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Conductive composties form poly(vinyl chloride) and polypyrrole

Marco‐A. De Paoli、R. J. Waltman、Arturo F. Diaz 等 4 位作者1984-01-01Journal of the Chemical Society Chemical Communications

The electrochemical polymerization of pyrrole on a platinum electrode covered with a film of poly(vinyl chloride) produces a dark brown, ductile, and flexible composite polymer film with an electrical conductivity comparable to polypyrrole, and mechanical properties very simllar to poly(vinyl chloride).

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Morphology—properties relationships in binary polyamide 6/rubber blends: Influence of the addition of a functionalized rubber

Sossio Cimmino、L. D’Orazio、Roberto Greco 等 9 位作者1984-01-01Polymer Engineering and Science

Abstract The modification of an amorphous random ethylene‐propylene rubbery copolymer (EPM) has been accomplished by solution grafting of maleic anhydride molecules promoted by radical initiators, The resulting EPM‐g‐succinic anhydride (EPM‐g‐SA) and EPM have been used to obtain binary polyamide 6/EPM or polyamide 6/E…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Cartilage ultrastructure after high pressure freezing, freeze substitution, and low temperature embedding. I. Chondrocyte ultrastructure--implications for the theories of mineralization and vascular invasion.

Ernst B. Hunziker、Wolfgang Herrmann、Robert Schenk 等 5 位作者1984-01-01The Journal of Cell Biology

Electron microscopic examination of epiphyseal cartilage tissue processed by high pressure freezing, freeze substitution, and low temperature embedding revealed a substantial improvement in the preservation quality of intracellular organelles by comparison with the results obtained under conventional chemical fixation…

Meat and Animal Product QualitySilk-based biomaterials and applicationsCollagen: Extraction and Characterization

Stability of the spin density wave phases in (TMTSF)2ClO4 : quantized nesting effect

M. Héritier、Gilles Montambaux、P. Lederer1984-01-01Journal de Physique Lettres

The stability of the SDW phases in (TMTSF)2ClO4 can be interpreted by simple arguments of anisotropic Fermi surfaces nesting : first, we show that anion ordering, by introducing new Bragg's reflexions, perturbs the nesting and lowers the SDW stability. Then, we improve Gor'kov and Lebed's argument on the effect of a m…

Physics of Superconductivity and MagnetismAdvanced Condensed Matter PhysicsOrganic and Molecular Conductors Research

On the stability of the quasi-onedimensional metallic phase in magnetic fields against the spin density wave formation

L. P. Gor’kov、A.G. Lebed'1984-01-01Journal de Physique Lettres

For a simple anisotropic metal model with two open nested Fermi surfaces, it is shown that the tendency to spin density wave formation increases when a magnetic field is applied, which could lead to a series of phase transitions as functions of the field value. The results are suggested as an explanation of the phase…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

The effect of radiolytic oxidation on graphite moderator brick strength in advanced gas-cooled reactors

B.T. Kelly1984-01-01OpenAlex

Etude theorique du procede d'oxydation radiolytique du graphite dans des reacteurs refroidis par l'anhydride carbonique. Etude experimentale de l'influence de cette oxydation sur differentes proprietes physiques et mecaniques du graphite. Influence de cette oxydation sur la duree de vie des briques de graphite utilise…

Nuclear Materials and PropertiesGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Solvent effect on the quantum yield of the self-sensitized photoperoxidation of 1,3-diphenylisobenzofuran

Maria Nowakowska1984-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

The solvent effect on the quantum yield of the self-sensitized photoperoxidation of 1,3-diphenylisobenzofuran has been investigated. The influence of the singlet-oxygen lifetime as well as the viscosity of the solvent are quantitatively described.

Photochemistry and Electron Transfer StudiesPhotochromic and Fluorescence ChemistryFree Radicals and Antioxidants

Thermal decomposition of titanium hydride and its application to low pressure hydrogen control

Y. Hirooka1984-01-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Thermal decomposition behavior of titanium hydride (TiH2) powder at temperatures between 250 and 330 °C (523 and 603 K) has been studied from both thermodynamic and kinetic viewpoints. Equilibrium hydrogen pressure measured in a closed system was found to vary from the order of 10−3 to 10−2 Torr (10−1 to 1 Pa) and the…

Fusion materials and technologiesHydrogen Storage and MaterialsNuclear Materials and Properties

Rate processes in cycling a reversible gas‐solid reaction

M. A. Stanish、D. D. Perlmutter1984-01-01AIChE Journal

Abstract Rate studies are reported of the effect of rehydration‐dehydration cycling on the vapor hydration behavior of solid K 2 CO 3 . Isothermal rate data were obtained at different temperatures and water vapor pressures for the reaction of narrowlysized anhydrous particles. Effects of different particle preparation…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesCrystallization and Solubility Studies

Mineral Composition of Selected Soils in Saudi Arabia

H. Shadfan、A. S. Mashhady、A. Eter 等 4 位作者1984-01-01Zeitschrift für Pflanzenernährung und Bodenkunde

Abstract Ten soil profiles from the agricultural areas in Saudi Arabia were investigated for their mineralogical properties and some general characteristics. It was found that the soils of the eastern region were Torrifluvents and Gypsiorthids, coarse in texture with high salt, gypsum and carbonate contents. Soils of…

Soil Carbon and Nitrogen DynamicsSoil and Unsaturated FlowClay minerals and soil interactions

The inorganic content of pleromin in tooth plates of the living Holocephalan, Chimaera phantasma, consists of a crystalline calcium phosphate known as .BETA.-Ca3(PO4)2 (whitlockite).

