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Absolute vibrational excitation cross sections for slow-electron (1–18 eV) scattering in solidH2O

M. Michaud、Léon Sanche1987-11-01Physical Review A

High-resolution vibrational electron-energy-loss spectra of amorphous ice films condensed at 14 K are reported for the incident-energy range 1--18 eV. Absolute electron scattering cross sections for elastic collisions, individual vibrational excitations, and the sum of electronic transitions are obtained by performing…

Advanced Chemical Physics StudiesLuminescence Properties of Advanced MaterialsGa2O3 and related materials

Polariton and effective-medium theory of magnetic superlattices

N. Raj、D. R. Tilley1987-11-01Physical review. B, Condensed matter

The retarded modes of a superlattice comprising alternating layers of two magnetic media characterized by a gyrotropic permeability tensor are investigated. The transfer matrix and dispersion relation are given in general form; a number of previous results are included as special cases. An effective-medium description…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Aluminum/polyimide interface formation: An x-ray photoelectron spectroscopy study of selective chemical bonding

Lj. Atanasoska、Steven G. Anderson、Harry M. Meyer 等 5 位作者1987-11-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

High-resolution x-ray photoelectron spectroscopy has been used to study the formation of the aluminum/polyimide (Al/PI) interface at room temperature. Aluminum films up to 80 Å thick were vapor deposited onto cured polyimide in situ. Our results show that Al is chemically active for coverages below ∼20 Å. Preferential…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityElectron and X-Ray Spectroscopy Techniques

Total cross sections for slow-electron (1–20 eV) scattering in solidH2O

M. Michaud、Léon Sanche1987-11-01Physical Review A

An analytical method is proposed to determine absolute total cross sections per scatterer and related mean free paths for low-energy electron scattering in disordered molecular solid films. The procedure is based on a two-stream multiple-scattering model of the thickness dependence of the film reflectivity for elastic…

Luminescence Properties of Advanced MaterialsGa2O3 and related materialsInorganic Fluorides and Related Compounds

Spinodal decomposition patterns in an isodensity critical binary fluid: Direct-visualization and light-scattering analyses

P. Guénoun、R. Gastaud、F. Perrot 等 4 位作者1987-11-01Physical Review A

In order to study the phase-separation process near the critical point of fluid mixtures (spinodal decomposition) without the influence of the Earth's gravity, we have used a carefully density-matched system of deuterated cyclohexane, cyclohexane, and methanol. Such a system is known to behave as a real binary fluid […

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesSolidification and crystal growth phenomena

Angular discrimination of light transmission through polymer-dispersed liquid-crystal films

Baogang Wu、John L. West、J. W. Doane1987-11-01Journal of Applied Physics

The refractive index of the polymer np is adjusted relative to the ordinary refractive index of dispersed droplets of nematic liquid crystal no to regulate the angle of maximum transmission through a film in the presence of an applied field. Maximum transmission occurs at normal incidence when np≤no with the breadth o…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsOptical Polarization and Ellipsometry

Algorithms for the identification of three-dimensional maximal common substructures

Andrew Brint、Peter Willett1987-11-01Journal of Chemical Information and Computer Sciences

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAlgorithms for the identification of three-dimensional maximal common substructuresAndrew T. Brint and Peter WillettCite this: J. Chem. Inf. Comput. Sci. 1987, 27, 4, 152–158Publication Date (Print):November 1, 1987Publication History Published online1 May 2002Published inis…

Computational Drug Discovery MethodsMachine Learning in Materials ScienceSurface Chemistry and Catalysis

STUDIES ON THE STRUCTURE OF PORPHYRINS CONTAINED IN PHOTOFRIN® II

Thomas J. Dougherty1987-11-01Photochemistry and Photobiology

Abstract Using three methods to attempt to identify the presence of ester‐linked porphyrins in Photofrin® II, lithium aluminum hydride reduction, basic hydrolysis and proton NMR. it can be concluded that 40‐50% of such linkages are present. The majority of the remaining material is cleaved by acid hydrolysis, which is…

Mass Spectrometry Techniques and ApplicationsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Solubility of NiO in Al 2 O 3

Ken Ando、Masataka Momoda、Takeshi Azumi 等 4 位作者1987-11-01Journal of the American Ceramic Society

Solubility of NiO in Al 2 O 3 was determined by electron probe microanalysisy A diffusion couple method was used by coupling an NiO‐doped Al 2 O 3 polycrystal to a pure single crystal of Al 2 O 3 . The solubility of NiO in Al 2 O 3 in air was 230 wt ppm (157 at. ppm of cations) and 170 wt ppm (116 at. ppm) at 2073 and…

Catalytic Processes in Materials Science

Gegen Benzin, Kerosin und Mineralöle Beständige organische Werkstoffe

Karl Häuffe1987-11-01Materials and Corrosion

Abstract Für Bauteile, die mit Benzin, Kerosin und Mineralölen in Kontakt kommen, werden in zunehmendem Maße organische Werkstoffe eingesetzt, wie z.B. hochdichtes Polyethylen, Phenolharze, Polyamide, Polyester, Acrylharze, Epoxy‐ und Fluorcarbonharze, allein oder als Verbundwerkstoffe mit Glas‐, Kohlenstoff‐ und Aram…

Silicone and Siloxane ChemistryEngineering and Materials Science StudiesMaterial Properties and Applications

Variable-angle X-ray photoelectron spectroscopic determination of the thickness of the oxide layer on aluminum metal: An advanced undergraduate laboratory experiment

David E. King、W. E. Swartz1987-11-01Journal of Chemical Education

Introduces students to X-ray photoelectron spectroscopy, the chemical information revealed by the "chemical shift", the surface sensitivity of the technique, and the enhancement of composite data by employing nonlinear least-squares curve-fitting routines.

