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The Intermediate Role of Gd3+ in the Energy Transfer from a Sensitizer to an Activator (Especially Tb3+)

J.Th.W. de Hair、W.L. Konijnendijk1980-01-01Journal of The Electrochemical Society

Energy transfer from a sensitizer to an activator via Gd 3+ ions is discussed. This is done for the Bi 3+ → Dy 3+ and Sb 3+ → Dy 3+ transfer in , and for the Bi 3+ → Tb 3+ transfer in . The phosphor shows Tb 3+ luminescence with a quantum efficiency of 80% for excitation of Bi 3+ . After excitation of Bi 3+ , energy t…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesLuminescence and Fluorescent Materials

A low cobalt ternary Cr-Co-Fe alloy for telephone receiver magnet use

S. Jin、G.M. Chin、B. C. Wonsiewicz1980-01-01IEEE Transactions on Magnetics

The processing, structure, and properties of a low-cobalt, ternary Fe-28Cr-10.5Co isotropic magnet alloy (Chromindur II), developed for use in the telephone receiver, are described. The new alloy is easy to process, and permits a convenient low-temperature recrystallization anneal of heavily cold rolled strips leading…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Étude par spectrométrie Mössbauer de ferrites de lithium substitués. Influence des champs hyperfins supertransferrés et de la relaxation

J.L. Dormann1980-01-01Revue de Physique Appliquée

Des séries de ferrites de Li substitués avec du zinc, du titane et du chrome ont été étudiées de 4 à 300 K. Les paramètres hyperfins des différents sites élémentaires de fer ont été déterminés. La variation du champ hyperfin supertransferré Δ HHST due à la substitution de Zn ou de Li en site A, de Ti, de Cr ou de Li e…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsIron oxide chemistry and applications

Silicate species in solution. Part 1. Experimental observations

Lesley S. Dent Glasser、Eric E. Lachowski1980-01-01Journal of the Chemical Society Dalton Transactions

Changes in the pH or concentration of sodium silicate solutions produce changes in the degree of polymerisation of the silicate species, and these have been followed by the technique of trimethylsilylation. Provided that the pH remains relatively high, above ca. 10 or 11 according to concentration, equilibrium is rapi…

Diatoms and Algae Research

The Orientational Optical Non-linearity of Liquid Crystals. I. Nematics

Nelson V. Tabiryan、Boris Ya Zel'dovich1980-01-01Molecular crystals and liquid crystals

The optical non-linearity of a nematic liquid crystal (NLC) is considered. The strongest effect studied is due to the local turn of NLC director. The possibility of wavefront conjugation by four-wave interaction in a NLC is considered. Strong effects of self-focusing in a NLC due to the orientational mechanism of non-…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationMolecular spectroscopy and chirality

Experimental study on rare-earth element partitioning in minerals formed at 20 and 30kb for basaltic systems.

Hiroshi Shimizu1980-01-01GEOCHEMICAL JOURNAL

Crystal/glass partition coefficients of rare-earth elements (REE), Ba and Sr were precisely determined for the systems prepared by partial melting and partial solidification of high-alumina basalt at 30kb and alkali olivine basalt at 20 and 30kb. At 30kb partial melting produced garnet and clinopyroxene as the solid p…

Geological and Geochemical AnalysisMaterial Dynamics and PropertiesGlass properties and applications

Low temperature hexagonal BaTiO3polymorph and carbonate adsorptiona

N.G. Eror、Thomas M. Loehr、Bahne C. Cornilsen1980-01-01Ferroelectrics

High temperature (1460°C) hexagonal BaTiO3 was found to be stable at temperatures below 700°C. This structure was stabilized at low temperature by an increase in surface free energy that is significant for small crystallites. The hexagonal phase was a precursor for reversible adsorption and desorption of surface carbo…

Zeolite Catalysis and SynthesisCalcium Carbonate Crystallization and InhibitionLayered Double Hydroxides Synthesis and Applications

Pedogenic Degradation of Sepiolite and Palygorskite on the Texas High Plains

Jerry M. Bigham、W. F. Jaynes、Brett L. Allen1980-01-01Soil Science Society of America Journal

Abstract The acicular (needle‐like) clay minerals, sepiolite and palygorskite, were found to be widespread in late Cenozoic sediments of the Texas High Plains. Five soils developed in these sediments, or in materials derived thereform, were analyzed to determine if sepiolite and palygorskite were stable under soilform…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

THE EFFECT OF γ‐AMINOBUTYRIC ACID ON THE INPUT CONDUCTANCE AND MEMBRANE POTENTIAL OF ASCARIS MUSCLE

Richard J. Martin1980-01-01British Journal of Pharmacology

1 Twin intracellular recordings were made from the bag region of Ascaris muscle in order to make conductance measurements. The preparation was bathed in a cool (22 degrees C) Ringer solution to abolish the large spontaneous depolarizing potentials and to improve stability for recording.2 The resting membrane potential…

Conducting polymers and applicationsMuscle activation and electromyography studiesNeuroscience and Neural Engineering

Active carbons from almond shells as adsorbents in gas and liquid phases

Á. Linares-Solano、J. de D. López-González、M. Molina‐Sabio 等 4 位作者1980-01-01Journal of Chemical Technology & Biotechnology