Mikio Ishiyama、Ichiro Sasagawa、Junji Akai1984-01-01Archivum histologicum japonicum

The tooth plates in the living Holocephalan, Chimaera phantasma were studied by various techniques. They consisted of osteodentin and hypermineralized pleromin (kosmin). The degree of mineralization on the latter was as much as in the enameloid of Chondrichthyes and Osteichthyes. Scanning electron microscope observati…

Calcium Carbonate Crystallization and Inhibition

The polarization ratio of crystal monochromators

L. D. Jennings1984-01-01Acta Crystallographica Section A Foundations of Crystallography

A tabulation of some 40 measured values of the polarization ratio K (a measure of the fractional polarization introduced into an X-ray beam by a crystal monochromator) is presented. The values may be represented through the parameter n given by K = cosn2θM. The measured values of n cluster around unity and the theoret…

Advanced X-ray Imaging TechniquesNuclear Physics and ApplicationsX-ray Diffraction in Crystallography

Hydrogen Transport through Highly Purified Iron

T. Tanabe、Y. Yamanishi、S. Imoto1984-01-01Transactions of the Japan Institute of Metals

Precise measurements of hydrogen permeation through highly purified iron have been performed utilizing the gaseous permeation technique with the hydrogen pressure ranging between 0.001 and 0.1 MPa in a wide temperature range from 420 to 1100 K. The effect of surface oxide and/or lattice imperfections on hydrogen trans…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Kinetics of the electrochemical evolution of isotopically enriched gases. Part 2.—18O16O evolution on NiCo2O4 and LixCo3–xO4 in alkaline solution

D. Brynn Hibbert、Christine R. Churchill1984-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

The kinetics of the electrochemical evolution of 18O16O from NiCo2O4 and LixCo3–xO4(0 < x < 1.5) electrodes enriched with 18O have been studied. The number of sites responsible for oxygen evolution is related to the lithium content of LixCo3–xO4, showing the importance of tetrahedrally coordinated Co3+. NiCo2O4 has di…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsTransition Metal Oxide Nanomaterials

Preparation and characterization of ZrF4-BaF2-LaF3-NaF-AIF3glass optical fibers

K. Ohsawa、Toshio Shibata1984-01-01Journal of Lightwave Technology

The glass system consisting of ZrF4, BaF2, LaF3, NaF, and AlF3has been developed for optical fibers operating in the mid-infrared region. The glasses in the system possess less tendency to crystallize and favorable optical properties. Additives to improve light scattering characteristics of the fluoride glasses are re…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Non-stoicheiometric Zn–Cr spinel as active phase in the catalytic synthesis of methanol

G. Del Piero、Ferruccio Trifirò、Angelo Vaccari1984-01-01Journal of the Chemical Society Chemical Communications

Zn2+ ions octahedrally co-ordinated in a non-stoicheiometric Zn–Cr spinel-like phase are the active sites in the catalytic synthesis of methanol from syngas at high temperature.

Catalytic Processes in Materials ScienceCatalysts for Methane Reformingnanoparticles nucleation surface interactions

Heat Capacity of Sodium Silicate Liquids

Pascal Richet、Y. Bottinga、Christophe Téqui1984-01-01Journal of the American Ceramic Society

Drop calorimetry measurements for four Na 2 0‐Si0 2 liquids indicate that, to within ±0.5%, the heat capacities are temperature‐independent between 900 and 1800 K and additive functions of composition for liquids containing from 50 to 100 mol% Si0 2 . In this composition interval, the partial molar heat capacities of…

Thermal and Kinetic Analysis

Effect of silver on whole cells and spheroplasts of a silver resistant Pseudomonas aeruginosa.

R M E Richards、H. A. Odelola、B. Anderson1984-01-01PubMed

Electron micrographs of a silver resistant strain of Pseudomonas aeruginosa grown in the presence of 50 micrograms/ml Ag+ indicate that the surviving cells are resistant at the level of the cytoplasmic membrane. Spheroplasts of the resistant strain were not lysed by 1 h contact with 8 micrograms/ml Ag+, but were 36% a…

Nanoparticles: synthesis and applications

Transition to drag-controlled deformation in copper at high strain rates

P.S. Follansbee、G. Regazzoni、U.F. Kocks1984-01-01OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)

The strain rate sensitivity in a variety of metals is known to increase dramatically when the strain rate exceeds about 10/sup 3/ s/sup -1/. In copper, this behavior is analyzed in terms of the transition in rate controlling deformation mechanism from thermal activation to dislocation drag. The mobile dislocation dens…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsHigh-Velocity Impact and Material Behavior