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Raman and infrared spectra of transition metal halide hexahydrates

F. Agulló‐Rueda、J. M. Calleja、M. Martini 等 5 位作者1987-11-01Journal of Raman Spectroscopy

Abstract The Raman and infrared spectra of NiCl 2 ·6H 2 O, NiCl 2 ·6D 2 O, CoCl 2 ·6H 2 O, CoCl 2 ·6D 2 O and CoBr 2 ·6H 2 O single crystals have been measured in the range 3600–30 cm −1 (Raman) and 3800–400 cm −1 (IR). The water internal modes have been best assigned for NiCl 2 ·6H 2 O, including Fermi resonance effe…

Solid-state spectroscopy and crystallographyInorganic Chemistry and MaterialsInorganic Fluorides and Related Compounds

Suppression of superconductivity by antiferromagnetism inTm2Fe3Si5

J. A. Gotaas、J. W. Lynn、R.N. Shelton 等 5 位作者1987-11-01Physical review. B, Condensed matter

Powder neutron-diffraction experiments at pressures up to 8.2 kbar and temperatures down to 0.3 K have been performed on the antiferromagnetic ternary compound ${\mathrm{Tm}}_{2}$${\mathrm{Fe}}_{3}$${\mathrm{Si}}_{5}$. For pressures between 2 and 21 kbar, this system becomes superconducting at ${T}_{c1}>{T}_{N}$, w…

Rare-earth and actinide compoundsIron-based superconductors researchMagnetic Properties of Alloys

Stress‐Strain Relation for Coated Fabrics

Rene B. Testa、Lop Man Yu1987-11-01Journal of Engineering Mechanics

A constitutive relation is formulated for coated fabrics that exhibit both elastic and inelastic, but time‐independent, responses. The nonlinear orthotropic response is represented by an elastic portion related to yarn stretch and coating shear, and an inelastic part related to crimp interchange. A method is proposed…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis and Optimization

Stability of Glutamine and Pyroglutamic Acid under Model System Conditions: Influence of Physical and Technological Factors

Charles B. Airaudo、André Gayte‐Sorbier、P Armand1987-11-01Journal of Food Science

ABSTRACT The stability of glutamine and pyroglutamic acid as regards pH, temperature and oxygen was studied during storage and two thermal processings, the residual products and those which appeared being determined. Contrary to glutamic acid, the two derivatives are labile below pH 2 and above pH 13 and alteration oc…

Enzyme Structure and FunctionCrystallization and Solubility Studiesthermodynamics and calorimetric analyses

Deep-etch visualization of 27S clathrin: a tetrahedral tetramer.

John E. Heuser、James H. Keen、L M Amende 等 5 位作者1987-11-01The Journal of Cell Biology

It has recently been reported that 8S clathrin trimers or "triskelions" form larger 27S oligomers upon dialysis into low ionic strength buffers (Prasad, K., R. E. Lippoldt, H. Edelhoch, and M. S. Lewis, 1986, Biochemistry, 25:5214-5219). Here, deep-etch electron microscopy of the 27S species reveals that they are clos…

Advanced biosensing and bioanalysis techniquesCellular transport and secretionSupramolecular Self-Assembly in Materials

Breakdown of passivity and localized corrosion processes

H. Boehni1987-11-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBreakdown of passivity and localized corrosion processesH. BoehniCite this: Langmuir 1987, 3, 6, 924–930Publication Date (Print):November 1, 1987Publication History Published online1 May 2002Published inissue 1 November 1987https://doi.org/10.1021/la00078a010RIGHTS & PERMISS…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Microstructural Changes in the Crack Tip Region of Carbon-Black-Filled Natural Rubber

D. J. Lee、J. A. Donovan1987-11-01Rubber Chemistry and Technology

Abstract CB facilitates strain-induced crystallization and increases the size of the crystallized zone at the stressed crack tip. Both effects are major reinforcement mechanisms that increase the fracture resistance of CB-reinforced NR.

Natural Fiber Reinforced CompositesFiber-reinforced polymer compositesTribology and Wear Analysis

Poly(dimethylsiloxane-co-diphenylsiloxanes): synthesis, characterization, and sequence analysis

G. N. Babu、Stumm Christopher、Richard A. Newmark1987-11-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPoly(dimethylsiloxane-co-diphenylsiloxanes): synthesis, characterization, and sequence analysisG. N. Babu, S. S. Christopher, and R. A. NewmarkCite this: Macromolecules 1987, 20, 11, 2654–2659Publication Date (Print):November 1, 1987Publication History Published online1 May…

Corrosion Behavior and InhibitionMarine Biology and Environmental ChemistrySilicone and Siloxane Chemistry