Abstract Almond shells have been used as raw material to prepare activated carbons. The preparation conditions, by direct activation of the raw material with CO 2 or air, or by activation after carbonisation under nitrogen, have been compared in respect to the percentage burn‐off and the adsorptive properties of the r…

Carbon Nanotubes in CompositesPolymer Foaming and CompositesAdsorption, diffusion, and thermodynamic properties of materials

Hydrodynamical behaviour of a two-phase superplastic alloy: α/β brass

M. Suery And、B. Baudelet1980-01-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Constitutive laws hitherto applied to two-phase superplastic alloys have not taken into account their two-phase nature. In order to determine the influence of each of the phases on the constitutive laws, α/β brass was studied for different phase fractions and at different temperatures. A constitutive law is found in w…

Microstructure and mechanical propertiesMetallurgy and Material FormingMetallurgy and Material Science

EFFECTS OF CARBON DEPOSITS ON THE SPECIFIC ACTIVITY OF NICKEL AND NICKEL BIMETALLIC CATALYSTS

Calvin H. Bartholomew、G.D. Weatherbee、G.A. Jarvi1980-01-01Chemical Engineering Communications

The effects of carbon formation on methanation activity of nickel and nickel bimetallic catalysts were investigated. Carbon was deposited on these catalysts at 675-700 K, 1 atm, H2/CO = 2 and space velocities of 80,000 to 200,000 h−1 over a period of 6-24 hours. Specific methanation activities were measured before and…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Ferroelectric behaviour of different classes of smectic liquid crystals

Б. И. Островский、A. Z. Rabinovich、A. S. Sonin 等 6 位作者1980-01-01Ferroelectrics

It is shown that two new classes of smectic liquid crystals - esters and salicelidenanilines - have ferroelectric properties. The new ferroelectric smectics have a hightened hydrolitical stability. Their electrical and heat properties are investigated, the correlation between a chemical composition and spontaneous pol…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Thermal degradation of a series of polyester polyurethanes

N. Grassië、Muhammad Zulfiqar、Marilyn I. Guy1980-01-01Journal of Polymer Science Polymer Chemistry Edition

Abstract A series of polyester polyurethanes with a range of polyester contents was prepared from an ethylene glycol/propylene glycol/adipic acid polyster, butane diol, and methylene bis (4‐phenyl isocyanate) (MBPI). They were thermally degraded under vacuum and the products of degradation were identified. The urethan…

Polymer composites and self-healingSynthesis and properties of polymersPhotopolymerization techniques and applications

Shear waves in colloidal crystals : I. Determination of the elastic modulus

E. Dubois‐Violette、P. Pierański、F. Rothen 等 4 位作者1980-01-01Journal de physique

Shear waves are excited in a latex sample. One detects the vibrations of the sample using light scattering phenomena (Kossel rings). The amplitude of vibrations of the latex sample, when recorded as a function of the frequency of excitation, presents a series of resonances. Analysis of the resonance peaks allows to de…

Diatoms and Algae Research

Kinetics of Potassium Exchange in a Paleudult from the Coastal Plain of Virginia

Donald L. Sparks、L. W. Zelazny、D. C. Martens1980-01-01Soil Science Society of America Journal

Abstract The kinetics of K adsorption from solution to exchangeable phases were investigated on the Ap, A2, B21t, and B22t horizons of Dothan soil (Plinthic Paleudult) from two locations in Virginia. These soils are loamy sands in the upper horizons with clay content increasing with depth, are slightly acidic in the s…

Groundwater and Isotope GeochemistrySoil and Unsaturated FlowClay minerals and soil interactions

Kinetic matrix effects (response and density distribution functions): ring closure. Reaction of indolinobenzospiropyrans in glassy poly(alkyl methacrylates)

M. Κryszewski、Bogus aw Nadolski、A. M. North 等 4 位作者1980-01-01Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics

The ring closure (bleaching) reaction of photochromic indolinobenzospirans is a fast unimolecular process with a finite activation volume. When the reagent is immobilised in a rigid matrix, the isomerization is controlled by the amount of free volume in the neighbourhood of the reacting molecule and so the distributio…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

The Use of Evan's Blue Stain to Test the Survival of Plant Cells after Exposure to High Salt and High Osmotic Pressure

James A. Taylor、D. W. West1980-01-01Journal of Experimental Botany

The survival of plant cells may be tested rapidly and conveniently by staining tissue sections in a solution of Evan's blue (0·5% w/v) after exposure to solutions of high salt concentration or low osmotic potential. Living cells retain the ability to exclude Evan's blue at the plasma membrane and remain their natural…

Diatoms and Algae Research

Complexes of lanthanide ions with the crown ether 1,4,7,10,13,16-hexaoxacyclo-octadecane

J. D. Julius Backer-Dirks、James E. Cooke、Anita M. R. Galas 等 7 位作者1980-01-01Journal of the Chemical Society Dalton Transactions

The title crown ether forms three types of compound with lanthanide ions, [M(NO3)3(crown)](M = La—Nd), M4(NO3)12(crown)3(M = La—Gd), and [M(NO3)3(OH2)3]·crown (M =Gd—Lu). Crystal structures of the first and third types have been determined by X-ray diffraction. The complex [La(NO3)3(crown)] is orthorhombic, space grou…

Metal complexes synthesis and propertiesCrystal structures of chemical compoundsLanthanide and Transition Metal Complexes