfide) (PPS) has been examined by differential scanning calorimetry as a function of melt temperature, residence time in the melt, and the presence of a liquid crystal polymer. The results suggest that the thermal history of the sample plays an important role i…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

On the metallicity and the turnoff temperature of M67

L. M. Hobbs、J. A. Thorburn1991-09-01The Astronomical Journal

The present study analyzes high-dispersion echelle spectra of five stars located along the main sequence of M67 using the model atmospheres of Kurucz (1979). An average iron abundance of the cluster, relative to the sun, of -0.04 or - 0.12 is derived from the observed equivalent widths of up to four weak Fe II lines i…

Solidification and crystal growth phenomenaMetallurgy and Material Forming

Transport and Reaction during Pitting Corrosion of Ni in 0.5M NaCl: I . Stagnant Fluid

John N. Harb、Richard C. Alkire1991-09-01Journal of The Electrochemical Society

A two‐dimensional model of a corrosion pit was developed with use of a finite‐element method which accounted for multiple species in solution, reaction equilibria, migration, and surface kinetics. The model was used to simulate the dissolution of a hemispherical corrosion pit on nickel in . Concentration profiles show…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Chemistry of Smectitic and Illitic Phases in Interstratified Soil Smectite

David A. Laird、Phillip Barak、Edward A. Nater 等 4 位作者1991-09-01Soil Science Society of America Journal

Abstract The objective of this investigation was to determine the elemental composition and mineralogy of the smectitic and illitic phases in interstratified smectite‐illite from a typical upper Midwestern agricultural soil. A sample of soil clay (<2‐µm fraction) from the Ap horizon of a Webster (fine‐loamy, mixed,…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications