Materials Literature
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We report on the periodic well-defined flower-like zinc oxide (ZnO) nanostructures (NSs) self-assembled through a simple hydrothermal method using silicon (Si) subwavelength grating (SWG) structures. The Si SWGs serve as building blocks for constructing a two-dimensional (2D) periodic architecture to integrate the one…
Disorder-induced effects on plasmon coupling in chains of metallic nanoparticles are studied within a dipole model by considering two types of disorder: fluctuations of the particles' shapes and of their positions. Typical localization effects are found both in the eigenmodes and in the transport behavior of the syste…
Atomic and electronic structures as well as ferroelectricity at $\ensuremath{\Sigma}$5(001) twist boundaries in ferroelectric PbTiO${}_{3}$ have been investigated using first-principles (ab initio) density-functional theory calculations within the local-density approximation. The twist-boundary structure with the coin…
A glass-forming domain is found and studied within Bi 2 O 3 –Sb 2 O 3 –TeO 2 system. The glasses composition were obtained in pseudo-binary x SbO 1.5 , (1− x )TeO 2 for 0.05 ≤ x ≤ 0.20. The constitution of glasses in the system Sb 2 O 3 –TeO 2 was investigated by DSC, Raman, and Infrared spectroscopy. The influence of…
This study investigates the ability of boron nitride nanotubes (BNNTs) to induce apatite formation in a simulated body fluid environment for a period of 7, 14 and 28 days. BNNTs, when soaked in the simulated body fluid, are found to induce hydroxyapatite (HA) precipitation on their surface. The precipitation process h…
The substitution of conventional materials such as aluminium alloys and steels with the lightest structural metal magnesium and its alloys can yield significant weight saving in the transportation industry and hence, reduce vehicle weight and greenhouse gas emissions. Producing magnesium sheets by conventional hot rol…
We investigated the structure and stability of several aluminum hydride complexes to understand the essence of "superatom chemistry" and to gain a right perspective on the ligand (L)-stabilized metal (M) clusters. We successfully interpret the structure and stability using molecular orbital analysis, which clearly sho…
The lithium (Li) adsorption mechanism on the metallic (5,5) single wall carbon nanotube (SWCNT)-fullerene (C(60)) hybrid material system is investigated using first-principles method. It is found that the Li adsorption energy (-2.649 eV) on the CNT-C(60) hybrid system is lower than that on the peapod system (-1.837 eV…
Two novel complexes, [{Mn(salen)}(2){Mn(salen)(CH(3)OH)}{Cr(CN)(6)}](n)·2nCH(3)CN·nCH(3)OH (1) and [Mn(5-Clsalmen)(CH(3)OH)(H(2)O)](2n)[{Mn(5-Clsalmen)(μ-CN)}Cr(CN)(5)](n)·5.5nH(2)O (2) (salen(2-) = N,N'-ethylene-bis(salicylideneiminato) dianion; 5-Clsalmen(2-) = N,N'-(1-methylethylene)-bis(5-chlorosalicylideneiminato…
The properties of polymers on nanoparticles are different than those of the bulk, so that the interphase region becomes more important as the surface/volume ratio of the nanoparticles increases. Knowledge of the modified polymer properties is relevant both in nanocomposite applications and for nanoparticles in suspens…
Carbon and boron nitride nanotubes present significant differences in their electronics. However, they have isoelectronic bonds and very similar geometrical structures that allow BCN nanotubes to be synthesized. These BCN nanotubes present properties that can vary according to their relative number of B, C, and N atom…
Li-, Ta-, and Mn-modified (K,Na)NbO3 ceramics with various compositional homogeneity have been prepared by conventional and precursor methods. The homogeneous ceramic has demonstrated a sharper peak in temperature dependent piezoelectric response. The dielectric and piezoelectric properties of the homogeneous ceramics…
Surface-enhanced Raman scattering (SERS) has recently been investigated extensively for chemical and biomolecular sensing. Multilayer silver (Ag) nanofilms deposited on glass slides by a simple electroless deposition process have been fabricated as active substrates (Ag/GL substrates) for arsenate SERS sensing. The na…
In this paper, we have comparatively investigated the stability of superhydrophobic behaviors of fresh and biomimetic lotus leaf surfaces under controlled water condensation conditions. The binary micro/nano structures of the superhydrophobic surfaces are observed with electron micrographs. Contact and sliding angles…
We show that the magnetically induced waveguide in graphene leads to strong confinement of Dirac fermions, regardless of its edge terminations. The proposed waveguide indeed acts as a ballistic conductor and produces well-localized current density and stepwise increasing conductance. Furthermore, when the waveguide is…
Abstract The effect of the incorporation of several lithium salts on the electrical and mechanical properties of polyurethane rigid (PUR) foams was investigated. Different amounts of lithium chloride (LiCl), lithium perchlorate (LiClO 4 ), and lithium trifluoromethanesulfonate (LiCF 3 SO 3 ) were added to the polyuret…
The complex Tp(Ph,Me)NiS(2)CNMe(2) [Tp(Ph,Me) = hydrotris(3-phenyl-5-methyl-1-pyrazolyl)borate] features a bioinspired N(3)S(2) ligand set supporting a five-coordinate, trigonally distorted square-pyramidal geometry in the solid state. Spin crossover of Ni(II) was demonstrated by temperature-dependent X-ray crystallog…
In this work it was demonstrated that the addition of Sn on CaCu3Ti4O12 material improved non-Ohmic behavior by suppressing dielectric properties. It was noted that the improvement of the varistor characteristics, monitored by the increase in nonlinear coefficient, occurs with the disappearance of the grain dielectric…
We investigate atomic force microscope nanolithography of single and bilayer graphene. In situ tip current measurements show that cutting of graphene is not current driven. Using a combination of transport measurements and scanning electron microscopy we show that while indentations accompanied by tip current appear i…
We investigated the photoluminescence properties of ZnO nanowires coated with Au, Ag, and Pt nanoparticles deposited by dc sputtering. A strong enhancement of the near-band-edge emission was observed in all metal-coated samples but also if the samples were treated with Ar plasma without any nanoparticle deposition. Hi…